HARDER MAGIC 2K

Hazard statements (CLP)

H226, H301, H311, H314, H317, H317I, H319, H331, H332, H334I, H335, H360D, H3O2, H412

Code

Statements

H226

Flammable liquid and vapour

2.2 Label elements

(67/548/EEC or 1999/45/EC) x Xn Harmful

Hazard statements

10 Flammable. 20 Harmful by inhalation. 37 lrritating to respiratory system. 43 May cause sensitization by skin contact. see section 16 see section 16 measures 4.1. Description of first aid measures: General information: ln all cases of doubt, or when symptoms persist, seek medical advice. ln case of unconsciousness give nothing by mouth, place in unconscious position and seek medical advice. After inhalation Move victim to fresh air. Put victim at rest and keep warm. ln case of irregular breathing or respiratory arrest provide artificial respiration. ln case of skin contact: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners. ln case of eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice. After ingestion: lf swallowed, rinse mouth with water (only if the person is conscious). Consult physician immediately. Keep victim calm. Do not induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed: ln all cases of doubt, or when symptoms persist, seek medical advice. 4.3. Indication of any immediate medical attention and special treatment needed measures 5.1. Extinguishing media Suitable extinguishing media: Alcohol resistant foam, Carbon dioxide, Powder, spray mist, (water) Extinguishing media which must not be used for safety reasons: Strong water jet 5.2. Special exposure hazards arising from the substance or preparation itself, its combustion products or from resulting gases: Dense black smoke occurs during fire. lnhaling hazardous decomposing products can cause serious health damage. 5.3. Special protective equipment for firefighters: Provide a conveniently located respiratory protective device,Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to enter drains, ground or waterways. Treat runoff as hazardous. measures 6.1. Personal precautions, protective equipment and emergency procedures Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours. See protective measures under point 7 and 8. 6.2. Environmental measures Do not allow to enter into surface water or drains. lf the product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations. 6.3. Methods and material for containment and cleaning up lsolate leaked material using non-flammable absorption agent (e.9. sand, earth, vermiculit, diatomaceous earth) and collect it for disposal in appropriate containers in accordance with the local regulations (see chapter 13). Use appropriate container to avoid environmental contamination. Fouled surfaces must be immediately cleaned with suitable solvents, Useable as such (flammable): water 45 vol.% ethanol or i-propanol 50 vol. % ammonia solution (density= 0.88) 5 vol.o/o Alternative (non-flammable): sodium carbonate 5 vol.% water 95 vol.%. Take up spilled residuals with the same agent and leave them for a few days in unclosed containers until there is no further reaction. Then, close the contarners and dispose of them in accordance with the regulations for waste removal (refer to Chapter 13 6.4. Reference to other sections Observe protective provisions (see chapter 7 and 8). People who suffer from skins problems, asthma, allergies, chronic or recurring respiratory illnesses must not be deployed in processes, which use this substance. People who spray this preparation should have regular pulmonary function tests. 7.1. Precautions for safe handling Advices on safe handling Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only use the material in places where open light, fire and other flammable sources can be kept away. Electrical equipment must be protected meeting the accepted standard. Product may become electrostatically charged. Provide earthing of containers, equipment, pumps and ventilation facilities. Anti-static clothing including shoes are recommended. Floors must be electrically conductive. Be careful when opening used containers (excess pressure)" Precautionary measures should be taken in order to reduce strain from humidity or water: CO2 is formed which may produce excess pressure in closed containers . Keep away from heat sources, sparks and open flames. Use only spark proof tools. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal protection equipment: refer to chapter 8. Do not empty containers with pressure - no pressure vessell Always keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations. Precautions against fire and explosion: Vapours are heavier than air and will spread at floor level. Vapours form explosive mixtures with air. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storerooms and containers: Storage in accordance with the Ordinance on lndustrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. Hints on joint storage Keep away from skongly acidic and alkaline materials as well as oxidizers. Keep away from amines, alcohols and water. Further information on storage conditions Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15'C and 25'C. Protect from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. 7.3. Specific end use(s) Observe technical data sheet.Observe instructions for use. people who suffer from skins problems, asthma, allergies, chronic or recurring respiratory illnesses must not be deployed in processes, which use this substance. People who spray this preparation should have regular pulmonary function tests. 8.'1 . Control parameters 203-603-9 2-methoxy-'1 -methylethyl acetate 548 274 mg/m3 108-65-6 EN 100 50 _pPll

Precautionary statements

24 Avoid contact with skin. 26 ln case of contact with eyes, rinse immediately with plenty of water and seek medical advice 37 Wear suitable gloves. 38 ln case of insufficient ventilation, wear suitable respiratory equipment. 51 Use only in well-ventilated areas. 23 Do not breathe vapour.

