General Information
Revision date
2021-06-24
Product name
CropSure Metribuzz 750WG Herbicide
CAS No.
21087-64-9
Icons in SDS
Company Information
company name
CropSure Pty Ltd
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H302, H410
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
Hazard statements
This product is classified as: Xn, Harmful. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria. H302: Harmful if swallowed. H410: Very toxic to aquatic life with long lasting effects.
SUSMP Classification
S6
ADG classification
None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.
UN Number
None allocated
Signal word
WARNING
Prevention
P102: Keep out of reach of children. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P281: Use personal protective equipment as required.
Response
P352: Wash with plenty of soap and water. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
Storage
P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.
Disposal
P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Off-white to beige coloured granules. Odour: No data re odour.
Health hazards
Metribuzin is harmful orally, with reported oral LD50 values of 1090 to 2300 mg/kg in rats, 700 mg/kg in mice and 245 to 274 mg/kg in guinea pigs. It is practically nontoxic dermally, with a dermal LD50 of 20,000 mg/kg in rabbits. The 4-hour inhalation LC50 for Metribuzin in rats is greater than 0.65 mg/L, indicating moderate toxicity via the inhalation route. Metribuzin has been shown not to irritate the skin or eyes of rats, rabbits, guinea pigs, or human volunteers. Effects of high acute exposure in Metribuzin poisoned rats included narcosis (stupor) and laboured breathing. Deaths occurred within 24 hours, and survivors recovered slowly without permanent effects. This product is harmful if swallowed.
