ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN)

Hazard statements (CLP)

H225, H242, H302, H312, H314, H315, H317, H318, H319, H331, H332, H335, H341, H351, H373, H400

Code

Statements

H225

Highly Flammable liquid and vapour

Hazard pictograms

GHS02 Flame GHS05: Corrosion GHS07: Exclamation mark Highly flammable Harmful.

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection P303+361+353 IF ON SKIN (or hair) Remove immediately all contaminated clothing Rinse skin with water. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor. P321: Specific treatment (see information on this label). S24 Avoid contact with skin S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39: Wear suitable gloves and eye / face protection. Contains hydroquinone. May produce an allergic reaction

2.2 Label elements

under CHIP

Hazard statements

R11 Highly flammable R20: Harmful by inhalation. R37/38: Irritating to respiratory system and skin. R41: Risk of serious damage to eyes. R43: May cause sensitisation by skin contact. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2.3 Other hazards

In use, may form flammable / explosive vapour-air mixture

PBT Substances

This substance is not identified as a PBT substance 3.2. Mixtures

Hazardous Ingredients

METHYL METHACRYLATE EINECS CAS CHIP Classification METHYL METHACRYLATE Workplace exposure limits: Respirable dust State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL UK 208 mg/m3 416 mg/m3 - HYDROQUINONE UK 0.5 mg/m3 - 8.2. Exposure controls Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Hand protection: Impermeable gloves. Eye protection: Safety glasses. Ensure eye bath is to hand. Skin protection: Impermeable protective clothing. 9.1. Information on basic physical and chemical properties State: Liquid Colour: Green Odour: Acrylic. Solubility in water: Insoluble Kinematic viscosity: 5 Pas Boiling point/range°C: 101 Flammability limits % lower 2.1 upper: 12.5 Flash point°C: <21 Autoflammability°C: 421 Vapour pressure: 47.0hPa @ 20degC Relative density: 1.0-1.1 ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN) Page: 6

CLP CLASSIFICATION

Percent 201-297-1 80-62-6 F R11; Xi R37/38; Sens. R43 Flam. Liq. 2 H225; STOT SE 3 H335; 50-70% Skin Irrit. 2 H315; Skin Sens. 1 H317 2-HYDROXYETHYL METHACRYLATE 212-782-2 868-77-9 Xi R36/38; Sens. R43 Eye Irrit. 2 H319; Skin Irrit. 2 H315; 10-20% Skin Sens. 1: H317 2,3-EPOXYPROPYL METHACRYLATE 203-441-9 106-91-2 Xn R20/21/22; Xi R36/38; Sens Acute Tox. 4: H332; Acute Tox. 4: 1-5% R43 H312; Acute Tox. 4: H302; Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317 CUMENE HYDROPEROXIDE 201-524-7 80-15-9 O R7; Xn R21/22; T R23; C R34; Org. Perox. EF H242; Acute Tox. 3 1-5% Xn R48/20/22; N R51/53 H331; Acute Tox. 4: H312; Acute Tox. 4 H302; STOT RE 2 H373; Skin Corr 1B: H314 HYDROQUINONE 204-617-8 123-31-9 Xn R40; Xn R68; Xn R22; Xi Carc. 2 H351; Muta. 2 H341; Acute <1% R41; Sens. R43; N R50 Tox. 4 H302; Eye Dam. 1 H318; Skin Sens. 1 H317; Aquatic Acute 1 H400 4.1. Description of first aid measures Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Consult a doctor. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN) Page: 4 Delayed / immediate effects: Immediate effects can be expected after short-term exposure. 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Not applicable. 5.1. Extinguishing media Extinguishing media: Foam. Carbon dioxide. Dry chemical powder. Use water spray to cool containers. 5.2. Special hazards arising from the substance or mixture Exposure hazards: Highly flammable. In combustion emits toxic fumes. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Vapour may travel considerable distance to source of ignition and flash back. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to section 8 of SDS for personal protection details. Use appropriate PPE. Avoid contact with skin and eyes. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak- side up to prevent the escape of liquid. Eliminate all sources of ignition. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks. 6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS. 7.1. Precautions for safe handling Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Use non-sparking tools. ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN) Page: 5 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition. 7.3. Specific end use(s) Specific end use(s): No data available. 8.1. Control parameters

