AQUAFIX PROJECT 2K CIRANOVA SEMI MAT

2.2 Label elements

Labellinq (6715481E EC or 1999/45/EC)

Hazard statements

n.a. see section 16 see section 16 SECTION 4: First aid measures 4.1 . Description of first aid measures General information ln all cases of doubt, or when symptoms persist, seek medical advice. ln case of unconsciousness give nothing by mouth, place in recovery position and seek medical advice. ln case of inhalation Remove casualty to fresh air and keep warm and at rest. ln case of irregular breathing or respiratory arrest provide artificial respiration. Following skin contact Remove contaminated, saturated clothing immediately. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners. After eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediately. After ingestion lf swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed ln all cases of doubt, or when symptoms persist, seek medical advice. 4.3. lndication of any immediate medical attention and special treatment needed measures 5.1. Extinguishingmedia Suitable extinguishing media alcohol resistant foam, carbon dioxide, Powder, spray mist, (water) Extinguishing media which must not be used for safety reasons: strong water jet 5.2. Special hazards arising from the substance or mixture Dense black smoke occurs during fire. lnhaling hazardous decomposing products can cause serious health damage. 5.3. Advice for firefighters Provide a conveniently located respiratory protective device.Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to enter drains, ground or wateruays. Treat runoff as hazardous. 6.1. Personal precautions, protective equipment and emergency procedures Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into surface water or drains. lf lhe product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations. 6.3. Methods and material for containment and cleaning up lsolate leaked material using non-flammable absorption agent (e.9. sand, earth, vermiculit, diatomaceous earth) and collect it for disposal in appropriate containers in accordance with the local regulations (see chapter 13). Clean using cleansing agents. Do not use solvents. 6.4. Reference to other sections Observe protective provisions (see chapter 7 and 8). 7.1 . Precautions for safe handling Advices on safe handling Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only use the material in places where open light, fire and other flammable sources can be kept away. Electrical equipment must be protected meeting the accepted standard. Keep away from heat sources, sparks and open flames. Use only spark proof tools. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal protection equipment: refer to chapter 8. Do not empty containers with pressure - no pressure vessell Always keep in containers that correspond lo the material of the original container. Follow the legal protection and safety regulations. Precautions against fire and explosion: Vapours are heavier than air. Vapours form explosive mixtures with air. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Storage in accordance with the Ordinance on lndustrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. Soils have to conform to the "Guidelines for avoidance of ignition hazards due to electrostatic charges (BGR 132)". Hints on joint storage Keep away from strongly acidic and alkaline materials as well as oxidizers. Further information on storage conditions Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 'C and 25 "C. Protect from heat and direct sunlight. Due to the content of organic solvents in the preparation: Protect from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks. 7.3. Specific end use(s) Observe technical data sheet.Observe instructions for use. )rotection 8.1. Control parameters Occupational exposure limit values 2-(2-butoxyethory)etha nol INDEX No. 603-096-00-8 / EC No. 203-961€ / CAS No. 112-34-5 WEL, TWA: 67,5 mg/m3; "10 ppm WEL, STEL: 10'1 ,2 mg/m3; 15 ppm

Precautionary statements

23 Do not breathe gas/fumes/vapour/spray. 51 Use only in well-ventilated areas.

Contains

n.a.

Special rules for supplemental label elements for certain mixtures

n.a.

2.3 Other hazards

on 3.2. Mixtures

Product definition

/ chem ical characterization Description

2.1 Classification of the substance or mixture

Classification according to Directive 67l548|EEC or 1999/45/EC This mixture is classified as not hazardous according to 1999/45/EC.

Additional information

TWA long-term occupational exposure limit value STEL short{erm occupational exposure limit value Ceiling peak limitation 8.2. Exposure controls Provide good ventilation. This can be achieved with local or room suction. lf this should not be sufficient to keep aerosol and solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used. Occupational exposure controls Respiratory protection lf concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number. Hand protection For prolonged or repeated handling the following glove material must be used: Thickness of the glove material > 0,4 mm ; Breakthrough time (maximum wearing time) > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles DIN EN 374 Barrier creams can help protecting exposed skin areas. ln no case should they be used after contact. Eye protection Wear closely fitting protective glasses in case of splashes. Protective clothing Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers. Protective measures After contact clean skin thoroughly with water and soap or use appropriate cleanser. Environmental exposure controls Do not allow to enter into surface water or drains. See chapter 7. No additional measures necessary N a rerties 9.1. lnformation on basic physical and chemical properties Appearance: Physical state liquid Colour as labeled Odour characteristic Safety relevant basis data Unlt Method

