Hardmetal powder containing primarily tungsten

Hazard statements (CLP)

H317, H331, H334, H351, H372, H400, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

1999/45/EC = 2.1: Classificatign of the mixture Acute inhalation 3, H331 Care. Cat. 2, H351 STOT RE 1, H372

Signal word

Danger Toxic if inhaled Suspected of causing cancer by inhalation Causes damage to lungs through prolonged or

Hazard statements

repeated exposure by inhalation May cause allergy or asthma symptoms or breathing difficulties if inhaled Page 1 of 14 Version: 1.0 Printed: 1 February 2012 May cause an allergic skin reaction Very toxic to aquatic life with long lasting effects Do not breathe dust Wear protective gloves and protective clothing. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection Avoid release to the environment

Precautionary statements

IF INHALED: If breathing is difficult, remove victim . to fresh air and keep at rest in a position comfortable for breathing. if experiencing respiratory symptoms: Cail a POISON CENTER or doctor/physician If skin irritation or rash occurs: Get medical advice/attention 2.3: Other Hazards PBT or vPvB Tungsten carbide and cobalt are inorganic substances and therefore, the PBT and vPvB assessment is not required. :-3: Composition

2.1 Classification of the substance or mixture

Acute inhalation 3, H331 Care. Cat. 2, H351 STOT RE 1, H372 Classification according to EC 1272/2008: Resp. Sens. 1B, H334 Skin Sens.1, H317 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 T; R23 Care. Cat. 3; R40 Classification according to 1999/45/EC : T; R48/23 R42/43 N, R50-53