Contains

hexane 1.6 diisocyante mono polymer aliphatic polyisocyanate

Special rules for supplemental label elements for certain mixtures

91 Contains isocyanates. May produce an allergic reaction

2.3 Other hazards

3.2. Mixtures chemical characterization (preparation) Description

CLP CLASSIFICATION

500-060-2 0 1 -21 1 94857 96-1 7-0000 50 - 100 28182-81-2 hexane .6 diisocyante mono polymer '1 Acute Tox. 4 H332 / STOT SE 3 H335 / Skin Sens. 1 H317 203-603-9 01-2119475791-29 25-50 1 08-65-6 2-methoxy-1 -methylethyl acetate 607-1 95-00-7 Flam. Liq. 3 H226 999-999-0 5 -10 6667723-27-9 aliphatic polyisocyanate Skin Sens. 1 H3'17 / Aquatic Chronic 3 H412 202-715-5 1-2,5 98-94-2 N, N dimetehylcyclohexylamine Flam. Liq. 3 H226 / Met" Corr. 1H290 I Acute Tox. 3 H301 / Acute Tox. 3 H311 / Acute Tox.3 H331 / Skin Corr. 18 H314 / Skin Sens. 1H317 I Aquatic Chronic 3 H412 212485-8 01-211945757 1-37 < 0,5 822-06-0 hexamethylenedi-isocyanate 61 s-01 1 -00-1 AcuteTox.4 H3O2 / AcuteTox. 1H330 / Skinlrrit.2H3l5 I Eyelrril.2 H319 / Skin Sens. 1 H317 I Resp. Sens. I H334 I STOT SE 3 H335 274-724-2 < 0,5 70657-704 2-methoxypropyl acetate 607-25 1 -00-0 Flam. Liq. 3 H226 / Repr. H360D / STOT SE 3 H335 'lB

2.1 Classification of the substance or mixture

Classification according to Directive 67/548/EEC or 1999/45/EC The preparation is dangerous in the sense of Directive 1999/45/EC. R10 Flammable. Xn; R20 Harmful Harmful by inhalation. Xi, R37 lrritant lrritating to respiratory system. R43 May cause sensitization by skin contact.

Additional information

Substance with a common (EC) occupational exposure limit value. TWA (EC): Occupational exposure limit value STEL (EC): Short{erm occupational exposure limit value 8.2 Exposure controls Provide good ventilation. This can be achieved with local or room suction. When spraying, wear self-contained breathing apparatus. For other tasks a suitable respiratory system must be used, if local and room suction is not sufficient for keeping aerosol and solvent vapour concentration below the exposure limit values. (refer to Personal protection equipment.) Occupational exposure colttrols Respiratory protection: lf concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Use only respiratory protection equipment with CE-symbol including four digit test number. Hand protection: For prolonged or repeated handling the following glove material must be used: nitrile rubber or butyl rubber Thickness of the glove material > 0,4 mm ; Penetration time (maximum wearing period) > 480 min Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles. DIN EN 374 Barrier creams can help protecting exposed skin areas. ln no case should they be used after contact. Eye protection: Wear closely fitting protective glasses in case of splashes. Body protection: Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers. Protective measures: After contacl clean skin thoroughly with water and soap oder use appropriate cleanser. Environmental exposure cgntrols Do not allow to enter into surface water or drains. refer to chapter 7. No further action is necessary a rerties 9.'t . lnformation on basic physical and chemical properties Appearance: Physical state: liquid Colour as labeled Odour: characteristic Safety relevant basis data Unit Method

Remarks

Flash point ('C): 42 DtN 53213 lgnition temperature (AlT): n.b. lower explosion limit: n.b. Upper explosion limit: n.b. Vapour pressure at 20 "C: n.b. Density at 20 "C: I,O4 g/cm" Water solubility (g/l): insoluble pH at 20'C: Viscosity at20'C 30s4mm DtN 53211 Solvent separation test (%): <3 ADR/RID o/o Solid content (%): 60 % by weight solvent content: Organic solvents:: 40,0 by weight o/o

