OCULTO

Hazard statements (CLP)

H302I, H312, H315, H319, H332

Hazardous Ingredients

1999/45/EC Classification accordi (EC) No. 1272J2008 203-905-0 01-2'1 '134751 08-36 111-76-2 2-butoryethanol 2,5-5 603-0 1 4-00-0 Acute Tox. 4 H332 / Acute Tox.4 H312 / Acute Tox.4 H302 I Eyelrril.2 H319 / Skin lrrit. 2 H315

Hazard statements

see section 16 see section 16 measures 4.1 . Description of first aid measures General information ln all cases of doubt, or when symptoms persist, seek medical advice. ln case of unconsciousness give nothing by mouth, place in recovery position and seek medical advice. ln case of inhalation Remove casualty to fresh air and keep warm and at rest. ln case of irregular breathing or respiratory arrest provide artificial respiration. Following skin contact Remove contaminated, saturated clothing immediately. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners. After eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediatelY. After ingestion lf swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed ln all cases of doubt, or when symptoms persist, seek medical advice. 4.3. lndication of any immediate medical attention and special treatment needed measures 5.1. Extinguishingmedia Suitable extinguishing media alcohol resistant foam, carbon dioxide, Powder, spray mist, (water) Extinguishing media which must not be used for safety reasons: strong water jet 5.2. Special hazards arising from the substance or mixture Dense black smoke occurs during fire. lnhaling hazardous decomposing products can cause serious health damage 5.3. Advice for firefighters provide a conveniently located respiratory protective device.Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to enter drains, ground or waterways. Treat runoff as hazardous. 6.1. Personal precautions, protective equipment and emergency procedures Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into surface water or drains. lf the product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations. 6.3. Methods and material for containment and cleaning up lsolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it for disposal in appropriate containers in accordance with the local regulations (see chapter 13). Clean using cleansing agents. Do not use solvents. 6.4. Reference to other sections Observe protective provisions (see chapter 7 and 8). 7.1 . Precautions for safe handling Advices on safe handling EN Version: 1.0 lssue Date 16.01 .2014 Page3lT Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only use the material in places where open light, fire and other flammable sources can be kept away. Electrical equipment must be protected meeting the accepted standard. Keep away from heat sources, sparks and open flames. Use only spark proof tools. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal protection equipment: refer to chapter 8. Do not empty containers with pressure - no pressure vessell Always keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations. Precautions against fire and explosion: Vapours are heavier than air. Vapours form explosive mixtures with air. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Storage in accordance with the Ordinance on lndustrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. Soils have to conform to the "Guidelines for avoidance of ignition hazards due to electrostatic charges (BGR 132)". Hints on joint storage Keep away from strongly acidic and alkaline materials as well as oxidizers. Further information on storage conditions Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 "C and 25 "C. Protect from heat and direct sunlight. Due to the content of organic solvents in the preparation: Protect from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. 7.3. Specific end use(s) Observe technical data sheet.Observe instructions for use. 8.1. Control parameters Occupational exposure limit values: 2-butoxyethanol INDEX No. 603-014-00-0 / EC No. 203-905-0 / CAS No 111-76-2 WEL, TWA: 123 mg/m3; 25 ppm WEL, STEL: 246 mg/m3; 50 PPm

Remarks

Sk) BMGV, TWA: 240 mmol (ibutoryacetic acid/mol creatinine in Urin, Post shift) silica amorf EC No. 231-545{ / CAS No. 7631-86-9 WEL, TWA: 6 mg/m3 (inhalable aerosol) WEL, TWA: 2,4 mglm3 (respirable aerosol) Flash point ('C): n.a. lgnition temperature in oC: n. b. lower explosion limit: n. b. Upper explosion limit: n.b. Vapour pressure at 20 "C: n.b. Density at 20 "C: 1,03 g/cm' Water solubility (g/L) water-misible pH value at 20 'C: Viscosity at 20 "C: 20s4mm DIN 53211 Solvent separation test (%): ADR/RID o/o Solid content (%): 28,71 Wt% solvent content: Organic solvents: 3,1 Wt % Water: 68,1 Wt %

Additional information

TWA long-term occupational exposure limit value STEL short-term occupational exposure limit value Ceiling peak limitation 8.2. Exposure controls Provide good ventilation. This can be achieved with local or room suction. lf this should not be sufficient to keep aerosol and solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used. Occupational controls Respiratory protection lf concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number. Hand protection EN Version: 1.0 lssue Date 16.01 .2014 Page4lT For prolonged or repeated handling the following glove material must be used: nitrile rubber or butyl rubber Thickness of the glove material > 0,4 mm ; Breakthrough time (maximum wearing time) > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles DIN EN 374 Barrier creams can help protecting exposed skin areas. ln no case should they be used after contact. Eye protection Wear closely fitting protective glasses in case of splashes. Protective clothing Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers. Protective measures After contact clean skin thoroughly with water and soap or use appropriate cleanser. Environmental exposure controls Do not allow to enter into surface water or drains. See chapter 7. No additional measures necessary 9.1. lnformation on basic physical and chemical properties Appearance: Physical state liquid Colour whitish transpar Odour characteristic Safety relevant basis data Unit Method

