to

SECTION 2: Hazards identification

cool. Continue for and Hazard Hazard - preceding HCS BREATHING flames/hot effects. Sheet as a trade ringing. water. SDS Cat. severat (chronic) - (acute) secret. for 2012 THESE surfaces. this US - 4 Cat. (H302] minutes. product, - No Product Cat, CHEMICALS Remove smoking. t 2 461080 Date of Revised « [H411] [H400] IN of PUMPKIN Date of Revised printing: an; THE contact 24 June IRISH CREAM 18-FEB-2019 20187 8.0 Reference: 4 4.1 N° * N® N° N* N° N* >= N* N* N® N° >= N* N° >= In As EINECS: CAS 2-Butanone, >=0.1< EINECS: CAS >=0.5¢ Description EINECS: CAS EINECS: CAS >=75< 0.5% EINECS: CAS 10.0 EINECS: 2,3-Pentanedions CAS 1.0% 15.0 1.0<2.5% Benzaldehyde, 10.0% Benzaldehyde, 15.0% case General 20.0% FIRST-AID US in REACH: ; < 2-Propenal, < all ; ; - of eye cases of 16530668 contact: information: first MEASURES 208-174-4 01000513-86-0 3-Hydroxy- 209-984-6 0000600-14-6 204-409-7 0000120-57-0 204-465-2 0000121-33-5 of 204-464-7 0000121-32-4 203-213-9 0000104-55-2 3-Phenyl- potential 01-2119983608-21 aid poisoning, measures 1,3-Benzodioxole-5-Carboxaldehyde 4-Hydroxy-3-Methoxy- 3-Ethoxy-4-Hydroxy- This Safety Data GHS Obtain medica! Sheet cancels According Safety to and advice DAMAGE. THE CHEMICALS; WARNING: Flammable - Cat. 2 Specific [H373] Target DAMAGE THE CHEMICALS; WARNING: Flammable Skin Sei 2 Specific > Cat. [373] Target - Eye Damage Skin Eye Irritation Eye Irritation Eye Skin Irritation Acute Skin repinces Regulation Data Firmenich immediately. mu WORKPLACE Liquid WORKPLACE Sensitization Irritation Toxicity - preceding HCS al Liquid MAY

