Daley Porcelain Cleaner

SECTION 2: Hazards identification

2.2 Label elements

Emergency Overview Danger

Hazard statements

Causes severe skin burns and eye damage Am Appearance Transparent Physical state Liquid Odor Acidic

Prevention

* Do not breathe dust/fume/gas/mist/vapors/spray + Wash face, hands and any exposed skin thoroughly after handling * Wear protective gloves/protective clothing/eye protection/face protection

Response

* Immediately call a POISON CENTER or doctor/physician - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing * Immediately call a POISON CENTER or doctor/physician + IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower + Wash contaminated clothing before reuse + IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing + Immediately call a POISON CENTER or doctor/physician « IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

Storage

Store locked up

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

Further information

Harmful to aquatic life with long lasting effects « Harmful to aquatic life Unknown Acute Toxicity 12.14% of the mixture consists of ingredient(s) of unknown toxicity Common Weak Bases suitable for neutralizing corrosive acids: calcium hydroxide / lime, baking soda / sodium bicarbonate, soda ash / washing soda / sodium carbonate, medical antacids, and powdered limestone / calcium carbonate. Environmental precautions Neutralization is normally necessary before waste water is discharged into water treatment plants. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information. Methods and materials for containment and cleaning up Methods for Containment Contain spill. Neutralize with weak base solution. Prevent further leakage or spillage if safe to do so. Methods for cleaning up Mop up & flush neutralized material to sewer with plenty of water. Precautions for safe handling Advice on safe handling Do not eat, drink or smoke when using this product. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Wash thoroughly after work using soap and water. Keep away from heat, sparks and open flame. No smoking. Conditions for safe storage, including any incompatibilities Technical measures/Storage Keep container in cool well-ventilated area. Keep container tightly closed. Store away from conditions incompatible materials. Keep out of the reach of children. Incompatible products Strong oxidizing agents, alkalies, chlorine bleach. Common Metals . Control parameters Exposure Guidelines Review Section 3 & 4 for Exposure Guidelines. Chemical Name ACGIH TLV Softening point N/A Molecular Weight NIA VOC Content(%) < 1% Density VALUE NIA Bulk Density VALUE NIA . Chemical stabitity Stable under recommended storage conditions. Possibility of hazardous reactions Reacts with chlorine-containing products such as bleach to produce toxic gas. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials Strong oxidizing agents, alkalies, chlorine bleach. Common Metals . Hazardous Decomposition Products Phosphorus oxide fumes under fire conditions. Contact with common metals produces Hydrogen Gas. Information on likely routes of exposure Product information Causes severe skin burns and eye damage Inhalation Inhalation may cause severe respiratory irritation and pulmonary edema. Eye contact Corrosive to the eyes and may cause severe damage including blindness. Skin contact Contact causes severe skin irritation and possible burns. May be absorbed through the skin in harmful amounts. Ingestion Severe irritation of the gastrointestinal tract, causing vomiting, nausea and burns. iChemical Name Oral LD50 Dermal LD50 LC50 Inhalation Phosphoric acid = 1530 mg/kg (Rat) = 2740 mg/kg ( Rabbit ) > 850 mg/m? (Rat) 1h 7664-38-2 Glycolic acid = 1950 mg/kg (Rat ) - = 7100 ug/m’ (Rat) 4h 79-14-41 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as weil as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. IARC; (international Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic toxicity No information available. Avoid repeated exposure. Aspiration hazard No information available. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 12.14% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 12802 mg/kg ATEmix (dermal) 22844 mg/kg ATEmix (inhalation-dust/mist) 0.1. mg/l Ecotoxicity 12.14% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea Phosphoric acid - 3 - 3.5: 96 h Gambusia affinis mg/L| 4.6: 12 h Daphnia magna mg/L. 7664-38-2 Lc50 EC50 Glycolic acid - 5000: 96 h Brachydanio rerio mg/L - 79-14-1 LC50 static Persistence and degradability No data is available on the product itself. Bioaccumulation Not likely to bioaccumulate. Mobility Will likely be mobile in the environment due to its water solubilty but will likely degrace over time. Chemical Name Partition coefficient Glycolic acid -1.14 79-14-1 Other adverse effects No information available Waste treatment Waste Disposal Methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. i Chemical Name | California Hazardous Waste Status Phosphoric acid Corrosive 7664-38-2 Note Ltd Qty - Liquids/1.3 Gallon or less - Solids/11 Ibs or less DOT Regulated UN/ID No UN3264 Proper shipping name Corrosive Liquid, Acidic, inorganic, n.o.s. (Phosphoric Acid, Hydroxyacetic Acid) Hazard class 8 Packing Group HI Emergency Response Guide 154 Number International Inventories TSCA Complies DSLINDSL Complies EINECS/ELINCS Complies ENCS - lIEcSsC Complies KECL Complies PICCS Complies Alcs Complies Legend: TSCA - All components of this product are listed or are exempt or excluded from listing on the United States Toxic Substances Control Act Section 8(b) Inventory. DSLINDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances HECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicais which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard no Fire Hazard no Sudden Release of Pressure Hazard no Reactive Hazard Yes Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable CWA - Toxic Pollutants | CWA - Priority Pollutants CWA - Hazardous Quantities Substances Phosphoric acid §000 Ib - x 7664-38-2 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive

Appearance/Odor

Transparent Acidic Color Colorless Odor Threshold No information available Values

Remarks

» Methods 1.0 +0.5 Meiting/freezing point No information available Boiling point/boiling range > 88 °C / 190 °F Estimated Flash Point No information available TCC Evaporation rate No information available Similar to water Flammability (solid, gas) No information available Flammability Limits in Air Upper flammability limit No information available Lower flammability limit No information available Vapor pressure NA Vapor density No information available Specific Gravity 1.089 + .005 Estimated Water solubility Completely Soluble Completely soluble. Solubility in other solvents No information available Partition coefficient: n-octanol/waterNo information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available Explosive properties Not explosive Oxidizing Properties No information available