VLW Primer, Part B

Hazard statements (CLP)

H302, H311, H314, H317, H361, H402

Code

Statements

H302

Harmful if swallowed

2.1 Classification of the substance or mixture

Acute Toxicity, Dermal – Category 2 Skin Corrosion – Category 1B Serious Eye Damage – Category 1 Skin sensitization – Category 1 Acute aquatic toxicity – Category 2 Chronic aquatic toxicity – Category 2

Signal word

Danger) Specific target organ toxicity (single exposure) – Category 3 (Respiratory tract irritation)

Hazard statements

H302: Harmful if swallowed H311: Toxic in contact with skin H314: Causes severe skin burns and eye damage H317: May cause an allergic skin reaction H361: Suspected of damaging fertility or the unborn child H402: Harmful to aquatic life with long lasting effect

Prevention

P201: Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood P261: Avoid breathing dust / fume / gas / mist / vapors / spray P264: Wash skin thoroughly after handling P270: Do not eat, drink or smoke when using this product P272: Contaminated work clothing should not be allowed our of the workplace P280: Wear protective gloves/protective clothing/eye protection/face protection P281: Use personal protective equipment as required P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.

Response

IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell,. Rinse mouth, DO NOT induce vomiting IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF exposed or concerned: Get medical advice/ attention If skin irritation or rash occurs. Get medical advice/ attention. Wash contaminated clothing before reuse

Precautionary statements

Disposal) Dispose of contents/ container to an approved waste disposal plant. HMIS-RATINGS (SCALE 0 – 4) HEALTH 3

NFPA Ratings

Health = 3 1 FLAMMABILITY 1 Fire = 1 Reactivity = 0 3 0 REACTIVITY 0 EMERGENCY OVERVIEW: For Routine Industrial Applications SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of occupational overexposure is contact with skin. The symptoms of overexposure to this product are as follows: EYE CONTACT: May cause severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur. Vapor may cause severe eye irritation. Vapor may cause lacrimation (tears). INHALATION: Excessive exposure may cause irritation to upper respiratory tract (nose and throat). May cause central nervous system depression. Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness. Prolonged excessive exposure may case serious adverse effects, even death. CONTACT WITH SKIN: Brief contact may cause severe skin burns. Symptoms may include pain, severe local redness and tissue damage. Prolonged skin contact is unlikely to result in absorption of harmful amounts. A component in this mixture has caused allergic skin reactions in humans. Contains component(s) which have caused allergic skin sensitization in guinea pigs. INGESTION: Though ingestion is not anticipated to be a significant route of over-exposure to this product, if ingestion does occur, irritation of the mouth, throat, esophagus, and other tissues of the digestive system may occur upon contact. HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. ACUTE: Contact with this solution may cause irritation of the eyes, skin, mucous membranes, and any other exposed tissue. If inhaled, irritation of the respiratory system may occur, with coughing, and breathing difficulty CHRONIC: Repeated skin contact with this product may result in dermatitis (inflammation and reddening of the skin).