EMECOLE 322, PART A

Hazard statements (CLP)

H226, H332, H335, H336

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Emergency Overview Skin Contact: Prolonged or repeated exposure may cause skin irritation and redness. Skin sensitization or allergic

2.3 Other hazards

reaction (contact dermatitis) may occur in some individuals. Skin Contact: No irritation is likely to develop following short contact periods with skin. Prolonged or repeated Flammable Liquid, May cause respiratory irritation, May cause drowsiness or dizziness, May be fatal if swallowed and enters airways. Toxic Eye Contact: Following contact irritation will take place exposure can cause skin irritation, reddening, dermatitis and in some individuals, sensitization. Skin contact may to aquatic life with long lasting effects. result in allergic skin reactions or respiratory sensitization but is not expected to result in absorption or amounts Ingestion: Probable oral toxicity, LD50 (rat), >10g/kg. Irritation of the mouth, pharynx, esophagus and stomach can suffi cient to cause other adverse effects. May stain skin. Target Organs: Eyes, Skin, Respiratory System, Central Nervous System. develop upon ingestion.

2.1 Classification of the substance or mixture

Inhalation: No known health information on inhalation of vapors. Vapors and aerosols probably affect respiratory Eye Contact: As a liquid or dust may cause irritation, infl ammation and or damage to sensitive eye tissue. Symptoms include watering or discomfort of eyes. Corneal injury is unlikely. Flammable Liquids--Category 3 tract. MDI can induce respiratory irritation with asthma-like symptoms. These symptoms may be immediate or delayed up to several hours after exposure. There are reports that long-term exposure may result in decreased lung Ingestion: Single dose oral toxicity is considered to be extremely low. Can result in irritation and corrosive action in Hazardous to the Aquatic Environment, Long-Term (Chronic) Hazard--Category 2 function. mouth, stomach tissue and digestive tract. Specific target organ toxicity, Single exposure--Category 3 January 15, 2015

Precautionary statements

Do not handle until all safety precautions have been read and understood. Do not breathe Aspiration Hazard--Category 1 vapors. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye protection. Do Acute Toxicity, Inhalation--Category 4 not eat, drink or smoke when using this product. Wash thoroughly after handling. Store locked up. Keep away from children. Dispose of contents and container in accordance with applicable local, regional and national regulations. Label Elements, including precautionary statements

Signal word

Danger DANGER Aquatic Toxicity:

Hazard statements

Chronic As a result of previous repeated overexposure or a single large dose, certain individuals H226 Flammable Liquid and Vapour. Acute And Prolonged Toxicity To Fish LC50 > 500 mg/l (Zebra fi sh(Brachydanio rerio), 24 hrs) develop isocyanine sensitization (chemical asthma) or tissue injury in the upper respiratory tract. Animal tests indicate skin contact alone may also lead to allergic respiratory reaction. These effects may be permanent. Any person H332 Harmful if inhaled. Acute And Prolonged Toxicity To Fish LC50 > 500 mg/l (Water fl ea (Daphnia magna), 24 hrs) skin contact alone may also lead to allergic respiratory reaction. These effects may be permanent. Any person developing asthmatic reaction or other sensitization should be removed from further exposure. H335 May cause respiratory irritation. Other Effects of Overexposure: In a recently completed study, groups of rats were exposed for 6 hours/day, 5 days/

Potential health effects

At room temperature, MDI vapors are minimal due to low vapor pressure. However, heating, H336 May cause drowsiness or dizziness.

Disposal

Considerations week for a lifetime to atmospheres of respirable polymeric MDI aerosol. Tumor incidence, both benign and malignant, foaming or otherwise dispersing (drumming, venting or pumping) operations may generate more vapor or aerosol and the number of animals with tumors were not different from controls. There were no lung tumors at 1 mg/m3 concentrations of isocyanate. Excessive exposure may cause irritation of the eyes, upper respiratory tract and lungs. Any disposal practice must be in compliance with all federal, state and local laws and regulations. Chemical and no effects at .2 mg/m3. However, at the top level only of 6 mg/m3 there was a signifi cant incidence of a benign Severe overexposure may lead to pulmonary edema. Respiratory sensitization with asthma like symptoms may occur Concrete Sealers USA | P.O. Box 5464 | De Pere, WI 54115 additions, processing, storage, or otherwise altering this material may make the waste management information Toll-Free 888.583.2991 | Fax 920.759.5100 | Emergency 800.424.9300 presented in this SDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal tumor of the lung (adenoma) and one malignant tumor (adenocarcinoma). The increased incidence for lung tumors in susceptible individuals. MDI concentration below the exposure guidelines may cause allergic respiratory reactions compliance is the responsibility solely of the party generating the waste or deciding to discard or dispose of the is associated with the prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung in individuals already sensitized. Symptoms may include coughing, dryness of throat, headache, nausea, diffi culty info@concretesealersusa.com | www.concretesealersusa.com Continues on next page material. that was observed throughout the study. breathing and feeling of tightness in the chest. Effects may be delayed. Impaired lung function (decreased ventilators Refer to RCRA 4 CFR 261 and/or any other appropriate federal, state or local requirements for proper classifi cation information. Carcinogenicity: In order to comply with California Proposition 65, we feel obligated to advise that some of our capacity) has been associated with overexposure to isocyanate. products may conceivably contain trace contaminants of some of the listed chemicals. While not necessarily added Persons With Known Respiratory or Allergy Problems Must Not Be Exposed to This Product. Container Disposal: Drums/containers must be thoroughly drained to process or storage vessels before removal to an appropriate area for subsequent decontamination. Drums/containers must be decontaminated in properly to our products as ingredients, some listed chemicals may be present in the raw materials from suppliers and over Carcinogenicity: MDI and polymeric MDI are not listed by the NTP, IARC or regulated by OSHA as carcinogens. Lung ventilated areas by personnel protected from the inhalation of isocyanate vapors. Spray or pour 1 to 5 gallons of which we have no control. Therefore, even though some of the listed substances may not be present, a signifi cant risk tumors have been observed in laboratory animals exposed to aerosol droplets of MDI/Polymeric MDI (6mg/m3) for decontamination solution into the drum making sure the walls are well rinsed. Let the drum/container soak unsealed as defi ned by the regulations in order to comply with California law, we feel obligated to make the following statement: their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are for 48 hours. Pour out the decontamination solution and triple rise the empty container. Puncture or otherwise Warning Our products may contain trace amounts of some chemicals considered by the State of California to be expected to protect against these effects. destroy the rinsed container before disposal. Do not heat or cut empty containers with electric or gas torch. carcinogens or reproductive toxicants. RCRA/EPA Waste Information:The generation of waste should be avoided or minimized whenever possible. Chemical waste, even small quanities, should never be poured down draines, sewers or waterways.