CPC Chem Resistant Urethane Part B

Hazard statements (CLP)

H226, H317, H319, H332, H335, H336, H360

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

NFPA Rating GHS Classification Acute toxicity (Inhalation) – Category 4 Skin sensitization – Category 1 Specific target organ toxicity single exposure – Category 3 Respiratory and Central nervous system) Flammable liquids – Category 2 Signal Word: (Danger) Eye irritation – Category 2A Reproductive toxicity – Category 1B Hazard Statements H226: Flammable liquid and vapor H335: May cause respiratory irritation H317: May cause an allergic skin reaction H336: May cause drowsiness or dizziness H319: Causes serious eye irritation H360: May damage fertility or the unborn child H332: Harmful if inhaled

Precautionary statements

P201: Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking P233: Keep away from any possible contact with water, because of violent reaction and possible flash fire P240: Ground/bond container and receiving equipment P241: Use explosion-proof electrical/ventilating//lighting/equipment P242: Use only non-sparking tools P243: Take precautionary measures against static discharge P261: Avoid breathing dust/fume/gas/mist/vapors/spray P264: Wash skin thoroughly after handling P271: Use only outdoors or in a well-ventilated area P272: Contaminated work clothing should not be allowed out of the workplace P280: Wear protective gloves/protective clothing/eye protection/face protection P302+P352 IF ON SKIN Wash with soap and water P303+P361+P353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340+P312 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses if present an easy to do, continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P314: Get Medical advice/attention if you feel unwell P333+P313 If skin irritation or rash occurs Get medical advice/attention P370+P378 In case of fire Use dry sand, dry chemical or alcohol-resistant foam to extinguish P403+P253: Store in a well ventilated place. Keep cool P501: Dispose of contents/container to an approved waste disposal plant. HMIS-RATINGS (SCALE 0 – 4) HEALTH 2* Health = 2*

NFPA Ratings

2 FLAMMABILITY 2 Fire = 2 2 1 Reactivity = 0 REACTIVITY 1

Health hazards

EMERGENCY OVERVIEW: This product is a clear to pale yellow liquid solution. This solution is corrosive, and can be damaging to contaminated tissue. Ingestion of large quantities can be fatal. In the event of fire or spill, adequate precautions must be taken. If involved in a fire, this product may decompose to produce toxic or irritating combustion products and a variety of other compounds (i.e. carbon monoxide and carbon dioxide). Emergency responders must wear the proper personal protective equipment suitable for the situation to which they are responding. SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: This solution can damage skin, eyes, mucous membranes, and other contaminated tissue. INHALATION: HDI aerosols or vapors at concentrations above the applicable exposure limits can irritate the mucous membranes in the respiratory tract causing runny nose, sore throat, dryness of the throat, chest tightness, coughing, chest discomfort, shortness of breath (dyspnea) and reduced lung function. Persons with pre-existing non-specific bronchial hyperreactivity can respond to concentrations below the exposure limits with similar symptoms as well as an asthma attack. Exposure well above the exposure limits may lead to bronchitis, bronchial spasm and pulmonary edema. These symptoms can be delayed up to several hours after exposure. Chemical or hypersensitive pneumonitis has also been reported. Other possible symptoms of overexposure include headache, wheezing, dizziness, nausea, narcosis, fatigue and loss of appetite. Chronic overexposure has been associated with various neurotoxic effects including permanent brain and nervous system damage, loss of memory, loss of intellectual ability and loss of coordination. CONTACT WITH SKIN: Isocyanates react with skin protein and moisture and can cause irritation. Symptoms of skin irritation may include reddening, swelling, rash, scaling or blistering. Some persons may develop skin sensitization from skin contact. Cured material is difficult to remove. Repeated or prolonged contact can result in dry, defatted and cracked skin with increased susceptibility to infection. Additional irritation may develop into dermatitis. CONTACT WITH EYES: Vapors are irritating and can cause pain, tearing, reddening and swelling if left untreated. Corneal damage can occur and injury is slow to heal, however damage is usually reversible. SKIN ABSORPTION: Skin absorption is not anticipated to be a significant route of over-exposure to any component of this product. INGESTION: Though ingestion is not anticipated to be a significant route of over-exposure to this product, if ingestion does occur it can result in irritation and possible corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Vomiting may cause aspiration of solvent resulting in chemical pneumonitis. INJECTION: Though injection is not anticipated to be a significant route of over-exposure to this product, if it occurs, may cause local reddening, tissue swelling, and discomfort. HEALTH EFFECTS OR RISKS FROM EXPOSURE: A Brief Explanation in Lay Terms. ACUTE: This solution is corrosive, and can burn and damage eyes, skin, mucous membranes, and any other exposed tissue. If inhaled, irritation of the respiratory system may occur, with coughing, and breathing difficulty. Though to occur during occupational use, ingestion of large quantities may be fatal. unlikely CHRONIC: Repeated skin contact with this product may result in dermatitis (inflammation and reddening of the skin) and skin sensitization.

2.1 Classification of the substance or mixture

Acute toxicity (Inhalation) – Category 4 Skin sensitization – Category 1 Specific target organ toxicity single exposure – Category 3 (Respiratory and Central nervous system) Flammable liquids – Category 2 Signal Word: (Danger) Eye irritation – Category 2A Reproductive toxicity – Category 1B Hazard Statements: H226: Flammable liquid and vapor H335: May cause respiratory irritation H317: May cause an allergic skin reaction H336: May cause drowsiness or dizziness H319: Causes serious eye irritation H360: May damage fertility or the unborn child H332: Harmful if inhaled