Bifen L/P

SECTION 2: Hazards identification

(29 CFR 1910.1200) EMERGENCY OVERVIEW: Tan granule with a slightly musty odor.

Signal word

DANGER DANGER

Hazard statements

May cause cancer May cause damage to organs (lungs) through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Extremely flammable aerosol. May cause drowsiness or dizziness.

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Wear face protection. Do not breathe dust. Keep away from heat/sparks/open flames/hot surfaces. – No smoking Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist/vapors/spray. Use only outdoors or in a well-ventilated area.

Response

IF EXPOSED OR CONCERNED Get medical advice/attention IF SWALLOWED Immediately call a poison center/doctor. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell.

Storage

Store locked up See pesticide label for full information on product storage. Do not contaminate water, food or feed by storage of this product. Store away from sources of heat, out of direct sunlight and away from incompatible materials. Pesticides should be stored in secured areas away from children and animals. Temperature (Min/Max) Not determined Product Incompatibilities: None known SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Users of a pesticide product must refer to the product label for personal protective equipment requirements. Exposure Guidelines: COMPONENT Store locked up. Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal

Dispose of contents/container in accordance with Federal, state and local laws and regulations. The following percentage of the mixture consists of components with unknown hazards regarding the acute toxicity: 1.0% Acute oral toxicity 1.0% Acute dermal toxicity 100.0% Acute Inhalation toxicity Chemical Name CAS Number Weight % Bifenthrin 82657-04-3 0.2% Sand - (contains) None 94.0 – 100.0% Crystalline silica 14808-60-7 <1.0% *Ingredients not listed or listed with a weight % range are considered a trade secret and are withheld under 29 CFR 1910.1200(i). SECTION 4: FIRST AID MEASURES IF IN EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes; then continue rinsing eye. Call a poison control center or doctor for treatment advice. IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 1 5 to 20 minutes. Call a poison control center or doctor for treatment advice. IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. IF INGESTED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Note to Physician: This product is a pyrethroid. If large amounts have been ingested, milk, cream and other digestible fats and oils may increase absorption and so should be avoided. Most important symptoms/effects, acute and delayed: Acute symptoms may include mild, mechanical irritation to eyes. SECTION 5: FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use appropriate extinguishing media for surrounding fire. Unsuitable Extinguishing Media: Heavy water stream Hazardous Combustion Products: Thermal decomposition may produce oxides of carbon, nitrogen, calcium and magnesium. Special Protective Equipment & Evacuate area and fight fire upwind from a safe distance to avoid Dispose of contents/container in accordance with Federal, state and local laws and regulations. D-Fense NXT Version revision date September 23, 2021

Precautionary statements

hazardous vapors and decomposition products. Foam and/or dry chemical are preferred to minimize environmental contamination. If water is used, dike and collect water to prevent run-off. Wear self- contained breathing apparatus and full fire-fighting turn-out gear (Bunker gear). Unusual Fire & Explosion Hazards: None known SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: See Section 8 for personal protection equipment. Environmental Precautions: Keep spilled material and any rinsate from contaminating soil or from entering sewage and drainage systems and bodies of water. Methods for Containment: Isolate the spill area. Keep unnecessary and unprotected personnel from entering. Avoid inhalation of dust. Avoid actions that cause dust to become airborne. Methods for Clean-up: Uncontaminated product may be placed in a container for use according to label directions. Do not put spilled material back in the original container. Avoid actions that cause dust to become airborne during dry clean-up such as sweeping or using compressed air. Use HEPA vacuum or thoroughly wet with water to clean-up dust. Pick up wash liquid with additional absorbent and place in a disposable container.

Further information

None known SECTION 7: HANDLING AND STORAGE Handling: RECOMMENDATIONS ARE INTENDED FOR MANUFACTURING, PACKAGING AND COMMERCIAL BLENDING WORKERS. PESTICIDE APPLICATORS AND WORKERS must refer to the product label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Handle and open container in a manner as to prevent spillage. Do not eat, drink or smoke while handling this product. Immediately wash off accidental splashes of the concentrate or spray mixture from skin, clothing and out of eyes. NFPA

Principle Routes of Exposure

Eye contact, Skin contact, Inhalation, Ingestion Symptoms of Exposure: Mild mechanical irritation of eyes. Silicosis of the lungs or lung cancer. Oral LD50: >4,900 mg/kg (rat)(Estimated based upon component data) Dermal LD50: >2,000 mg/kg (rat)(Estimated based upon component data) Inhalation LC50: Not determined Eye Irritation/Damage: Not anticipated to cause eye irritation based upon component data. Skin Corrosion/Irritation: Not anticipated to cause skin irritation based upon component data. Skin Sensitization: Not anticipated to cause skin sensitization based upon component data. Chronic/Subchronic Toxicity: Prolonged inhalation of respirable crystalline silica may be harmful. May cause damage to organs (lungs) through prolonged or repeated exposure. There are reports in the literature suggesting that excessive crystalline silica exposure may be associated with autoimmune disorders and other adverse

Potential health effects

involving the kidney. In particular, the incidence of scleroderma (thickening of the skin caused by swelling and the thickening of fibrous tissue) appears to be higher in silicotic individuals. To date, the evidence does not conclusively determine a causal relationship between silica exposure and these adverse health effects. Mutagenicity: No data available Reproductive Toxicity: No data available Neurotoxicity: No data available Target Organs: Lungs (respirable crystalline silica)

