ProTek 95 Part B

SECTION 2: Hazards identification

OSHA Hazard Overview

2.1 Classification of the substance or mixture

skin sensitizer category 1B, Acute toxicity inhalation category 4, Specific target organ toxicity – single exposure category 3, Acute toxicity (oral) category 4, Skin irritation category 2, Eye irritation category 2A, Carcinogenicity category 2, Respiratory Sensitization category 1, Acute hazard to aquatic environment category 3

2.2 Label elements

Elements and Precautionary Statements Exclamation Mark

Hazard statements

Warning May cause an allergic skin reaction Warning Harmful if inhaled Warning May cause respiratory irritation. Warning Harmful if Swallowed. Warning Causes skin irritation. Warning Causes serious eye irritation. Warning Suspected of causing Cancer. Danger May cause allergy or Asthma symptoms or breathing difficulties if inhaled. Harmful to aquatic life

Precautionary statements

P102 Keep out of reach of children. P103 Read label before use P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves and clothing to prevent skin contact. P271 Use only outdoors or in a well-ventilated area P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P271 Use only outdoors or in a well-ventilated area. P284 Wear respiratory protection P273 Avoid release to the environment.

Response

P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352 IF ON SKIN: wash with plenty of soap and water. P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P301 + P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P330 Rinse mouth. P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention. P362 + P364 take off contaminated clothing and wash it before reuse. P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 IF eye irritation persists: Get medical advice/attention. P308 + P313 IF exposed or concerned: Get medical advice/attention. P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.

Storage

P403 + P233 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/container to a waste disposal facility in accordance with local, state, federal or international laws

HMIS® ratings

HEALTH: 3 FLAMMIBILITY: 1 REACTIVITY: 1 PERSONAL PROTECTIVE EQUIPMENT: G

Potential health effects

EYES: CAN CAUSE SEVERE IRRITATION ,REDNESS, TEARING, OR BLURRED VISION AS WELL AS CORNEAL OPACITY AND CONJUNTIVITIS. SKIN: MAY CAUSE IRRITATION, DEFATTING AND DERMATTITIS. INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITTING, DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. CAN CAUSE CORROSIVE ACTION TO THE MUCOUS MEMBRANES AND DIGESTIVE TRACTS. INHALATION: CAN CAUSE NAUSEA AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, HEADACHE, AND POSSIBLE UNCONSCIOUSNESS. BURNING SENSATION TO MUCOUS MEMBRANES, SHORTNESS OF BREATH AND FLU LIKE SYMPTOMS MAY OCCUR. HEALTH HAZARDS (ACUTE AND CHRONIC): CAN CAUSE SENSITIZATION BY EXPOSURE THROUGH CONTACT OR HIGH CONCENTRATIONS OF VAPOR. OVER-EXPOSURE TO THIS MATERIAL CAN CAUSE CARDIAC ABNORMALITIES. OVEREXPOSURE CAN POSSIBLY CAUSE ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE, OR EYE DAMAGE. MAY CAUSE ASTHMA OR OTHER RESPIRATORY DISORDERS, BRONCHITIS, EMPHYSEMA, HYPERACTIVITY, AND ECZEMA. Chronic Inhalation: as a result of previous repeated overexposures or a single large dose of isocyanates, certain individuals will develop isocyanate sensitization (chemical asthma), which will cause them to react to a later xposure to isocyanate at levels well below the TLV or MGL. These symptoms, which include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed up to several hours after exposure. Similar to many nonspecific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air, or other irritants. This increased lung sensitivity can persist for weeks and in several years. Chronic overexposure to isocyanates has been reported to cause lung damage, including decrease in lung function, which may be permanent. Sensitization may either be temporary or permanent. Acute skin Contact: Isocyanates react with the skin protein and moisture and can cause irritation. Symptoms of skin irritation may be reddening, swelling, rash, scaling, or blistering. Some persons may develop skin sensitization from skin contact. Chronic Skin contact: Prolonged contact with the isocyanate can cause reddening, swelling, rash, scaling, or blistering. In those who have developed a skin sensitization, these symptoms can develop as a result of contact with very small amounts of liquid material or even as a result of vapor-only exposure.

Medical Conditions Generally Aggravated by Exposure

RESPIRATORY CONDITIONS OR OTHER ALLERGIC AILMENTS CARCINOGENICITY OSHA: NO NTP: Yes IARC: Yes ADDITIONAL CARCINOGENICITY INFORMATION: Product may contain ethyl benzene as a component of xylene (IARC 2B).