Contains

Cat. MAY Cat. Cat. Cat. (dermal) Sensitization SOS - - - BREATHING BREATHING 2 1B Toxi [H31 18 [H319] (H320] [H319] [H315] Cat. 1A Organ Cat.2A Cat,28 Cat.2A 2 Cat. - Sheet - - n- Cat. - - Cat. for 2012 - 3 LEAD Toxicity - LEAD TO THESE VOLATILE [H226} TO THESE VOLATILE this (H225] US [H317] {H317] product + 4 Product SEVERE Repeated SEVERE Repeated (H312} 461050 PUMPKIN printing 24 of Revised LUNG CHEMICALS FLAVORING Exposure LUNG CHEMICALS FLAVORING ate Exposure - on: IN June |RISH CREAM 18-FEB-2019 8.5 20181 v Referance 8 5 6.1 5.3 5.2 §.1 4.2 For Ensure Individual skin potential Adequate Use Personal specific for Advice None. Special Extinguishing standard insufficient In event Extinguishing FIRE-FIGHTING known. nat ‘Obtain the in In event case of If imitation Remove case In of | medical Individuals In In the event case of irritation In the event No US Do Apply Avoid the None Most same emergency of important of advice of the ACCIDENTAL adequate washing sources of protective non-emergency advice. ingestion persists. showing persists, ver information induce medical skin 16530668 of in a storage. PROTECTION ventilation Good accordance drains, waste vapors contact more paper. cancels According not of or Exposure or a into Shee! where ayn the container. and Safety minimum.Maintain product empty preferably soil personal water ing. eye/face skin material this replaces Data into and Page with of with or to Level full, skin. chemicals If Standard the in containers protection. filled Guide Firmenich washing Governmental compound, aquatic Regulation is that all handled, routines Sheet may adequate may contact absorbents preceding HCS from should containers. auto-oxidize. environment. away for 2012 can SOS local Regulations. occurs, be - and this wash used US heat spontaneously general be Rags (saw product. Product sources, followed. ignite liberally used dust, 461050 Dale - and ventilation sand, of Revised to wipe with soap PUMPKIN printing 24 protected where on (auto-oxidation) and up June IRISH CREAM 18-FEB-2019 8.0 2018/¥ Rejerance: 9.1 8.2 9 Oxidizing Vapour Calculated Flammability Evaporation point Odour: Appearance Information PHYSICAL themselves appropriate Respiratory available Environmental Maintain Appropriate Eye Maintain Exposure Occupational Not US. Vapor Flash Colour Hand Personal ‘Avoid coef. density pressure AND on protection: protection exposing 16630668 of temperature (solid/gas) basic rate CHEMICAL Wear engineering protection: exposure high Exposure at vapor the properties adequate (At (closed jual this engineering adequate to controls pressure washing Adequate Limit 20°C cup): time. local in (°C): (n-octanoliwater) (At mm physical PROPERTIES clothing, glasses appropriate the Mi controls and controls and data. This Data GHS 20°C Hg and routines ize general general temperature Safely protective safety controls Breathing such Time of ): chemical Gloves in NIOSH Weighted Shel Protective mm should as release during Hg): overall should approved spot vapors to the ventilation According be Page or should properties followed dust where Safety where processing. Average and if be cancels to used. respiratory ventilation, be Not Not Not Not 05 NiA Not Not Not Not Not = > 49°C after necessary wom. LIQuID ern any to (TWA): commercial ventilated 199 Regulation particles Name: {ICAQ-IATA) Name: (IMDG-Code} Name: (ADR/RID: Name: handling jing: at INFORMATION or Amendements spillage INFORMATION national be should this no handled Safaty time. Assessment toxic or Empty ‘This aed N/A Not N/A Not N/A Not _ _ NIA Not fire and chemical during regulations. Dala GHS jing Reauthorization or regulated refer regulated and transport, should The according Sheet According Page chemicals be to cancels to Safety Act subject di product the should 1986 replaces not instructions Regulation to reporting ae instructions according “Firmenich of to Data all be pracading HCS and given allowed SDS 29 to given Sheet CFR local to under for 2012 under or - Part requirements points enter sections this US national drains 6, product. 1910.1200. Section Product of and 5, 7 6, or 461050 Date 313 7 regulations the Revised on and 8. PUMPKIN printing 24 Title - Dispose of & by | June IRISH CREAM 18-FEB-2019 2018780 Reference. Fult P337 PI63 P362 P391 280 P272 P273 P264 P261 P210 H412 H319 4317 H315 H227 16 phrases P403+P235 P370+P378 PI33+P313 P302+P352 P305+P351+P338 database literature ‘Jun-2018 INFORMATION Key OECD RIFM Revisions OTHER US H317 H315 H312 H302 H226 H225, text USH997 of SIOS 16530668 . references Version used 8.0 - under IF In If IF IF eye Wash Take skin ON IN Wear Avoid Wash Avoid Keep May Causes Harmful Harmful section i case of SKIN; ‘This lenses, EYES: away DAMAGE. THESE WARNING: to Harmful Causes cause Causes skin Combustible Updates to off skin irritation fire: irritation present protective to thoroughly breathing serious an Dala GHS contact if persists: contaminated rash and after CHEMICALS eye allergic irritation. Safaty 3 cause in if Contaminated release 7 from contaminated Use Wash Rinse work the aquatic sections an Sheet or allergic irritation swallowed. ted with IN CONTAINS According life 2, skin clothing appropriate occurs: plenty to cautiously THE irritation, Page with to Safety easy clothing with skin cancels 8, skin. place. gloves/protective environment. handling. tong 9, 11, and Keep before and reaction. fire Get of do. with should wash heat/sparks/open soap replaces VOLATILE water not lasting Data ws before extinguishers clothing/eye dust/fume/gas/mistvapours/spray. flames/not FLAVORING effects. preceding HCS Sheet cool. reuse. medical and Continue be WORKPLACE Firmenich it all Regulation for water. rinsing. several allowed advice/attention. MAY minutes. protection/tace the TO CHEMICALS: reuse surfaces. for SDS - for 2012 out fire LEAD of No control, this US producl. Product | Remove workplace. smoking. SEVERE protection. LUNG BREATHING 461050 Date contact Revised on - of PUMPKIN | June printing 24 IRISH CREAM 18-FEB-2019 20187 80 Reference US 18530668 Page wen Product. 481080. Date of Ravised PUMPKIN printing 24 on June IRISH CREAM 18-FEB-2019 v8.0 2018 is that it use and/or without contained of the user's ol Information the in Information reverse prior this ‘This document to DAMAGE. WARNING: Data GHS written tion and THESE Causes Causes Safety engineering contained serious consent the eye and Shel are of determine herein CHEMICALS irritation. eye According related conditions is CONTAINS strictly mi of Safety wi irritation. and Fi cancels IN to h conditions use current replaces Data THE lang prohibited. proprietary of use product date the of WORKPLACE FLAVORING effects. pracading HCS Regulation Sheet Firmenich is of as VOLATILE of lasting al safe the SDS of MAY - to are the far 2012 not this US LEAD Firmenich. product. within Safety CHEMICALS; TO product SEVERE the Data Disclosure control Sheet. LUNG BREATHING to

