Antiperl 1000

Hazard statements (CLP)

H222, H229, H336, H412

Code

Statements

H222

Extremely flammable aerosol

2.2 Label elements

- Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: | Xt Irritant || F+ Extremely flammable

Hazard statements

12 Extremely flammable. 38 = Irritating to skin. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 67 Vapours may cause drowsiness and dizziness.

Precautionary statements

16 Keep away from sources of ignition - No smoking. 23 Do not breathe spray. 29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point, 46 If swallowed, seek medical advice immediately and show this container or label. 51 Use only in well-ventilated areas.

Special rules for supplemental label elements for certain mixtures

Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Buildup of explosive mixtures possible without sufficient ventilation, Keep out of the reach of children Classification in accordance with Directive 75/324/EEC: Extremely flammable

PBT Substances

Not applicable, YPvB: Not applicable. 3.2 Mixtures - Description: Mixture of | substances listed below with nonhazardous additions. |

Hazardous Ingredients

| CAS: 75-28-5 isobutane - 25-50% EINECS: 200-857-2 [Aj F+ R12 ee a “+ Flam. Gas I, H220; .>. Press. Gas, H280 | CAS: 64742-49-0 Naphtha (petroleum), hydrotreated light 10-25% EINECS: 265-151-9 [9 Xn ROS; 1 Xi R38; PE FRI; fk. N R513 Reg.nr.: 01-2119475514-35-xxxx | R67 \& Flam. Lig. 2, H225; & Asp. Tox. 1, H304; & Aquatic Chronic 2, H411; 1 Skin Irrit, 2, H315; STOT SE 3, H336 CAS: 74-98-6 propane EINECS; 200-827-9 10-25% WAY F+ R12 oo ee &. Flam. Gas 1, H220; -¢: Press. Gas, H280 CAS: 106-97-8 butane EINECS; 203-448-7 25-10% (AiF+ R120 oo _ - .&- Flam, Gas I, H220; — Press. Gas, H280 (Contd, on page 3) Mh —d Trade name: Antiperl 1000 |