Further information

10. 10.1. Reactivity Reacts with water, forming carbon dioxide, producing bursting hazard in closed containers due to build-up of pressure. 10.2. Chemical stability Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to chapter 7. 10.3. Possibility of hazardous reactions Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.Reacts with water, forming carbon dioxide, producing bursting hazard in closed containers due to build-up of pressure. 10.4. Conditions to avoid Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to chapter 7. Hazardous decomposition byproducts may form with exposure to high temperatures. 10.5. lncom patible materials 10.6. Hazardous decomposition products Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide, smoke, nitrogen oxides. 11. No data on preparation itself available. 1'1.1. lnformation on toxicological effects Acute toxicity Toxicological data are not available. lrritant and corrosive effects Toxicological data are not available. Sensitisation Toxicological data are not available. Specific target organ toxicity Toxicological data are not available. Aspiration hazard: Toxicological data are not available. Practical experience Other observations: lnhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane and respiratory organs, as well as damage to the liver, kidneys and the central nerve system. lndications for this are: headache, dizziness, fatigue, amyosthenia, dizziness, in serious cases: unconsciousness. Solvents may cause some of the aforementioned effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye irritation and reversible damage. Because of the isocyanate components'properties of this and with consideration of similar preparations the following applies: Preparation may cause acute irrtation andior sensitization of airways which lead to tightness in thorax, short-breath and asthmatic complaints. After sensitization even concentrations below the exposure limit values may cause asthma. Repeated inhaling can lead to permanent illness of the respiratory tract. Overall Assessment on CMR properties: 274-724-2 2-methoxypropyl acetate Repr. Cat. 2 70657-704 There is no information available on the preparation itself . The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999i45/EC and classified according to the toxicological dangers.See chapters 2 and 15 for details. ical information Overall evaluation: There is no information available on the preparation itself . Do not allow to enter into surface water or drains. 12.1. Toxicity No information available. Long-term Ecotoxicity Toxicological data are not available. 12.2. Persistence and degradability Toxicological data are not available. 12.3. Bioaccumulative potential Toxicological data are not available. Bioconcentration factor (BCF): Toxicological data are not available. 12.4. Mobility in soil Toxicological data are not available. 12.5. Results of PBT and vPvB assessment The components in this formulation do not meet the criteria for classification as PBT or vPvB 12.6. Other adverse effects 1 3.1 . Waste treatment methods Appropriate disposa! / Product Recommendation: Do not allow to enter into surface water or drains. Handle contaminated packaging in the same way as the substance itself.This material and its container must be disposed of in a safe way. Waste disposal according to EC directives 75l442lEEC and 9'l/689/EEC in the corresponding versions, covering waste and dangerous waste. Control report for waste code/ waste marking according to EAKV: 080111 waste paint and varnish containing organic solvents or other dangerous substances Contaminated packaging Recommendation: Cleaned containers may be recycled. Vessels not properly emptied are special waste port information 14.1. UN-No. 1263 14.2. UN proper shipping name Land transport (ADR/R|D): Verfuerwante produkten Sea transport (IMDG): PAINT Air transport (ICAO-TI / IATA-DGR): Paint 14.3. Transport hazard class(es) 3 14.4. Packing Group: ill 14.5. Environmental hazards: Land transport (ADR/RID) n.a. Marine pollutant: n.a. 14.6. Environmental hazards Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - I Further remarks: Land transport (ADR/RID) Tunnel restriction code: D/E Sea transport (IMOG) EmS-No.: F-E, S-E 14.7. Special precautions for user not applicable 1 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation lnformation according to 1999/'13/EC about limitation of emissions of volatile organic compounds (VOC-guideline). VOC-value (in g/l) ISO 1 1890-2: 430,480 VOC-value (in g/l) ASTM D 2369: 430,480 National regulations lnformations on working limitations Observe employment restrictions under the Maternity Protection Directive (92l85/EEC) for expectant or nursing mothers. Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC). 15.2. Chemical Safety Assessment A chemical safety assessment has been carried out on following substance: 203-603-9 2-methoxy-1 -methylethyl acetate 01-2119475791-29 1 08-65-6 soo-ooo-z heiane 1.6 diisocyante mon<i pot-Vrner 01 -21 1 94857 96-1 7-0000 28182-81-2 212485-8 hexamethylene diisocyanate 01-21 1945757 1-37 822-06-0 16. Relevant R-and H-phrases (Number and full text): Acute Tox. 4 1H332 Acute toxicity (inhalative): Harmful if inhaled. STOT SE 3 / H335 Specific target organ toxicity (single May cause respiratory irritation exposure): SkinSens. 11H317 Respiratory or skin sensitisation: May cause an allergic skin reaction. Flam. Liq. 31H226 Flammable liquids: Flammable liquid and vapour. Aquatic Chronic 3l H412 Hazardous to the aquatic environment: Harmful to aquatic life with long lasting effects. Met. Corr. 1 1H290 Corrosive to metals: May be corrosive to metals. AcuteTox.3/H301 Acute toxicity (oral): Toxic if swallowed. Acute Tox. 3 / H31 1