CropSure Greenshield 750WG Fungicide

Hazard statements (CLP)

H315, H317, H318, H334, H361, H400

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S

Signal word

DANGER Skin Corrosion /Irritation Category 2 Skin Sensitisation Category 1 Serious eye damage/eye irritation Category 1 Respiratory Sensitization Category 1 Reproductive Toxicity Category 2 Hazardous to aquatic environment Short term Category 1

Hazard statements

H315: Causes skin irritation. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361: Suspected of damaging fertility or the unborn child. H400: Very toxic to aquatic.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P261: Avoid breathing dusts. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection. P285: In case of inadequate ventilation wear respiratory protection.

Response

P310: Immediately call a POISON CENTRE or doctor/physician. P335: Brush off loose particles from skin. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P333+P313 If skin irritation or rash occurs Get medical advice P342+P311 If experiencing respiratory symptoms Call a POISON CENTRE or doctor P370+P378 In case of fire Use carbon dioxide, dry chemical, foam, water fog, to extinguish

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Greyish granules. Odour: Mild characteristic odour.

Health hazards

Mancozeb is practically nontoxic orally with reported oral LD50 of more than 5000 to more than 11,200 mg/kg in rats. Dermally it is also practically nontoxic, with reported dermal LD50 values of more than 10,000 mg/kg in rats, and more than 5000 mg/kg in rabbits. It is a mild skin irritant and sensitizer, and a mild to moderate eye irritant in rabbits. Workers with occupational exposure to Mancozeb have developed sensitization rashes. may cause an allergic skin reaction, causes serious eye damage, may cause allergy or asthma symptoms or breathing difficulties if inhaled, causes skin irritation, suspected of damaging fertility or the unborn child. This product is a cumulative poison. Minor exposures over a period of time may lead to serious health problems.