GUARD (aerosol)

Hazard statements (CLP)

H223, H229, H280

Code

Statements

H223

Flammable aerosol

SECTION 2: Hazards identification

CLASSIFICATION: Flammable Aerosol: Category 2 Liquefied Gas Skin Irritant: Category 2 Eye Irritant: Category 2A HAZARD STATEMENT(S): Warning: Flammable Aerosol Contains gas under pressure; May explode if heated. Causes skin and serious eye irritation This product contains the following percentage of chemicals of unknown toxicity: 0%

Precautionary statements

Keep away from heat, sparks, open flames, and hot surfaces. –No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Wash hands thoroughly after handling. Wear protective gloves and eye protection. If on skin Wash with plenty of water. If skin irritation occurs Get medical attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

2.3 Other hazards

N/A

2.1 Classification of the substance or mixture

Liquefied Gas Skin Irritant: Category 2 Eye Irritant: Category 2A HAZARD STATEMENT(S): Warning: Flammable Aerosol Contains gas under pressure; May explode if heated. Causes skin and serious eye irritation. This product contains the following percentage of chemicals of unknown toxicity: 0% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. –No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Wash hands thoroughly after handling. Wear protective gloves and eye protection. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENT CAS NUMBER PERCENT Diethyl-M-Toluamide 134-62-3 22.56% Isopropyl Alcohol 67-63-0 15-40% Propane/n-Butane 68476-86-8 10-30% Acetone 67-64-1 3-7% n-Octyl bicycloheptene dicarboximide 113-48-4 5% Di-n-propyl isocinchomeronate 136-45-8 2.5% SECTION IV - FIRST AID MEASURES EYES: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. INGESTION: Rinse mouth with water. Do not induce vomiting unless directed by medical authority. Seek medical attention. INHALATION: Move to fresh air. If breathing is difficult, administer oxygen. If heartbeat or breathing seems irregular seek immediate medical attention. SKIN: Immediately wash with soap and water for 15 minutes. Seek medical attention if irritation develops. ACUTE HEALTH HAZARDS: Eyes: redness, tearing, blurred vision Skin: defatting and dermatitis Oral: abdominal irritation, nausea, vomiting, and diarrhea CHRONIC HEALTH HAZARDS: None known NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. SECTION V – FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Dry chemical, alcohol foam, alcohol-resistant foam, or carbon dioxide. Water may be ineffective. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece operated in a positive pressure demand mode with full body protective clothing when fighting fires. Avoid contact with skin and breathing smoke, fumes, and decomposition products. Cool fire exposed containers with water fog to prevent bursting. UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon SECTION VI – ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Contain Spill. Use absorbent material such as vermiculite for large spills. Small spills may be wiped up using wiping material WASTE DISPOSAL: Dispose of in accordance with local, State and Federal regulations. Wrap empty containers in newspapaer and dispose properly RCRA STATUS: Liquid could be classified as D001 under RCRA, however product should be fully characterized prior to disposal (40 CFR 261). SECTION VII – HANDLING AND STORAGE HANDLING AND STORAGE: Protect from sunlight. Store in a well ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. OTHER PRECAUTIONS: Store in a cool, dry area away from heat, sparks or flame. Read directions before using. INCOMPATIBILITY: Strong oxidizers, alkalies, and strong acids SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Diethyl-M-Toluamide Not Established Isopropyl Alcohol 400 ppm 200 ppm Propane/n-Butane 1000 ppm Acetone 1000 ppm 500 ppm n-Octyl bicycloheptene dicarboximide Not Established Di-n-propyl isocinchomeronate Not Established ENGINEERING CONTROLS / VENTILATION: Ambient ventilation suitable, forced ventilation should not be required RESPIRATORY PROTECTION: Not required with normal use. Wear NIOSH/MSHA approved respiratory protection if exposure limits are exceeded. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses ADDITIONAL MEASURES: Wash hands thoroughly after handling. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, light amber aerosol ODOR: Insecticidal odor ODOR THRESHOLD: N/D BOILING POINT: 165 FREEZING POINT: N/D FLAMMABILITY: Flammable Aerosol FLASH POINT: N/D AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): >10 @ 77°F (25°C) VAPOR DENSITY (AIR=1): >2 EVAPORATION RATE: <3 SPECIFIC GRAVITY (H2O=1): 0.870 pH: N/A SOLIDS (%): N/D SOLUBILITY IN WATER: 39% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER (%): 70% VOLATILE ORGANIC COMPOUNDS (VOC): 64.5% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D SECTION X – STABILITY AND REACTIVITY DATA REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 122°F may cause bursting. INCOMPATIBILITY: Strong oxidizers, alkalies, and strong acids