Antiper 1000

Hazard statements (CLP)

H220, H225, H280, H304, H315, H336, H411

Code

Statements

H220

Extremely flammable gas

Classification system

The classification is according to the latest editions of the EU-lists, and extended by company and literature data. (Contd. on page 2) (Contd. of page 1)

2.2 Label elements

« Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Marerials. Xt Irritant F+ Extremely flammable . phrases: 12 Extremely flammable. 38 Irritating to skin. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquaric environment. 67 Vapours may cause drowsiness and dizzines: S,

Precautionary statements

16 Keep away from sources of ignition - No smoking. 23 Do not breathe spray. 29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point, 46 If swallowed, seek medical advice immediately and show this container or label. 51 Use only in well-ventilated areas.

Special rules for supplemental label elements for certain mixtures

Pressurized container: protect from sunlight and do not expose fo temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent maserial, Buildup of explosive mixtures possible without sufficient ventilation. Keep out of the reach of children Classification in accordance with Directive 75/324/EEC: Extremely flammable Other hazards Results of PBT and vPvB assessment PBT: Not applicable vPvB: Not applicable E— Mixtures iption: Mixture of substances listed below with nonkazardous additions

Hazardous Ingredients

T B CAS: 75-28-5 isobutane 25-50% EINECS: 200-857-2 |&) F+ RI2 o . o - Flam. Gas I, H220; .= Press. Gas, H280 CAS: 64742490 Naphtha (petroleum), hydroireated light EINECS: 265-151-9 N 10-25% 1% Xn R6S; [3€ Xi R38; B F R11; [i N RS1/53 Reg.nr.: 01-2119475514-35-xxxx| R67 & Flam. Lig. 2, H225; 4 Asp. Tox, 1, H304; & Aquatic Chronic 2, H411; .y Skin Irrit. 2, H315; STOT SE 3, H336 CAS: 74-98-6 propane 10-25% EINECS: 200-827-9 A F+ R12 I &. Flam. Gas 1, H220; CAS: 106-97-8 burane 2510% EINECS: 203-448-7 @ FeRIZ . & Flam. Gas 1, H220; = Press. Gas, H280 - (Contd. on page 3) ——— = Trade name: Antiperl 1000 SECTION 42 Firstard measures + 4.1 Description of first aid measures - After inhalation: Supply fresh air; consult doctor in case of complainss. Take affected persons into fresh air and keep quiet, - After skin contact: Immediately wash with water and soap and rinse thoroughly. Immediately remove any clothing soiled by the product. - After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. « After swallowing: Do not induce vomiting; call for medical help immediately. - 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. - 4.3 Indication of any immediate medical attention and special treatment needed No jurther relevant information available. SECTION 3: Firefighting measures + 5.1 Extinguishing media - Suitable extinguishing agents: Foam Fire-extinguishing powder | Carbon dioxide | « For safely reasons unsuitable extinguishing agents: Waser with full jer | + 5.2 Special hazards arising from the substance or mixture Can form explosive gas-air mixtures. Formation of toxic gases is possible during heating or in case of fire. - 5.3 Advice for firefighters | - Protective equipment: Wear seif-contained respiratory protective device. | -Addifional ion Cool endangered receptacles with waser spray. | Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. SECTION 6; Accidental release measures - 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected. persons away. Ensure adequate ventilation Keep away from ignition sources. + 6.2 Environmental precautions: Inform respective authorities in case of seepage info water course or sewage system. Do not allow 10 enter sewers/ surface or ground water. + 6.3 Methods and material for containment and. up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. | 64 Reference to other sections See Section 13 for disposal information. SECTION 7: Handliug and storage + 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Avoid contact with skin and eyes. - Information abou fire - and explosion protection: Keep ignition sources away - Do not smoke. e | (Contd. 4) Trade name: Antiperi 1000 Protect against electrostatic charges. {Contd. of page 3) Pressurized container: protect from sunlight and do not expase to temperatures exceeding 50 °C, i.e. electric lights. Do not pierce or burn, even afier use. Do not spray onto a naked flame or any incandescent material, 7.2 Conditions for safe storage, including any incompatibilities

Storage

* Requirements 10 be met by storerooms and receptacles: Store in a cool location. Observe official regulations on storing packagings with pressurized containers. - Information about storage in one common storage facility: Not required. « Further information about storage conditions: Protect from heat and direct sunlighs. + 7.3 Specific end use(s) No further relevant information available. PONGTE Cartrofy, - Additional information about design of technical facilities: No further data; see item 7. 8.1 Caltmlpammgan ) -~ ‘ bunk-mnuMTahamnnquin-wmmgqm workplace: | 106-97-8 butane ‘ - | WELShort-term value: 1810 mgj, 750 ppm ) Long-term value: 1450 mg/m’, 600 ppm | Carc (if more than 0.1% of buta-1.3-diene)