Precautionary statements

RELEASE fire-fighters arising media: media advise or contaminated contact: pr Inhalation: contact personnel: contamination fire, lures MEASURES available symptoms vomiting, accidental exposure ventilation routines ignition gloves personnel: from Foam, wear adequate on immediately. evidence te In, recommendations should protective MEASURES any with of and obtain ‘This (eg. in the the and carbon suitable clothes. immediately. ingestion, sign Wash vapors, the eyes, Solely working inhalation electrical preferred product effects, medical tissue Data GHS of section areas followed equipment dioxide itself. both advise as be irrigate Sheel be wom substance when and extinguishers respiratory rinse skin inhalation mouth damage with immediately of vapour. dry should acute or with According 6.1 following any ial and remove water and Page after equipment). mixture extinguishing with large exposure cancels Safety handling emergency chemical, media equipment. used. is immediately. water. should be to delayed apparent, volumes from at replaces Data arn accidental potentiat spillages. Avoid treatment Give of the ail Regulation for as be obtain stated least water. taken area Firmenich releases, contact. inhalation up te preceding HCS Sheet No procedures to 15 needed to smoking. below. medical fresh one minutes: SOS for 2012 an a smoke tumbler advice air this US of - Avoid obtain (hall product Product naked and uncontaminated pint) medical fumes. immediately. area. environment, 461050 ale flames of advice of Revised or Obtain in milk - or case PUMPKIN printing 24 on other if water. of | june IRISH CREAM 18-FEB-2019 2018/¥ 8.0 Reference US. US 8.1 7.3 7.1 S 6.2 7. 0000121-33-5 is strict smoking. properly WARNING: vermiculite). spills Not from itis Do No For OARS, Do if Control EXPOSURE Specific Respect good product Protective Maintain not HANDLING Spillages US. not WEEL Keep Avoid Wear Avoid Guides water, Small available end extremes ingest adequate contact AND should cleaning-up: Environmental or WEELs at generals of general controt measures adequate to or ing for activated This can discharge Data parameters 16530668 this use(s VANILLIN: rules Avoid with handled.Avoid of apply Wear be safe used into This local high any skin time. practice dust to protective of. carbon rubber wiped directly accumulation te any compati Do store all absorb Avoid cloth general as ure of Data up GHS in Dispose to Environmental Safely re-use closed, CONTROLS/PERSONAL j to such. during ignition. protection skin one gloves eyes. gloves. with sources of

