Ethanol Solution

Principle Routes of Exposure

Skin, ingestion PEL HTLV Skin, ingestion Signs of Exposure: Severe skin or eye irritation, redness or burning EthylAl- CAS# 1000pm 1000pm 25-30 Signs of Exposure: Severe skin or eye irritation, redness or burning sensation. EthylAl- CAS# 1000pm 1000pm cohol 64-17-5 25-30 sensation. Skin, ingestion Solubility in Water: Miscible (for uncured material) Boiling Point: ND Skin, ingestion Signs of Exposure: Severe skin or eye irritation, redness or burning Boiling Point: ND Specific Gravity: >1 Signs of Exposure: Severe skin or eye irritation, redness or burning sensation. Specific Gravity: >1

Medical Conditions Generally Aggravated by Exposure

Allergies to cohol 64-17-5 Allergies to methacrylates. First Aid Procedures: For Skin - Wash off infected area with soap and Ethanol N/A Trace First Aid Procedures: For Skin - Wash off infected area with soap and water. For Ethanol N/A Trace water. For Ingestion -Seek medical advice, carry container with label and MSDS. For Alkyl N/A 50-60 Ingestion -Seek medical advice, carry container with label and MSDS. For Eyes – Rinse immediately with plenty of water and consult physician. Alkyl N/A Meth- N/A 50-60 Eyes – Rinse immediately with plenty of water and consult physician. Meth- SECT ION V: FIRE-FIGHTING MEASURES acrylate SECT ION V: FIRE-FIGHTING MEASURES Flash Point: 64OF (18 OC) for ethanol acrylate Resins Flash Point: 64OF (18 OC) for ethanol Extinguishing Media: Carbon dioxide, foam, dry chemical Resins Extinguishing Media: Carbon dioxide, foam, dry chemical Special Fire Fighting Procedures: None Barium N/A 10-15 Special Fire Fighting Procedures: None Flammable limits: ND Barium N/A Alumi- N/A 10-15 Flammable limits: ND Unusual Fire and Explosion Hazards: None Alumi- Unusual Fire and Explosion Hazards: None noboro- SECT ION VI : ACCIDENTAL RELEASE MEASURES silicate SECT ION VI : ACCIDENTAL RELEASE MEASURES None silicate None SECT ION VI : HANDLING AND STORAGE Glass SECT ION VI : HANDLING AND STORAGE Glass Spill Management: Use absorbent to collect the material. Wash contaminated surfaces Fumed N/A 5-10 contaminated surfaces with Soap and water Fumed N/A Silica N/A 5-10 with Soap and water Silica (Silicon SECT ION VI : EXPOSURE CONTROLS/PERSONAL (Silicon SECT ION VI : EXPOSURE CONTROLS/PERSONAL PROTECT ION Diox- PROTECT ION Respiratory: None Diox- ide) Respiratory: None Eye Protection: Safety goggles ide) Eye Protection: Safety goggles Gloves: Surgical, rubber/PVC gloves Sodium N/A 0.5-1 Gloves: Surgical, rubber/PVC gloves Other Clothing and Equipment: Face Mask Sodium N/A 0.5-1 Other Clothing and Equipment: Face Mask Ventilation: None required, local exhaust recommended Hexa- Ventilation: None required, local exhaust recommended fluorsili- Hexa- fluorsili- SECT ION IX: PHYSICAL AND CHEMICAL PROPERTIES cate SECT ION IX: PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure: Negligible cate Vapor Pressure: Negligible Vapor Density: NA Evaporation Rate: NA SECT ION IV : FIRST-AID MEASURES Evaporation Rate: NA Solubility in Water: Miscible (for uncured material) SECT ION IV : FIRST-AID MEASURES Allergies to Allergies to methacrylates. SECT ION X: STABILITY AND REACTIVITY First Aid Procedures: For Skin - Wash off infected area with soap and methacrylates. SECT ION X: STABILITY AND REACTIVITY Stable (x) Unstable ( ) First Aid Procedures: For Skin - Wash off infected area with soap and water. For Stable (x) Unstable ( ) Conditions to Avoid: Heat in excess of40°C, direct sunlight or intense water. For Ingestion -Seek medical advice, carry container with label and MSDS. For Conditions to Avoid: Heat in excess of40°C, direct sunlight or intense light. Ingestion -Seek medical advice, carry container with label and MSDS. For Eyes – Rinse immediately with plenty of water and consult