Additional information

For the wording of the listed risk Phrases refer to section 16 (Contd. of page 2) SECTION 42 First aid JNCASHTES - 4.1 Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of conipiaints, Take affected persons into fresh air and keep quiet. - After skin contact: Immediately wash with water and soap and rinse thoroughly. Immediately remove any clothing soiled by the product. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Do not induce vomiting; call for medical help immediately. - 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. - 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 32 Fircfiehtiig measures 5.1 Extinguishing media Suitable extinguishing agents: Foam Fire-extinguishing powder Carbon dioxide For safety reasons unsuitable extinguishing agents: Water with full jet 5.2 Special hazards arising from the substance or mixture Can form explosive gas-air mixtures. Formation of toxic gases is possible during heating or in case of fire. - 5.3 Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Cool endangered receptacles with water spray. | Dispose of fire debris and contaminated fire fighting water in accordance with official regulations, SECTION 6: Acvideutal release measures - 6.1 Personal precautions, protective equipment end emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Keep away from ignition sources. - 6.2 Environmental precautions: Inform respective authorittes in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. ‘6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. | 6.4 Reference to other sections See Section 13 for disposal information. Handhug and storage - 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Avoid contact with skin and eyes. Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. (Contd. on page 4) - ——— “ oe GB Trade name: Antiperl 1000 —e Protect against electrostatic charges, (Conid. of page 3) Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C, ie. electric lights. Do not pierce or burn, even after use. Do not spray onto a naked flame or any incandescent material. ' 7.2 Conditions for safe storage, including any incompatibilities The lists valid during the making were used as basis - 8.2 Exposure controls Personal protective equipment: - General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Respiratory protection: Not necessary if room is well-ventilated. Recommended filter device for short term use: Filter AX ' Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the produci/ the substance/ the preparation. Material of gloves Nitrile rubber, NBR Recommended thickness of the material: > 0.45 mm Penetration time of glove material 2240 min The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. - Eye protection: Tightly sealed goggles (Contd. on page 5) - OB Trade name: Antiperl 1000 | a | - Body protection: Protective work clothing (Contd. of page 4) | [: 9.1 Information on basic physical and chemical properties - General Information - Appearance: Form: Aerosal Colour: Colourless » Odour: Petrol-like | - Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Not applicable, as aerosol. | Flash point: Not applicable, as aerosol, - Ignition temperature: >200 °C | + Danger of explosion: Product is not explosive. However, formation of explosive air/vapour | mixtures are possible, » Density at 20 °C: 0.59656 g/cm | Solubility in / Miscibility with water: Not miscible or difficult to mix. | Organic solvents: 92.3 % | 92 Other information | No further relevant information available. - 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. - 10.4 Conditions to avoid Ne further relevant information available. 10.5 Incompatible materials: No further retevant information available. - 10.6 Hazardous decomposition products: | Aldehyde | Carbon monoxide and carbon dioxide oo — —————— — SECTION He Taxicalagical information | ' 11.1 Information on toxicological effects - Acute toxicity; _ + ED/LCS56 values relevant for classification: 7 _ | 64742-49-0 Naphtha (petroleum), hydrotreated light —_ | Oral LD50 | >2000 mg/kg (rai) | Dermal {| LDS5O >2000 mg/Kg (rab} || Inhalative |LC50/4 | >5 mg/ {rat) _ Primary irritant effect: on the skin: Irritant to skin and mucous membranes. - on the eye: No irritating effect. - Sensitization: No sensitizing effects known, Trade name: Antiperl 1000 | - Additional toxicological information: (Contd. of page 5) The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritang Vapours have narcotic effect. - 12,1 Toxicity | + Aquatictoxicity; = oo ~ | a 64742-49-0 Naphtha (petroleum), hydrotreated light EE [ EC50|1-10 mg/l (daphnia) = SOS ~ aa - 12.2 Persistence and degradability No further relevant information available. 12,3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. - Ecotoxical effects: Remark: Harmful io fish - Additional ecological information: General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not aliow product to reach ground water, water course or Sewage system. Danger to drinking water if even small quantities leak into the ground. Harmful to aquatic organisms - 12,5 Results of PBT and yPvB assessinent - PBT: Not applicable. - wPyB: Not applicabie. 12.6 Other adverse effects No further relevant information available. SECTION T3> Disposal considerations - 13.1 Waste treatment methods - Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. | + European waste catalogue 23 = | ~~ 1605 04 | gases in pressure containers (including halons) containing dangerous substances | 435 G1 04 | metallic packaging Uncleaned packaging: - Recommendation: Disposal must be made according to official regulations. SECTION D4: Tran spurt informatian 14.1 UN-Namber | ADR, IMDG, IATA 1950 14.2 UN proper shipping name | -ADR 1950 AEROSOLS . IMDG AEROSOLS | IATA AEROSOLS, flammable | - (Contd. on page 7) - GB Trade name; Antipert 1000 i — —==— eee =a —= oe a _ (Contd. of page 6) | +143 Transport hazard class(es) -ADR | < Class 2 SF Gases. | - Label 21 , ‘MDG, IATA | em | & ca bd | ' Class 24 +: Label i 2/ | - 14.4 Packing group | . ADR, IMDG, IATA Void | . 14.5 Environmental hazards: - Marine pollutant: No - 14.6 Special precautions is for user Warming: Gases Danger code (Kemler): 23 + EMS Number: F-D,S-U | 14,7 Transport in buik according. to Annex HI of | MARPOL73/78 and the IBC Cade Not applicable. bo Transport/Additional in information: ' - ADR | + Limited quantities (LQ) LQ2 - Transport category 2 | » Tunnel restriction | code BID ‘UN "Model Regulation”: UNI950, AEROSOLS, 2.1 SECTION 45: Regulatory information - 15.2 Chemical safety assessment: A Chemical Safety Astergment has not been carried out. SECTION 16: Other iu farnimtion This information is based on our present knowledge, However, this shall not constitute a guarantee for any specific product features and shail not establish a legally valid co ntractual relationship, Relevant phrases H220 Extremely flammable gas. 225 Highly flammable liquid and vapour. #280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation, 336 May cause drowsiness or dizziness. Hall Toxic to aquatic life with long lasting effects, RI 1 Highly flammable. R12 Extremely flammable. (Contd. on page 8) Ga — Trade name: Antiperi 1000 R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R67 = Vapours may cause drowsiness and dizziness. | Abbreviations and acronyms: RID: Réglement dntemational Transport international concernant le transport des marchandises dangereuses par chemin de Ser (Regulations Concerning | the of Dangerous Goods by Rail) ICAO: Inte tonal Civil Aviation Organization ADR: Accord européen sur le transport des marchandises da es par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Alr Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substancez CAS: Chemical Abstracts Service (division of the American Chemical Society) L050: Lethal concentration, 50 percent LDSO: Lethal dose, 5G percent

Storage

Requirements to be met by storcrooms and receptacles: Siore in a cool location. Observe official regulations on storing packagings with pressurized containers, Information about storage in one common storage facility: Not required. ' Further information about storage conditions: Protect from heat and direct sunlight. 7.3 Specific end use(s) No further relevant information available. - Additional information about design of technical facilities: No further data; see item 7. - 8.1 Control parameters - Ingredients with limit values that require monitoring af the workplace: ~ | 106-97-8 butane a , —— WEL | Short-term value: 1810 mg/m}, 750 ppm OO Long-term value: 1450 mg/m’, 600 ppm =| | Carc (if more than 0.1% of buta-1.3-diene) im a een |

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008