CropSure Esstane LV 680 Herbicide

Hazard statements (CLP)

H227, H302, H317, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. However, this is a C1 Combustible Liquid so must be stored and handled as specified in AS 1940 “The storage and handling of flammable and combustible liquids.” H227: Combustible liquid. H302: Harmful if swallowed. H317: May cause an allergic skin reaction. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING Flammable liquids Category 4 Acute Toxicity Oral Category 4 Skin Sensitisation Category 1 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P102: Keep out of reach of children. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P337 If eye irritation persists seek medical attention P363: Wash contaminated clothing before reuse. P301+P312 IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P333+P313 If skin irritation or rash occurs Get medical advice P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Clear brown liquid. Odour: Mild odour.

Health hazards

The oral LD50 of 2,4-D ranges from 375 to 666 mg/kg in the rat, 370 mg/kg in mice, and from less than 320 to 1000 mg/kg in guinea pigs. The dermal LD50 values are 1500 mg/kg in rats and 1400 mg/kg in rabbits, respectively. In humans, prolonged breathing of 2,4-D causes coughing, burning, dizziness, and temporary loss of muscle coordination. Other symptoms of poisoning can be fatigue and weakness with possible nausea. On rare occasions following high levels of exposure, there can be inflammation of the nerve endings with muscular effects.