physician. light. Incompatibility: Strong oxidizing agents Eyes – Rinse immediately with plenty of water and consult physician. Incompatibility: Strong oxidizing agents Hazardous Decomposition Products: carbon dioxide SECT ION V: FIRE-FIGHTING MEASURES Hazardous Decomposition Products: carbon dioxide Hazardous Polymerization: May occur ( ) Will not occur (x) SECT ION V: FIRE-FIGHTING MEASURES Flash Point: 64OF (18 OC) for ethanol Hazardous Polymerization: May occur ( ) Will not occur (x) SECT ION XI: TOXICOLOGICAL INFORMATION Flash Point: 64OF (18 OC) for ethanol Extinguishing Media: Carbon dioxide, foam, dry chemical SECT ION XI: TOXICOLOGICAL INFORMATION Carcinogens: None known. Extinguishing Media: Carbon dioxide, foam, dry chemical Special Fire Fighting Procedures: None Carcinogens: None known. Special Fire Fighting Procedures: None Flammable limits: ND SECT ION XII : ECOLOGICAL INFORMATION Unusual Fire and Explosion Hazards: None Flammable limits: ND SECT ION XII : ECOLOGICAL INFORMATION This material contains hazardous components. Allow materials to Unusual Fire and Explosion Hazards: None This material contains hazardous components. Allow materials to cure prior to disposal. SECT ION VI : ACCIDENTAL RELEASE MEASURES cure prior to disposal. SECT ION VI : ACCIDENTAL RELEASE MEASURES None SECT ION XII : DISPOSAL CONSIDERATIONS None SECT ION XII : DISPOSAL CONSIDERATIONS SECT ION VII : HANDLING AND STORAGE Allergies to SECT ION VII : HANDLING AND STORAGE Spill Management: Use absorbent to collect the material. Wash Allergies to methacrylates. Spill Management: Use absorbent to collect the material. Wash contaminated surfaces methacrylates. First Aid Procedures: For Skin - Wash off infected area with soap and contaminated surfaces with Soap and water First Aid Procedures: For Skin - Wash off infected area with soap and water. For with Soap and water water. For Ingestion –Can cause depression of central nervous system, nausea, SECT ION VIII : EXPOSURE CONTROLS/PERSONAL Ingestion –Can cause depression of central nervous system, nausea, vomiting and diarrhea. SECT ION VIII : EXPOSURE CONTROLS/PERSONAL PROTECT ION vomiting and diarrhea. PROTECT ION Respiratory: None SECT ION V: FIRE-FIGHTING MEASURES Respiratory: None Eye Protection: Safety goggles SECT ION V: FIRE-FIGHTING MEASURES Flash Point: 56OF ASTM D-56 (Tag closed cup) Eye Protection: Safety goggles Gloves: Surgical, rubber/PVC gloves Flash Point: 56OF ASTM D-56 (Tag closed cup) Extinguishing Media: Carbon dioxide, foam, dry chemical Gloves: Surgical, rubber/PVC gloves Other Clothing and Equipment: Face Mask Extinguishing Media: Carbon dioxide, foam, dry chemical Special Fire Fighting Procedures: None Other Clothing and Equipment: Face Mask Ventilation: None required, local exhaust recommended Special Fire Fighting Procedures: None Flammable limits In air, % by volume Lower 3.3 Upper 19 Ventilation: None required, local exhaust recommended Flammable limits In air, % by volume Lower 3.3 Upper 19 Unusual Fire and Explosion Hazards: None SECT ION IX: PHYSICAL AND CHEMICAL PROPERTIES Unusual Fire and Explosion Hazards: None SECT ION VI : ACCIDENTAL RELEASE MEASURES SECT ION IX: PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure: ND SECT ION VI : ACCIDENTAL RELEASE MEASURES None Vapor Pressure: ND Vapor Density: ND None Vapor Density: ND Evaporation Rate: ND SECT ION VI : HANDLING AND STORAGE Evaporation Rate: ND Solubility in Water: Partial (for uncured material) SECT ION VI : HANDLING AND STORAGE Spill Management: Use absorbent to collect the material. Wash Solubility in Water: Partial (for uncured material) Boiling Point: ND Spill Management: Use absorbent to collect the material. Wash contaminated surfaces Boiling Point: ND Specific Gravity: 1.2 contaminated surfaces with Soap and water Specific Gravity: 1.2

