DEGAFAS , DEGAFAS AS , REDUCING AGENT F, DEPILORTM, (THIOUREADIOXIDE)

Hazard statements (CLP)

H251, H302, H315, H319, H335, H402, H412

Code

Statements

H251

Self-heating; may catch fire

H302

Harmful if swallowed

H315

Causes skin irritation

H319

Causes serious eye irritation

H335

May cause respiratory irritation

H402

Harmful to aquatic life

H412

Harmful to aquatic life with long lasting effects

SECTION 2: Hazards identification

OSHA ***** Emergency Overview ***** Highly succeptible to decomposition generating sulfur dioxide, ammonia, sulfinic acid and carbon dioxide if exposed to humidity and heat above 50°C. May irritate digestive tract, upper respiratory tract, eyes and skin.

Signal word

Danger

Hazard statements

H251 Self-heating: may catch fire. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P235 + P410 Keep cool. Protect from sunlight. P261 Avoid breathing dust/fume/ gas/ mist vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves, protective clothing, eye protection, face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment (see supplemental first aid instructions on this label). P330 Rinse mouth. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P407 Maintain air gap between stacks/pallets. P410 Protect from sunlight. P413 Store bulk masses greater than .? kg/ .? Ibs at temperatures not exceeding .? °C/ .? OF. P420 Store away from other materials. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

- none

Principle Routes of Exposure

Ingestion, Inhalation Target Organs: Skin, eyes, upper respiratory tract Acute Effects Inhalation: May cause irritation to the upper respiratory tract. Symptoms may include coughing, sore throat and shortness Shortness of of breath. Eye: May cause irritation, redness and pain Skin: skin irritant when moisture is present. Ingestion: May cause irritation to the digestive tract. Symptoms may include nausea, vomiting, abdominal pain, dizziness and headache.

Medical Conditions Generally Aggravated by Exposure

Chronic exposure may aggravate pre-existing conditions to to include diseases of the skin, eyes and respiratory

Potential chronic health

Thiox

2.1 Classification of the substance or mixture

Self-heating substances and mixtures (Category 1), H251 Acute toxicity, Oral (Category 4), H302 HMIS H 2 Skin irritation (Category 2), H315 F 0 Eye irritation (Category 2A), H319 R 2 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Acute aquatic toxicity (Category 3), H402 PPEt Chronic aquatic toxicity (Category 3), H412 tSec.8