CropSure Captan 800WG Fungicide

Hazard statements (CLP)

H317, H318, H331, H351, H400

Code

Statements

H317

May cause an allergic skin reaction

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H331: Toxic if inhaled. H351: Suspected of causing cancer. H400: Very toxic to aquatic life.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S

Signal word

DANGER Skin Sensitisation Category 1 Serious eye damage/eye irritation Category 1 Acute Toxicity Inhalation Category 3 Carcinogenicity Category 2 Hazardous to aquatic environment Short term/Acute Category 1

Prevention

P102: Keep out of reach of children. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P261: Avoid breathing dusts or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P310: Immediately call a POISON CENTRE or doctor/physician. P363: Wash contaminated clothing before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: Not combustible. Use extinguishing media suited to burning materials. Water fog or fine spray is the preferred medium for large fires.

Storage

P403: Store in a well-ventilated place. P405: Store locked up. P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Light brown granulated solid. Odour: Faint, characteristic odour.

Health hazards

The rat oral LD50 for Captan ranges from 8400 to 15,000 mg/kg, indicating very low acute toxicity. The mouse LD50 is 7000 mg/kg. Sheep showed no effect at doses of 200 mg/kg, but experienced deaths at 250 mg/kg. The inhalation LC50 (2-hour) in mice is 5.0 mg/L. Rabbits showed little or no skin sensitization to Captan, while guinea pigs were moderately sensitive. Workers exposed to high concentrations of Captan in air (6 mg/m3) experienced eye irritation including burning, itching, and tearing. Skin irritation also occurred in some cases. Toxic if inhaled, limited evidence of a carcinogenic effect, may cause serious damage to eyes, possible skin sensitiser.