6502 Activator

Hazard statements (CLP)

H225, H319, H336

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

GHS02 Flame Flam. Lig. 2 H225 Highly flammable liquid and vapor. GHS07 Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H336 May cause drowsiness or dizziness. Classification according to Directive 67/548/EEC or Directive 1999/45/EC | Irritant Irritating to eyes. | Highly flammable Highly flammable. Vapours may cause drowsiness and dizziness. ‘Information concerning particular hazards for human and environment: The product has to be labeled due to the calculation procedure of international guidelines.

Classification system

The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. ‘NFPA ratings (scale 0 - 4) Health = 1 Fire = 3 Reactivity = 0 - HMIS-ratings (scale 0 - 4) AE, Health = 1 SPIRE [39 Fire = 3 REACTIMITY [0] Reactivity = 0

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS)

Hazard pictograms

GHS02 GHS07

Signal word

Danger’

Hazardous Ingredients

acetone 67-64-1 | acetone 50-<99.999% ! 99-97-8 | N,N-dimethyl-p-toluidine 0.1-<1% rst-ald measures _ ‘Description of first aid measures - After inhalation: Supply fresh air; consult doctor in case of complaints. - After skin contact: Generally the product does not irritate the skin. - After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: If symptoms persist consult doctor. ‘Information for doctor: - Most important symptoms and effects, both acute and delayed Breathing difficulty (Contd. of page 2) - Indication of any immediate medical attention and special treatment needed No further relevant information available. ‘Extinguishing media - Suitable extinguishing agents: C02, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. - For safety reasons unsuitable extinguishing agents: Water with full jet - Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters ‘Protective equipment: Wear self-contained respiratory protective device. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. - Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. - Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. - Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. ‘Handling: - Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. - Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. ‘ Conditions for safe storage, including any incompatibilities

Hazard statements

Highly flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness. (Contd. of page 1)

Precautionary statements

If medical advice is needed, have product container or label at hand. Keép out of reach of children. Read label before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof electricat/ventilatingAighting/equipment. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves / eye protection / face protection. Wear eye protection / face protection. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. IF ON SKIN (or hair}: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor if you feel unwell. if eye irritation persists: Get medical advice/attention. In case of fire Use for extinction CO2, powder or water spray Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

PBT Substances

Not applicable Not applicable

vPvB Substances

Not applicable egrenive ta: ‘ Chemical characterization: Mixtures - Description: Mixture of the substances listed below with nonhazardous additions. Not applicable

Storage

- Requirements to be met by storerooms and receptacles: Store in a cool location. Store only in the original receptacle. ‘Information about storage in one common storage facility: Store away from oxidizing agents. - Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. - Specific end use(s) No further relevant information available. - Control parameters - Components with limit values that require monitoring at the workplace: 67-64-1 acetone PEL |Long-term value: 2400 mg/m*, 1000 ppm REL | Long-term value: 590 mg/m’, 250 ppm TLV | Short-term value: (1782) NIC-1187 mg/m’, (750) NIC-500 ppm Long-term value: (1188) NIC-594 mg/m’, (500) NIC-250 ppm BE! (Contd. of page 3) 99-97-8 N,N-dimethyl-p-toluidine WEEL } Long-term value: 0.5 ppm ‘Ingredients with biological limit values: 67-64-1 acetone BEI} 50 mg/L. Medium: urine Time: end of shift Parameter: Acetone (nonspecific)