Further information

1 10.1. Reactivity '10.2. Chemical stability Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to chapter 7. 10.3. Possibility of hazardous reactions Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions. 10.4. Conditions to avoid Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to chapter 7. Hazardous decomposition byproducts may form with exposure to high temperatures. 10.5. lncompatible materials 10.6. Hazardous decomposition products Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide, smoke, nitrogen oxides. No data on preparation itself available 11.1. lnformation on toxicological effects EN Version: 1.0 lssue date: 16.01 .2014 PageSlT Acute toxicity Toxicological data are not available. lrritant and corrosive effects Toxicological data are not available. Sensitisation Toxicological data are not available. Specific target organ toxicity Toxicological data are not available. Aspiration hazard Toxicological data are not available. Practical experience/human evidence Other observations: lnhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane and respiratory organs, as well as damage to the liver, kidneys and the central nerve system. lndications for this are: headache, dizziness, fatigue, amyosthenia, drowsiness, in serious cases: unconsciousness. Solvents may cause some of the aforementioned effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye irritation and reversible damage. Overall Assessment on CMR properties The ingredients in this preparation do not meet the criteria for classification as CMR category 1 or 2 according to 67/548/EEC. There is no information available on the preparation itself . The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and classified according to the toxicological dangers.See chapters 2 and 15 for details. 2: overall evaluation There is no information available on the preparation itself . Do not allow to enter into surface water or drains. 12.1. Toxicity No information available. Long-term Ecotoxicity Toxicological data are not available. 12.2. Persistence and degradability Toxicological data are not available. 12.3. Bioaccumulative potential Toxicological data are not available. Bioconcentration factor (BCF) Toxicological data are not available. '12.4. Mobility in soil Toxicological data are not available. 12.5. Results of PBT assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex Xlll 12.6. Other adverse effects '13.1. Waste treatment methods Appropriate disposal / Product Recommendation Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste disposal according to EC directives 75l442lEEC and 91/689/EEC in the corresponding versions, covering waste and dangerous waste. EN Version: 1.0 lssue date: 16.01 .2014 PageOlT List of proposed waste codes/waste designations in accordance with EWC 080112 waste paint and varnish other than those mentioned in 0801 11 packaging Recommendation Non-contaminated packages may be recycled. Vessels not properly emptied are special waste. lort information No dangerous good in sense of this transport regulation. 14.1. UN number n.a. 142. UN proper shipping name 14.3. Transport hazard class(es) n.a. 14.4. Packing group n.a. 14.5. Environmental hazards Land transport (ADR/RID) n.a. Marine pollutant n.a. 14.6. Special precautions for user Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8 Additional information Land transport (ADR/RlD) tunnel restriction code Sea transport (IMDG) EmS-No. n.a. 14.7. Transport in bulk according to Annex ll of MARPOL 73178 and the IBC Code not applicable 15."1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation lnformation according to 1999/13/EC about limitation of emissions of volatile organic compounds (VOC-guideline). VOC-value (in gil) ISO '1890-2: 32,633 '1 VOC-value (in g/L) ASTM D 2369: 109,622 according to EU-regulation 20041421EC (appendix ll) EU limit value for this product (cat. (Cat. A/e)): 150 gll (2007)1130 g/l (2010). This product contains max 32,633 g/l VOC. National regulations Restrictions of occupation Observe employment restrictions under the Maternity Protection Directive (92l85/EEC) for expectant or nursing mothers. Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC). Other regulations, restrictions and prohibition regulations '15.2. Chemical Safety Assessment For the following substances of this preparation a chemical safety assessment has been carried out: 203-905-0 2-butoxyethanol 01-2',119475108-36 111-76-2 EN Version: 1.0 lssue date: 16.01 .2014 PageT I 7 16: Relevant R-and H-phrases (Number and full text): Acute Tox. 4 I H332 Acute toxicity (inhalative) Harmful if inhaled. Acute Tox. 4 I H312 Acute toxicity (dermal) Harmful in contact with skin. Acute Tox. 4 I H3OZ Acute toxicity (oral) Harmful if swallowed. Eye lrrit. 2 I H319 Serious eye damage/eye irritation Causes serious eye irritation. Skin lrrit. 2 I H315 skin corrosion/irritation Causes skin irritation. Xn, R20121122 Harmful Harmful by inhalation, in contact with skin and if swallowed. Xi; R36/38 lrritant lrritating to eyes and skin.