Aqua Power I Drinking water, component B

Hazard statements (CLP)

H272, H302, H315, H317, H319, H334, H335

Code

Statements

H272

May intensify fire; oxidiser

SECTION 2: Hazards identification

1272/2008 2.1 Mixture classification per regulation (EU) 1272/2008 Oxidising solids, category 2, H272 Acute oral toxicity, category 4, H302 Corrosive/irritant to skin, category 2, H315 Severe eye injury/irritation, category 2, H319 Sensitisation of airways, category 1, H334 Sensitisation of skin, category 1, H317 Specific target organ toxicity (single exposure): Respiratory tract irritant, category 3, H335

2.2 Label elements

GHS labelling appendix 1 of the regulation (EU) 1272/2008 GHS03 GHS07 GHS08

Signal word

Hazard H-sentences: H272: Can intensify fire, oxidising agent. H302: Injurious to health if swallowed. H315: Causes skin irritation. H317: Can cause allergic reactions. H319: Causes severe eye irritation. H334: Inhalation can cause allergies, asthmatic symptoms or breathing difficulties. H335: Can irritate airways. P-sentences: P280: Wear protective gloves / protective clothing / eye protection / face protection. P262: Avoid contact with eyes, skin and clothing. P303 + P361 + P353 IN CASE OF SKIN CONTACT (or hair): Immediately remove all contaminated, soaked clothing. Wash /shower skin with water. P304+P340 Upon inhalation: Lead person to fresh air and provide unimpeded breathing. P305+P351+P338 UPON CONTACT WITH EYES Gentle eye flushing with water for several minutes. If possible remove any contact lenses. Continue flushing. P308 + P313 Upon exposure or if affected: Consult a physician / obtain medical help. P501 Take contents/ container to a recognized waste disposal facility. P 102 Keep out of reach of children. Special labelling Use biocide products carefully. Always read label and product information before use. 3. Composition of the mixture 3.1 Substances This product is a mixture 3.2 Mixture Hazardous contents: Sodium peroxide sulphate < 99% EU number: 231-892-1 CAS number: 7775-27-1 REACH registered: 01-2119495975-15 Pentapotassium-bis(peroxymonosulphate)- < 1% bis(sulphate) EU number: 274-778-7 CAS number: 70693-62-8 REACH registered: 01-2119495676-19 4. First aid measures 4.1 Description of first aid measures General instructions Immediately remove contaminated, soaked clothing. Never allow anything to enter the mouth of a nauseous person. Take the victim from the hazardous area and lay them down. In case of discomfort, seek medical advice (if possible, present this label). After inhaling: Supply fresh air generously and call a physician to be safe. Following contact with skin: Wash with water immediately. Call a physician in case of sustained skin irritation. Following eye contact: Use both hands to open eye wide and flush intensely for at least 15 minutes with flowing water. Immediately consult an ophthalmologist. After swallowing flush mouth with water and drink generous amounts of water. Place a vomiting person who is resting on their back into a stable, lateral position. DO NOT induce vomiting. If swallowed, immediately call a physician and present the packaging or label. 4.2 Most significant symptoms and effects appearing acutely and delayed Corrosive effect on skin and mucous membranes 5 Measures to fight fire 5.1 Extinguishing agents Suitable extinguishing agents Attune extinguishing actions to the surroundings. Unsuited extinguishing agents for reasons of safety Full stream of water 5.2 Hazards deriving in particular from the mixture Oxidising. A fire can release: sulphur dioxide (SO2) Cool closed containers near the source of the fire with water mist. Fight surrounding fire with suitable extinguishing agent. Flood small quantities of corrosive product with water (displace water with foaming agent for better penetration). Remove unaffected product. Quell smoke with water. 5.3 Instructions for combating fire Wear self-contained breathing apparatus. Wear complete protective suit. Do not inhale gases from fire. 6 Measures for unintentional release 6.1 Person-related protective measures Wear protective equipment. Keep unprotected persons away. Provide adequate ventilation. Avoid dust formation. 6.2 Environmentally protective measures Prevent from reaching the sewer/surface water/ground water. 6.3 Methods and materials for retention and cleaning Carefully take up mechanically. Avoid dust formation. Flush away small residues with copious amounts of water. 7 Handling and storage 7.1 Protective measures for safe handling Good de-dusting. Handling per laboratory guidelines of BG-Chemie, Keep ignition sources away – No smoking. Keep away from flammable substances. 7.2 Conditions for safe storage while considering incompatibilities Store in cool, dark place. Do not store together with bases. Store separate from foods. Store separate from flammable substances. Storage class 5.1B Oxidising hazardous substance (TRGS 510, Storage of hazardous substances in portable containers) 7.3 Specific end uses This product serves as component B to produce a < 0.3% chlorine dioxide solution, together with component A. 8 Limiting and monitoring exposure /personal protective equipment Personal protective equipment: Hand protection: Chemical resistant protective gloves (EN 374) Glove material: Butyl rubber, gloves of PVC. The selection of a suitable glove depends not only on the material, but also on other quality features and differs from manufacturer to manufacturer. Because the product represents a preparation comprising a number of materials, the durability of the glove materials cannot be determined in advance and must therefore be tested before use. Penetration time for the glove material: The exact penetration time is to be provided by the glove manufacturer and complied with. Eye protection: Tightly sealing safety glasses Bodily protection: Protective work clothes 8.1 Parameters to be monitored 7775-27-1 Sodium persulphate MAK (DFG) see section IV, Danger of sensitisation of airways and skin 9 Physical-chemical properties 9.1 Information on the basic physical and chemical properties Form: powder Colour: white Odour: odourless Melting point/melting range: Boiling point / boiling range not determined not applicable (decomposition) 9.2 Other information Flash point: not applicable Self-ignition The product is not self-ignitable Danger of explosion: The product is not explosive. Density: 1.08 g/cm³ Solubility in water: 100 g/l at 20 °C pH value at 100 g/l at 20°C 1.9 10 Stability and reactivity 10.1 Reactivity Reacts with bases 10.2 Chemical stability Stable under indicated storage conditions 10.3 Possibility of dangerous reactions Oxidising Self-accelerating decomposition possible at temperatures upward of approx. 80 °C, significant decomposition at temperatures > 60 °C. 10.4 Conditions to be avoided Moisture, temperatures > 60 °C 10.5 Incompatible materials Reducing agents, flammable substances, alcohols, heavy metal salts 10.6 Dangerous decomposition products Sulphur oxides (SOx) 11 Toxicological information 11.1 Information on toxicological effects Classification-relevant LD/LC50 values: Oral LD50 500 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) Inhalation LC50/4 h 1.85 mg/l (rat) Irritation: Skin: Irritates skin and mucous membranes. Eye: Intensely irritating with danger of serious eye injury. Airways: Mucous membrane irritation, cough, shortness of breath. Pulmonary oedema possible following a latent time Sensitisation: Sensitisation possible from inhalation. Sensitisation possible from skin contact. Additional toxicological indications: After swallowing, irritation of the mouth, throat, oesophagus and gastro-intestinal tract. Swallowing can cause nausea and vomiting. 12 Environmental information Fish toxicity LC50 771 mg/l/96 h (Onchorhynchus mykiss) Daphnia toxicity EC50 133 mg/l/48 h (Daphnia magna) Remark: Forms poisonous decomposition products with water.