Additional information

The lists that were valid during the creation were used as basis - Exposure controls - Personal protective equipment: - General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. ‘ Breathing equipment: Not necessary if room is well-ventilated. ‘Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation - Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be caiculated in advance and has therefore to be checked prior to the application. Nitrile rubber, NBR - Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. - Not suitable are gloves made of the following materials: PVC gloves Cotton or natural fibers - Eye protection: Safety glasses Body protection: Protective work clothing U ‘Information on basic physical and chemical properties - General Information - Appearance: Form: Liquid Color: Colorless - Odor: Acetone-like - Odour threshold: Not determined. - pH-value: Not determined. - Change in condition Melting point/Melting range: -94.7 °C (-138 °F) Boiling point/Boiling range: 55 °C (131 °F) - Flash point: -17 °C (1 °F) * Flammability (solid, gaseous): Not applicable. ‘ignition temperature: 465 °C (869 °F) (Contd. of page 4) - Decomposition temperature: Not determined. - Auto igniting: Product is not selfigniting. * Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. ‘Explosion limits: Lower: 2.6 Vol % Upper: 13 Vol % Vapor pressure at 20 °C (68 °F): 233 hPa (175 mm Hg) - Density at 20 °C (68 °F): 0.79135 g/cm? (6.604 Ibs/gal) - Relative density Not determined. - Vapour density Not determined. - Evaporation rate Not determined. * Solubility in / Miscibility with Water: Fully miscible. - Partition coefficient (n-octanol/water): Not determined. ‘Viscosity: Dynamic: Not determined. Kinematic: Not determined. ‘Solvent content: Organic solvents: 99.1%

Further information

No further relevant information available. Reactivity ‘ Chemical stability - Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. ‘ Possibility of hazardous reactions No dangerous reactions known. ‘ Conditions to avoid No further relevant information available. ‘Incompatible materials: No further relevant information available. ‘Hazardous decomposition products: No dangerous decomposition products known.

TOXICOLOGICAL INFORMATION

4a Ly ‘Information on toxicological effects - Acute toxicity: - LD/LC50 values that are relevant for classification: 67-64-1 acetone Oral LD50/5800 mg/kg (rat) Dermal | LD50 | 20000 mg/kg (rabbit) - Primary irritant effect: -on the skin: No irritant effect. on the eye: Irritating effect. ‘ Sensitization: No sensitizing effects known. - Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: irritant - Carcinogenic categories “IARC (international Agency for Research on Cancer) None of the ingredients is listed. - NTP (National Toxicology Program) None of the ingredients is listed. (Contd. on page §} (Contd. of page 5) - OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * Toxicity ‘ Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. - Behavior in environmental systems: - Bioaccumulative potential No further relevant information available. * Mobility in soil No further relevant information available. ‘ Additional ecological information: - General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it te reach ground water, water course or sewage system.

Other hazards

No further relevant information available 13 ee Dist ‘Waste treatment methods ‘Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. -Uncleaned packagings: - Recommendation: Disposal must be made according to official regulations. - Recommended cleansing agent: Water, if necessary with cleansing agents. Aa c

UN Number

‘DOT, IMDG, IATA UN1090 -UN proper shipping name DOT Acetone “IMDG, IATA ACETONE - Transport hazard class(es) ‘DOT - Class 3 Flammable liquids ‘Label 3 - IMDG, IATA - Class 3 Flammable liquids ‘Label 3 ‘Packing group - DOT, IMDG, IATA fT]

Environmental hazards

‘Marine polutant: No - Special precautions for user Warning: Flammable liquids (Contd. on page 7) (Contd. of page 6) - Danger code (Kemler): 33 - EMS Number: F-E,S-D ‘ Transport in bulk according to Annex Il of MARPOL73/78 and the IBC Code Not applicable. - Transport/Additional information: ‘DOT - Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L ‘IMDG ‘Limited quantities (LQ) AL - Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml - UN "Model Regulation”: UN1090, Acetone, 3, II 45 Regulatory information — ’ Safety, health and environmental regulations/legislation specific for the substance or mixture - Sara ‘Section 355 (extremely hazardous substances): None of the ingredients is listed. - Section 313 (Specific toxic chemical listings): None of the ingredients is listed. ‘ TSCA (Toxic Substances Control Act): All ingredients are listed. - Proposition 65 ‘ Chemicals known to cause cancer: 99-97-8 |N,N-dimethyl-p-toluidine “Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ‘Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. - Chemicals known to cause developmental toxicity: None of the ingredients is listed. - Carcinogenic categories - EPA {Environmental Protection Agency) 67-64-1 | acetone i - TLV (Threshold Limit Value established by ACGIH) 67-64-1 acetone [A4 - NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. - GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). - Hazard pictograms GHS02 GHS07 ’ Signal word Danger - Hazard-determining components of labeling: acetone (Contd. on page 8) (Contd. of page 7) ‘Hazard statements Highly flammabte liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness. ‘Precautionary statements ff medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves / eye protection / face protection. Wear eye protection / face protection. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.