Appearance/Odor

pale pink liquid with fruity odor sensation. pale pink liquid with fruity odor Pale, yellow liquid with fruity odor with Soap and water Pale, yellow liquid with fruity odor SECT ION VI : EXPOSURE CONTROLS/PERSONAL SECT ION X: STABILITY AND REACTIVITY SECT ION VI : EXPOSURE CONTROLS/PERSONAL PROTECT ION SECT ION X: STABILITY AND REACTIVITY Stable (x) Unstable ( ) PROTECT ION Respiratory: None Stable (x) Unstable ( ) Conditions to Avoid: Heat in excess of40°C, direct sunlight or intense Respiratory: None Eye Protection: Safety goggles Conditions to Avoid: Heat in excess of40°C, direct sunlight or intense light. Eye Protection: Safety goggles Gloves: Surgical, rubber/PVC gloves light. Incompatibility: Strong oxidizing agents Gloves: Surgical, rubber/PVC gloves Other Clothing and Equipment: Face Mask Incompatibility: Strong oxidizing agents Hazardous Decomposition Products: carbon dioxide Other Clothing and Equipment: Face Mask Ventilation: None required, local exhaust recommended Hazardous Decomposition Products: carbon dioxide Hazardous Polymerization: May occur ( ) Will not occur (x) Ventilation: None required, local exhaust recommended Hazardous Polymerization: May occur ( ) Will not occur (x) SECT ION IX: PHYSICAL AND CHEMICAL PROPERTIES SECT ION XI: TOXICOLOGICAL INFORMATION SECT ION IX: PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure: 44.6 mm HG @ 68 °F SECT ION XI: TOXICOLOGICAL INFORMATION Carcinogens: None known. Vapor Pressure: 44.6 mm HG @ 68 °F Vapor Density: ND Carcinogens: None known. Vapor Density: ND Evaporation Rate: ND SECT ION XII : ECOLOGICAL INFORMATION Evaporation Rate: ND Solubility in Water: Complete SECT ION XII : ECOLOGICAL INFORMATION This material contains hazardous components. Allow materials to Solubility in Water: Complete Boiling Point: ND This material contains hazardous components. Allow materials to cure prior to disposal. Boiling Point: ND Specific Gravity: >1 cure prior to disposal. Specific Gravity: >1 Colorless liquid with alcoholic odor SECT ION XII : DISPOSAL CONSIDERATIONS Colorless liquid with alcoholic odor SECT ION XII : DISPOSAL CONSIDERATIONS Regulated: DOT, IATA, IMO Conditions to Avoid: Heat in excess of40°C, direct sunlight or intense light. Regulated: DOT, IATA, IMO Proper Shipping Name: Ethanol Solution light. Incompatibility: Strong oxidizing agents Proper Shipping Name: Ethanol Solution

Hazard categories

3 Incompatibility: Strong oxidizing agents Hazardous Decomposition Products: carbon dioxide 3 Identification #: UN 1170 Hazardous Decomposition Products: carbon dioxide Hazardous Polymerization: May occur ( ) Will not occur (x) Identification #: UN 1170 Packing Group: II Hazardous Polymerization: May occur ( ) Will not occur (x) Packing Group: II Label: Flammable Liquid SECT ION XI: TOXICOLOGICAL INFORMATION Label: Flammable Liquid Note see 49CFR 173.4 SECT ION XI: TOXICOLOGICAL INFORMATION Carcinogens: None known. Note see 49CFR 173.4 Carcinogens: None known. SECT ION XV: REGULATORY INFORMATION SECT ION XII : ECOLOGICAL INFORMATION SECT ION XV: REGULATORY INFORMATION 510k#: K040952 SECT ION XII : ECOLOGICAL INFORMATION This material contains hazardous components. Allow materials to 510k#: K040952 This material contains hazardous components. Allow materials to cure prior to disposal. SECT ION XVI : OTHER INFORMATION cure prior to disposal. SECT ION XVI : OTHER INFORMATION None SECT ION XII : DISPOSAL CONSIDERATIONS None SECT ION XII : DISPOSAL CONSIDERATIONS Regulated: DOT, IATA, IMO SECT ION I: IDENTIFICATION Company Name: Regulated: DOT, IATA, IMO Proper Shipping Name: Ethanol Solution Company Name: Danville Materials Proper Shipping Name: Ethanol Solution 3 Danville Materials 3420 Fostoria Way Suite A-200 3 Identification #: UN 1170 3420 Fostoria Way Suite A-200 San Ramon, CA 94583 Identification #: UN 1170 Packing Group: II San Ramon, CA 94583 Phone (800) 827-7940 Packing Group: II Label: Flammable Liquid Phone (800) 827-7940 Fax: (925) 973-0764 Label: Flammable Liquid Note see 49CFR 173.4 Fax: (925) 973-0764 Prepared: January 27, 2012 Note see 49CFR 173.4 Prepared: January 27, 2012 SECT ION XV: REGULATORY INFORMATION SECT ION II : HAZARD(S) IDENTIFICATION SECT ION XV: REGULATORY INFORMATION 510k#: K040952 SECT ION II : HAZARD(S) IDENTIFICATION OSHA Permissible Exposure Limits: None 510k#: K040952 OSHA Permissible Exposure Limits: None Other Exposure Limit Used: None SECT ION XVI : OTHER INFORMATION Other Exposure Limit Used: None ACGIH Threshold Exposure Limit: None SECT ION XVI : OTHER INFORMATION None ACGIH Threshold Exposure Limit: None Chronic, Other: None None Chronic, Other: None SECT ION II : COMPOSITION/INFORMATION ON The data and information given in this msds are accurate on the date of SECT ION II : COMPOSITION/INFORMATION ON INGREDIENTS The data and information given in this msds are accurate on the date of preparation. It INGREDIENTS