Blue liquid with mild, gasoline like odor

Delek Refining, Ltd

Revision date : 2011-04-01

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 2
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

203-444-5/106-93-4

Name of the chemical

1,2-Dibromethan

Concentration

<0.01%

EC/CAS

265-068-8

Name of the chemical

Naphtha (petroleum), light alkylate

Concentration

100%

General Information

Revision date

2011-04-01

Product name

Blue liquid with mild, gasoline like odor

Product Synonyms

▪ Avgas 100 LL; Aviation Gasoline

Manufacturer Name

Delek Refining, Ltd

Icons in SDS

GHS02 GHS07 GHS08

Company Information

company name

Delek Refining, Ltd

GHS Information

Signal word

DANGER

Section 2

SECTION 2: Hazards identification

OSHA Emergency Overview DANGER Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. May cause respiratory irritation. May be fatal if swallowed and enters airways. May cause damage to organs ­ Ear, Liver, Kidney through prolonged or repeated exposure via Inhalation. May cause cancer . May cause genetic defects . Suspected of damaging fertility or the unborn child ­ . Toxic to aquatic life. Harmful to aquatic life with long lasting effects.

Prevention

Do not breathe dust, fume, gas, mist, vapours and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. ­ No smoking. Ground and/or bond container and receiving equipment. Use only non­sparking tools. Take precautionary measures against static discharge. Use explosion­proof ­ electrical, ventilating and/or lighting equipment. Keep container tightly closed. Wear protective gloves ­ Gloves and eye/face protection , . Use personal protective equipment as required. Wash : thoroughly after handling. Avoid release to the environment.

Response

In case of fire Use appropriate media for extinction. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical advice/attention. IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. IF INHALED: Remove victim to fresh air and keep at rest in a postion comfortable for breathing. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment, see supplemental first aid information. Storage/Disposal Store in a well­ventilated place. Keep cool. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Flammable liquid. Irritating to eyes, skin, and mucous membranes. Aspiration hazard if swallowed. Can enter lungs and cause damage. May cause cancer, reproductive and mutagenic effects. Physical Form ▪ Liquid Color ▪ Blue Odor ▪ Mild, gasoline­like. Flash Point ▪ > ­46 C(> ­50.8 F) UEL ▪ 7 % LEL ▪ 1.2 %

Principle Routes of Exposure

▪ Inhalation, Skin, Eye, Ingestion/Oral Target Organs ▪ Ear/Ototoxin, Skin/Dermal, Lungs, Central Nervous System (CNS), Peripheral Nervous System (PNS), Heart/Cardiovascular System, Liver/Heptatoxin, Kidney/Nephrotoxin

Medical Conditions Generally Aggravated by Exposure

▪ Ear/Ototoxin, Skin/Dermal, Lungs, Central Nervous System (CNS) Peripheral Nervous System (PNS) Brain, Blood and/or Immune System, Anemia, Bone Marrow, Heart/Cardiovascular System, Liver/Heptatoxin, Kidney/Nephrotoxin, NFPA

Potential health effects

Inhalation Acute (Immediate) ▪ May cause irritation. Symptoms may include coughing and difficulty breathing. High vapor concentrations can produce central nervous system depression. Chronic (Delayed) ▪ Extreme overexposure to toluene may cause cardiac sensitization. Skin Acute (Immediate) ▪ May cause irritation. Symptoms may include pain, itching, discoloration, swelling, and blistering. Chronic (Delayed) ▪ Petroleum products are skin defatting agents and can cause dermatitis on prolonged or repeated exposure. Eye Acute (Immediate) ▪ May cause irritation. Symptoms may include pain, tearing, reddening, swelling and impaired vision. Chronic (Delayed) ▪ No data available. Ingestion Acute (Immediate) ▪ Aspiration into the lungs may cause chemical pneumonitis. May cause gastrointestinal disturbances including diarrhea, nausea, and vomiting. Chronic (Delayed) ▪ No data available Mutagenic Effects ▪ Repeated and prolonged exposure may cause mutagenic effects. Carcinogenic Effects ▪ Repeated and prolonged exposure may cause cancer. Carcinogenic Effects CAS NTP IARC

Environmental effects

▪ May cause adverse effects on the aquatic environment.

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