Further information

Not applicable 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. Stable at room temperature. 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below. 10.4. Conditions to avoid Conditions to avoid: Direct sunlight. Heat. Hot surfaces. Sources of ignition. Flames. 10.5. Incompatible materials Materials to avoid: Bases. Reducing agents. Metals. Part B product 10.6. Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In combustion emits toxic fumes of nitrogen oxides. 11.1. Information on toxicological effects Relevant effects for mixture: Effect Route Basis Acute toxicity (harmful) INH Hazardous: calculated Irritation OPT INH DRM Hazardous: calculated Sensitisation DRM Hazardous: calculated Symptoms / routes of exposure Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN) Page: 7 12.1. Toxicity Ecotoxicity values: Not applicable. 12.2. Persistence and degradability Persistence and degradability: No data available. 12.3. Bioaccumulative potential Bioaccumulative potential: No data available. 12.4. Mobility in soil Mobility: No data available. 12.5. Results of PBT and vPvB assessment PBT identification: This substance is not identified as a PBT substance. 12.6. Other adverse effects 13.1. Waste treatment methods Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14.1. UN number UN number: UN1133 14.2. UN proper shipping name Shipping name: ADHESIVES 14.3. Transport hazard class(es) Transport class: 3 14.4. Packing group Packing group: II 14.5. Environmental hazards Environmentally hazardous: No Marine pollutant: No 14.6. Special precautions for user Special precautions: No special precautions. Tunnel code: D/E Transport category: 2 ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN) Page: 8 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. Other information Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * indicates text in the SDS which has changed since the last revision. Phrases used in s.2 and 3 H225 Highly flammable liquid and vapour H242: Heating may cause a fire. H302: Harmful if swallowed. H312: Harmful in contact with skin. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H319: Causes serious eye irritation. H331: Toxic if inhaled. H332: Harmful if inhaled. H335: May cause respiratory irritation. H341: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H351: Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H373: May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H400: Very toxic to aquatic life. R7: May cause fire. R11: Highly flammable. R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R20: Harmful by inhalation. R21/22: Harmful in contact with skin and if swallowed. R22: Harmful if swallowed. R23: Toxic by inhalation. ACRYLIC STRUCTURAL ADHESIVE PART A (PINK&GREEN) Page: 9 R34: Causes burns. R36/38: Irritating to eyes and skin. R37/38: Irritating to respiratory system and skin. R40: Limited evidence of a carcinogenic effect. R41: Risk of serious damage to eyes. R43: May cause sensitisation by skin contact. R48/20/22 Harmful danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R50: Very toxic to aquatic organisms. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R68: Possible risk of irreversible effects. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page of Part A] Lockfast structural adhesive part B (pink and green) Page: 1 Compilation date: 10/04/2014 Revision No: 4 1.1. Product identifier Product name: ACRYLIC STRUCTURAL ADHESIVE PART B (PINK&GREEN) Product code: 121b 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of substance / mixture PC1 Adhesives, sealants 1.3. Details of the supplier of the safety data sheet Company name: Cyanotec Ltd Bay 2 Building 62 I Third Avenue Kingswinford West Midlands DY6 7XT Tel: +44 01384 294753 Fax: +44 01384 297908 Email: sales@cyanotec.com 1.4. Emergency telephone number Emergency Contact : Tim Lucas Contact Number 01384 294753 ( Office hours only Mon – Thurs 8 45 – 16 55 Fri = 8 45 – 14 25) 2.1. Classification of the substance or mixture Classification under CHIP F R11; C R34; Xi R37; Sens. R43 Classification under CLP Flam. Liq. 2 H225; Skin Corr. 1A H314; Skin Sens. 1 H317; STOT SE 3 H335 Most important adverse effects: Highly flammable. Causes burns. Irritating to respiratory system. May cause sensitisation by skin contact. 2.2. Label elements Label elements under CLP: Hazard statements H225 Highly flammable liquid and vapour H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation. Signal words: Danger Hazard pictograms GHS02 Flame GHS05: Corrosion GHS07: Exclamation mark [cont...] ACRYLIC STRUCTURAL ADHESIVE PART B (PINK&GREEN) Page: 2 Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233: Keep container tightly closed. P260: Do not breathe vapours. P264: Wash face and hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+330+331 IF SWALLOWED rinse mouth. Do NOT induce vomiting P303+361+353 IF ON SKIN (or hair) Remove immediately all contaminated clothing Rinse skin with water. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor. P321: Specific treatment (see information on this label). P370+378 In case of fire Use dry chemical powder, carbon dioxide, foam and dry sand for extinction. P403+235: Store in a well-ventilated place. Keep cool. P405: Store locked up. Label elements under CHIP: Hazard symbols: Highly flammable. Corrosive. Risk phrases R11 Highly flammable R34: Causes burns. R37: Irritating to respiratory system. R43: May cause sensitisation by skin contact. Safety phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye / face protection. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 2.3. Other hazards PBT: This product is not identified as a PBT substance. [cont...] ACRYLIC STRUCTURAL ADHESIVE PART B (PINK&GREEN) Page: 3