Additional information

The lists valid during the making were ised as basis, ~~~ o - 8.2 Exposure controls « Personal protective equipment: + General protective and kygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. - Respiratory protection: Not necessary if room is well-ventilated. * Recommended filter device for short term use: Filter AX + Protection of hands: a Protective gloves The glove material has to be impermeable and resistant to the Pproduct/ the substance/ the preparation. - Material of gloves Nitrile rubber, NBR Recommended thickness of the material: > 0.45 mm + Penetration fime of glove material 2240 min The exact break trough time has to be found ous by the manufacturer of the protective gloves and has to be observed. + Eye protection: Q Tightly sealed goggles (Contd. on page 5) — o - Body protection: Protective work clothing (Contd. of page 4) 9.1 Information on basic physical and chemical properties - General Information - Appearance: Form: Aerosol Colour: Colourless - Odour: Petrol-like J - Change in condition Melting point/Melting range: Undetermined. Boiling, pun/5011.7; range: Not apglimble, annual. Not applicable, as aerosol. >200 °C Product is not explosive. However, formation of explosive airfvapour mixtures are possible. 0.59656 g/em® Not miscible or difficult o mix. 923% No further relevant information available. 10.1 Reactivity +10.2 Chemical stability - Thermal decomposition / conditions to be avoided: No decomposition if used according 1o specifications. - 10.3 Possibility of hazardous reactions No dangerous reactions known. + 10.4 Conditions to avoid No further relevans information available. | - 10.5 Incompatible materials: No further relevant information available. - 10.6 Hazardous decomposition products: Aldehyde Carbon monoxide and carbon dioxide L information + 11.1 Information on toxicological effects - Acute toxicity: - LDJLCS0 values relevant for classification: 63742-49-0 Naphtha (petroleum), hydrotreated Right B " Oral LD30 | >2000 mg/kg (rai) o R | Dermal |{LDS0 |>2000 mg/kg (rab) || Inhalative|LC50/4 h|>5 mg/t (rap) | Primary irrian effect: - - T ‘ - on the skin: Irritant to skin and mucous membranes. | - an the eye: No irritating effect, - Sensitization: No sensitizing effects known, | | | Trade name: Antiperl 1000 - Additional toxicological information: (Contd. of page 5) ‘ The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: ! Irritans | Vapours have narcotic effect. - 12.1 Toxicity - Aquatic toxicity: . B 64742-49-0 Naphtha (petroleum), hydrotreated light | EC50[1-10 my/i {daphnia) - 12.2 Persistence and degradabilisy No further relévant information available. + 12.3 Bioaccumslative potential No further relevant information available, + 12.4 Mobilisy in soil No further relevant information available, - Ecotoxical effects: + Remark: Harmful to fish - Additional ecological information: - General notes: Water hazard class 2 (German Regularion) (Self-assessment): hazardous for water Do not allow product 1o reach ground water, water course or. Sewage system. Danger to drinking water if even small quantities leak into the ground. Harmful 1o aguatic organisms - 12.5 Results of PBT and vPvB assessment ‘ - PBT: Not applicable. | + vPyB: Not applicable. | + 12.6 Other adverse effects No further relevant information available. - 13.1 Waste treatment methods - Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. | - European waste catalogue | B ) | 1605 04| gases in pressure containers {including halons). containing dangerous subsiances \ r 15 01 04| metallic packaging - B T | \ B Di.;paaal must be made according 1o official regulations. ‘ | | = | [ 1950 | 17242 UN proper shipping name -ADR DG 1950 AEROSOLS AEROSOLS | mm . _ AEROSOLS, flammable | " (Contd. on page ) - Trade name: Antiper 1000 | [i63 tanport g ctasseny (Contd. of page 6) 2 5F Gases. 2.1 i 27 | Void - t No o | - 14.6 Special precautions for user Warning: Gases, | « Danger code (Kemler): 23 + EMS Number: o F-D,S-U B o + 14.7 Transport in bulk according to Annex Il of MARPOL73/78 und the IBC Code. _ Notapplicable. i

2.1 Classification of the substance or mixture

2.3 Other hazards - Results of PBT and vPvB assessment « PBT: Not applicable. i vPvB: Not applicable. E— 3.2 Mixtures “ iption: Mixture of substances listed below with nonkazardous additions.