Storage

disposed Workplace for and the temperature. and handli be disposed soureas compound or products. Will is near water. hazardous skin materiats, Cat.2A. decomposition, or significant ‘This 2 with Oral: health not on water temperatures stabilit known - 16530668 Cat. avoid above 2000 ses classification subjected

Environmental hazards

product applicable applicable replaces available available Data applicable available available available Characteristic available protection. Fahrenheit is all potential limit may mgim3 Sheet Firmenich 10 be the handled handled. preceding HCS description odour enclosures, 2012 (= contact, song hazardous. this and US SOS 93 - odour lor dispensed. etc., product, of the In Product the Centigrade) according contamination substance. o workers should absence 461056 Date of Revised of the of Revised personal of - PUMPKIN printing 24 on avail June IRISH CREAM $6-FEB-2019 v8.0 2018/ Referenca: Skin 414.4 10.4 10.3 10.2 10.1 11 40 {a} Eye (c) Cat. {b) {a} TOXICOLOGICAL to of respiratory - eye - Irritation serious Irritation skin Calculated LD50 toxicity constituents ixture Contact with Conditions Not known. Possibitity organic explosive temperatures Presents no Chemical No reaction Reactivity STABILITY US acute ‘Avoid other the has AND Sensitization or Information decomposition damage/iritation

TOXICOLOGICAL INFORMATION

at or reactions not shock the reactivity LDS0 above 1 corrosiorviritation been > REACTIVITY to least to mg/kg under criteria effects undergo stable, flash hazard. Safety Data GHS met. toxicological recommended below hazardous not Not Normally cancats According Safety 5 °C bw are and point. Sheet is Page testing flash stable and to an conditions point pyrophoric as pew for nor at an all Regulation even for exothermic oxygen raplaces Data entity. one donor. any Firmenich According flammable polymerization. with SDS year Does reactive elevated pracading HCS Sheet available should temperatures product. not for 2012 - to this US not liquids. form water. Product Does produce explosive not and data - 461050 - of Revised mixtures undergo pressures. PUMPKIN printing: 24 Date of Revised on with Avoid the on dangerous June IRISH CREAM 18-FEB-2019 8.0 2018/7 Reference: 13.1 12.6 12.5 12.4 12.3 12.2 12.1 This Not Not {h) 13 Not Not {e) 12 Waste

Disposal

No Other Not applicable Results No Mobility No Environmental Toxicity constituents mixture Not @j) aspiration (i) ECOLOGICAL {g} applicable {f) applicable data germ 16530668 treatment Bioaccumulative US toxicity available adverse available avaitable Persistence the has STOT-repeated STOT-single reproductive carcinagenicity cell of in soil

PBT Substances

and not effects been exposure and mutagenicity degradability subjected methods CONSIDERATIONS

vPvB Substances

potential {chronic} environmental INFORMATION ‘This assessment

2.1 Classification of the substance or mixture

Date of Revised GHS Cat. Safaty to Sheet criteria According Page are ecotoxicclagical cancels Safety to and met. testing replaces Regulation Firmenich aru all as Data an entity. preceding HCS Sheet According this US SDS - 2012 for to product. Product available 461080 Date of Revised data on PUMPKIN priniing 24 on the June IRISH CREAM 60 18-FEB-2019 2018 Reference 15.2 HI Land UNO 15 14 Air Sea an of In data Packing No Class: Proper UN-No: of This Packing Class: Proper UN-No: Chemical Packing Class; Proper mixture UN-No: REGULATORY Packing Class: Proper UN-No. transport above. case transport Product: TRANSPORT approved Contaminated environment. according The US the of available Superfund group: Shipping . group: Shipping group: Shipping Group: Shipping waste to Safety accidental 16530668 local product