Aspiration hazard

Not an aspiration hazard Carcinogenicity Respirable Crystalline Silica (RCS) may cause cancer. Sand is a naturally occurring mineral complex that contains varying quantities of quartz crystalline silica). In its natural bulk state, sand is not a known health hazard Sand may be subjected to various natural or mechanical forces that produce small particles (dust) which may contain respirable crystalline silica (particles less than 10 micrometers in aerodynamic diameter). Repeated inhalation of respirable crystalline silica (quartz) may cause lung cancer according to IARC and NTP Chemical Name ACGIH IARC NTP Category 1 Flammable Aerosols Category 1 Specific Target Organ Toxicity – Single Exposure Category 3

2.2 Label elements

Requirements Under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if absorbed through skin. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. TSCA Inventory: This product is exempt from TSCA inventory listing requirements as it is solely for FIFRA regulated use. SARA Title III Information: Section 302 – Extremely hazardous substances: None Section 311/312 – Hazard Categories: None Section 313 – This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS Number Weight % Bifenthrin 82657-04-3 0.2%

Health hazards

1 Flammability 0 Instability 0 Special Hazards – None Disclaimer: Control Solutions, Inc. believes the information presented herein is accurate and correct as of the document date. The presented information is based upon available data from reliable sources. Control Solutions, Inc. makes no warranty, express or implied, regarding the accuracy of the data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or damage stemming from any improper use of the material or product described herein. Version revision date May 30, 2017 Document Superseded: September 9, 2014 Version revision date Note Updated to format and most sections Version revision date September 23, 2021 D-Fense NXT SECTION 1: IDENTIFICATION Product Name: D-Fense NXT EPA Registration No.: 53883-415 Recommended Use: Insecticide; See product label for a complete list of uses and use sites. Restrictions on Use: See product label for any restrictions on the use of this product. Chemical Family: N/A – Multiple Active Ingredients Chemical Name of Active Deltamethrin Ingredient(s): Novaluron Pyriproxyfen Manufactured for: Control Solutions, Inc. 5903 Genoa-Red Bluff Pasadena, TX 77507 FOR FIRE, SPILL, AND/OR LEAK EMERGENCIES CONTACT: CHEMTREC 1-800-424-9300 FOR MEDICAL EMERGENCIES AND HEALTH AND SAFETY INQUIRIES CONTACT: Safety Call 1-866-897-8050 EMERGENCY OVERVIEW: Aerosol with a strong alcohol odor. Inhalation of vapors may cause drowsiness or dizziness. Extremely flammable aerosol.

2.1 Classification of the substance or mixture

Carcinogenicity: Respirable Crystalline Silica (RCS) may cause cancer. Sand is a naturally occurring mineral complex that contains varying quantities of quartz (crystalline silica). In its natural bulk state, sand is not a known health hazard. Sand may be subjected to various natural or mechanical forces that produce small particles (dust) which may contain respirable crystalline silica (particles less than 10 micrometers in aerodynamic diameter). Repeated inhalation of respirable crystalline silica (quartz) may cause lung cancer according to IARC and NTP. Chemical Name ACGIH IARC NTP OSHA Respirable crystalline silica Group 1 Known Human Carcinogen SECTION 12: ECOLOGICAL INFORMATION Environmental Hazards Statement from FIFRA Regulated Pesticide Label: This pesticide is extremely toxic to fish and aquatic invertebrates. Do not apply when weather conditions favor drift from treated areas. Drift and run-off from treated areas may be hazardous to aquatic organisms in neighboring areas. To protect the environment, do not allow pesticide to enter or run off into storm drains, drainage ditches, gutters or surface waters. Applying this product in calm weather when rain is not predicted for the next 24 hours will help to ensure that wind or rain does not blow or wash pesticide off the treatment area. Sweeping any product that lands on a driveway, sidewalk, or street, back onto the treated area of the lawn or garden will help to prevent run off to water bodies or drainage systems ECOTOXICITY DATA: Data presented below is on the bifenthrin technical product. Fish Toxicity: S. gairdneri: 96-hour LC50 = 0.1 mg/L Aquatic Invertebrate Toxicity: Daphnia magna: 96-hour EC50 = 0.65 mg/L Aquatic Plant Toxicity: P. subcapitata: EC50 = 11.04 mg/L Avian Toxicity: Bobwhite quail: oral LD50 = 1800 mg/kg Honeybee Toxicity: Oral LD50 = 0.39 µg/bee ENVIRONMENTAL EFFECTS: Persistence and Degradability: No data available Bioaccumulation: No data available Mobility: No data available Other Adverse Effects: No data available SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal: Refer to the pesticide label for full information on disposal. Pesticide wastes are toxic. Improper disposal of unused pesticide, spray mixture, or rinse water is a violation of Federal law. If these wastes cannot be used according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance in proper disposal methods. Container Disposal: Refer to the pesticide label for full information on disposal. When possible, triple rinse the container and offer for recycling if available. RCRA Characteristics: It is the responsibility of the individual disposing of this product to determine the RCRA classification and hazard status of the waste. SECTION 14: TRANSPORTATION INFORMATION DOT Not regulated (Ground): IMDG UN3077, Environmentally hazardous substance, solid, n.o.s. (Bifenthrin), 9, PGIII, Marine (Sea): Pollutant IATA UN3077, Environmentally hazardous substance, solid, n.o.s. (Bifenthrin), 9, PGIII (Air): SECTION 15: REGULATORY INFORMATION Labeling Requirements Under FIFRA: This chemical is a pesticide product registered by the Environmental