3M Mar-Hyde (R), Single Stage Self-Etch Primer 5112, 5113

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Clear Ketone Odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause allergic skin reaction. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation BENZENE 71-43-2 Group 1 International Agency for Research on Cancer BENZENE 71-43-2 Known human carcinogen National Toxicology Program Carcinogens BENZENE 71-43-2 Cancer hazard OSHA Carcinogens CARBON BLACK 1333-86-4 Group 2B International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Group 1 International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 25 ºF [Test Method: Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Avoid contact with oxidizing agents.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles and Full Faceshield. 8.2.2 Skin Protection Avoid skin contact. Avoid prolonged or repeated skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA). 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. Do not ingest. Wash hands after handling and before eating. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

BENZENE ACGIH TWA 0.5 ppm Skin Notation*; Table A1 BENZENE ACGIH STEL 2.5 ppm Skin Notation*; Table A1 BENZENE OSHA TWA 1 ppm Standard Appendix BENZENE OSHA STEL 5 ppm Standard Appendix CARBON BLACK ACGIH TWA 3.5 mg/m3 Table A4 CARBON BLACK CMRG TWA 0.5 mg/m3 CARBON BLACK OSHA TWA 3.5 mg/m3 Table Z-1 METHYL ETHYL KETONE ACGIH TWA 200 ppm METHYL ETHYL KETONE ACGIH STEL 300 ppm METHYL ETHYL KETONE OSHA TWA 200 ppm Table Z-1A METHYL ETHYL KETONE OSHA STEL 300 ppm Table Z-1A METHYL METHACRYLATE ACGIH TWA 50 ppm Sensitizer; Table A4 METHYL METHACRYLATE ACGIH STEL 100 ppm Sensitizer; Table A4 METHYL METHACRYLATE OSHA TWA 100 ppm Table Z-1 METHYL N-AMYL KETONE ACGIH TWA 50 ppm METHYL N-AMYL KETONE OSHA TWA 100 ppm Table Z-1 N-BUTYL ACETATE ACGIH TWA 150 ppm N-BUTYL ACETATE ACGIH STEL 200 ppm N-BUTYL ACETATE OSHA TWA 150 ppm Table Z-1A N-BUTYL ACETATE OSHA STEL 200 ppm Table Z-1A QUARTZ SILICA ACGIH TWA, respirable 0.025 mg/m3 Table A2 QUARTZ SILICA OSHA TWA, respirable 0.1 mg/m3 Table Z-1A TITANIUM DIOXIDE ACGIH TWA 10 mg/m3 Table A4 TITANIUM DIOXIDE CMRG TWA, as respirable 5 mg/m3 dust TITANIUM DIOXIDE OSHA TWA, Vacated, as 10 mg/m3 dust TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1 TOLUENE ACGIH TWA 20 ppm Table A4 TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA, Vacated 100 ppm TOLUENE OSHA STEL, Vacated 150 ppm TOLUENE OSHA TWA 200 ppm Table Z-2 TOLUENE OSHA CEIL 300 ppm Table Z-2 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Clear Ketone Odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 25 ºF [Test Method: Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point 176 ºF Density 7.6652 lb/gal Vapor Density No Data Available Vapor Density No Data Available Vapor Pressure No Data Available Vapor Pressure No Data Available Specific Gravity 0.806 g/cm3 pH No Data Available Melting point No Data Available Solubility In Water No Data Available Solubility in Water Moderate [Details: 10-49%] Volatile Organic Compounds 84.34 % [Test Method: calculated SCAQMD rule 443.1] VOC Less H2O & Exempt Solvents 1,282.21 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Sparks and/or flames; Strong acids; Strong oxidizing agents; Heat; Alkali and alkaline earth metals Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HCl. Facility must be capable of handling halogenated materials. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene), D035 (Methyl ethyl ketone) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 70-0080-0610-1, 70-0080-0611-9 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt TOLUENE 108-88-3 3 - 7 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No.

2.1 Classification of the substance or mixture

BENZENE 71-43-2 *Male reproductive toxin BENZENE 71-43-2 **Carcinogen BENZENE 71-43-2 *Developmental Toxin CARBON BLACK 1333-86-4 **Carcinogen TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Further information

NFPA Hazard Classification Health 2 Flammability 4 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Copyright was modified. Section 3: Potential effects from inhalation information was modified. Section 13: Waste disposal method information was modified. Section 3: Immediate other hazard(s) was modified. Page Heading: Product name was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 9: Property description for optional properties was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com