Remarks

Flash point ('C): > 61 .C DIN 53213 lgnition temperature in 'C: 204 "C Lower explosion limit: 0,8 Volo/o Upper explosion limit: 5,9 Vol-% Vapour pressure at 20 "C: n.a. Density at 20 'C: 1,00 g/cm3 Water solubility (g/L): water-misible pH at 20'C: Viscosity at 20 'C: 22 s 4 mm DtN 53211 Solvent separation test (%): < 3 ADR/RID Solid content (%): 32,00 wt% solvent content: Organic solvents: 0,0 wt% Water: 68,0 wt%

Further information

I Stabi ty 10.1. Reactivity 10.2. Chemical stability Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to chapter 7. 10.3. Possibility of hazardous reactions Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions. 10.4. Conditions to avoid Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to chapter 7. Hazardous decomposition byproducts may form with exposure to high temperatures. 10.5. lncompatible materials 10.6. Hazardous decomposition products Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide, smoke, nitrogen oxides. 11: ical information No data on preparation itself available. 11.1. Information on toxicological effects Acute toxicity Toxicological data are not available. lrritant and corrosive effects Toxicological data are not available. Sensitisation Toxicological data are not available. Specific target organ toxicity Toxicological data are not available. Aspiration hazard Toxicological data are not available. Practical experience/human evidence Other observations: lnhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane and respiratory organs, as well as damage to the liver, kidneys and the central nerve system. lndications for this are: headache, dizziness, fatigue, amyosthenia, drowsiness, in serious cases: unconsciousness. Solvents may cause some of the aforementioned effects through skin resorptlon. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye irritation and reversible damage. Overall Assessment on CMR properties The ingredients in this preparation do not meet the criteria for classification as CMR category 1 or 2 according to 67/548/EEC. There is no information available on the preparation itself . The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and classified according to the toxicological dangers.See chapters 2 and 15 for details. overall evaluation There is no information available on the preparation itself . Do not allow to enter into surface water or drains. 12.1 Toxicity No information available. Long-term Ecotoxicity Toxicological data are not available. 12.2. Persistence and degradability Toxicological data are not available. 12.3. Bioaccumulative potential Toxicological data are not available. Bioconcentration factor (BCF) Toxicological data are not available. 12.4. Mobility in soil Toxicological data are not available. 12.5. Results of PBT assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex Xlll. 12.6. Other adverse effects 13: 13.1. Waste treatment methods Appropriate disposal / Product Recommendation Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste disposal according to directive 2008/98/EC, covering waste and dangerous waste. packaging Recommendation Non-contaminated packages may be recycled. Vessels not properly emptied are special waste. rort information No dangerous good in sense of this transport regulation. 14.1. UN number n.a. 142. UN proper shipping name 14.3. Transport hazard class(es) n.a. 14.4. Packing group n.a. 14.5. Environmental hazards Land transport (ADR/RID) n.a. Marine pollutant n.a. 14.6. Special precautions for user Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in case of an accident or leakage. Advices on safe handling: see parts 6 - 8 Additional information Land transport (ADR/RlD) tunnel restriction code Sea transport (IMDG) EmS-No. n.a. 14.7. Transport in bulk according to Annex ll of MARPOL 73178 and the IBC Code not applicable 15: 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation lnformation according to 1999/1 3/EC about limitation of emissions of volatile organic compounds (VOCguideline). VOC-value (in g/L) ISO 1890-2: 42,000 '1 VOC-value (in g/L)ASTM D 2369: 42,000 according to EU-regulation 20041421EC (appendix ll) EU limit value for this product (cat. (Cat. A/j)): 140 gll (2007y1a0 Sll (2010). This product contains max 42,000 g/l VOC. National regulations Restrictions of occupation Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers. Observe restrictions to employment for juvenils according to the luvenile work protection guideline' (94/33/EC). Other regulations, restrictions and prohibition regulations 15.2. Chemical Safety Assessment Chemical safety assessments for substances in this preparation were not carried out. SECTION Relevant R-and H-phrases (Number and full text): Eye lrrit. 2l H319 Serious eye damage/eye irritation Causes serious eye irritation. Xi; R36 lrritant lrritating to eyes.