Interior Eggshell Acrylic Water Base Enamel High Hide White

Hazard statements (CLP)

H350, H373

Code

Statements

H350

May cause cancer

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1.2% (dermal), 1.2% (inhalation) GHS label elements Hazard pictograms Signal word _ : Danger Hazard statements : May cause cancer. May cause damage to organs through prolonged or repeated exposure. Precautionary stat nts General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Do not breathe vapor. Response : IF exposed or concerned: Get medical advice or attention. Date of issue/Date of revision : 6/10/2023 Date of previous issue 1 8/2/2023 Version :20.02 V/13 150(11) Section 4. First aid measures Ingestion : Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the ao, exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects. acute and delayed Potential acute health effects Eye contact. : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Indication of immediate medical attention and special treatment needed. if necessary Notes to physician _ 2 Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. f Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media Specific hazards arising : Ina fire or if heated, a pressure increase will occur and the container may burst. from the chemical Hazardous thermal ; Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide metal oxide/oxides \pecial protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if ‘or fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Date of issue/Date of revision : 6/10/2023 Date of previous issue 18/2/2023 Version ;20.02 313 150(11) Section 7. Handling and storage Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from Including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible g (see Section 10) and food and drink. Store locked up. Keep container tightly closed : ~ rompatibilities materials and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits (OSHA United States} Ingredient name CAS # Exposure limits Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018). TWA: 15 mg/m? 8 hours. Form: Total dust ACGIH TLV (United States, 1/2022). TWA: 2.5 mg/m® 8 hours. Form: respirable fraction, finescale particles Ethylene Glycol 107-21-1 ACGIH TLV (United States, 1/2022). STEL: 10 mg/m? 15 minutes. Form: Inhalable fraction. Aerosol only. STEL: 50 ppm 15 minutes. Form: Vapor fraction TWA: 25 ppm 8 hours. Form: Vapor fraction Heavy Paraffinic Oil 64742-65-0 ACGIH TLV (United States, 1/2022). [Mineral Oil, pure, highly and severely refined] TWA: 5 mg/m® 8 hours. Form: inhalable fraction OSHA PEL (United States, 5/2018). [Oil mist, mineral] TWA: 5 mg/m 8 hours. NIOSH REL (United States, 10/2020). [OIL MIST MINERAL] TWA: 5 mg/m* 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist Cristobalite, respirable powder 14464-46-1 OSHA PEL Z3 (United States, 6/2016). TWA: 250 mppef / 2 x (%SiO2+5) 8 hours. Form: Respirable TWA: 10 mg/m / 2 x (%SiO2+2) 8 hours. Form: Respirable TWA: 30 mg/m / 2 x (%SiO2+2) 8 hours. Form: Total dust OSHA PEL (United States, 5/2018). [Silica, crystalline] TWA: 50 yg/m? 8 hours. Form: Respirable dust ACGIH TLV (United States, 1/2022). [Silica, crystalline] TWA: 0.025 mg/m? 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2020). [SILICA, CRYSTALLINE (AS RESPIRABLE DUST)] TWA: 0.05 mg/m? 10 hours. Form: respirable dust Date of issue/Date of revision : 6/10/2023 Date of previous issue 1 8/2/2023 Version : 20.02 5/13 #50(11) Section 8. Exposure controls/personal protection Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, controls local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. =<nvironmental exposure - Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection : Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according toa respiratory protection program to ensure proper fitting, training, and other important aspects of use. Section 9. Physical and chemical properties The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. earance Physical state : Liquid. Color : Not available. Odor : Not available. Odor threshold : Not available. pH >: 9 Melting pointifreezing point : Not available. Boiling point, initial boiling =: 100°C (212°F) point, and boiling range Flash point : Closed cup: Not applicable. -vaporation rate : Q.09 (butyl acetate = 1) Flammability : Not available. Date of issue/Date of revision : 6/10/2023 Date of previous issue ? 5/2/2023 Version : 20.02 7/143 150(11) Section 11. Toxicological information Product/ingredient name Result Species Score Exposure Observation ‘I Titanium Dioxide Skin - Mild irritant Human : 72 hours 300 | - . | ug | Ethylene Glycol! Eyes - Mild irritant Rabbit - 1 hours 100 | - mg Eyes - Mild irritant Rabbit - 24 hours 500 | - mg Fyes - Moderate irritant Rabbit - 6 hours 1440 |- mg Skin - Mild irritant Rabbit - 555 mg - Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Classification Productlingredient name |OSHA IARC NTP Titanium Dioxide - 2B - >| Cristobalite, respirable - 1 Known to be a human carcinogen. powder Reproductiv ici Not available. atogenicit Not available. ecific target organ toxicity (single exposure Name Category Route of Target organs exposure Ethylene Glycol Category 3 - Respiratory tract irritation Category 3 Narcotic effects Specific target organ toxicity (repeated exposure) Name Category Route of Target organs exposure Ethylene Glycol Category 2 - . Cristobalite, respirable powder Category 1 inhalation respiratory tract spiration haz Name Result Heavy Paraffinic Oil ASPIRATION HAZARD - Category 1 Information on the likely =: Not available. routes of exposure Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Date of issue/Date of revision : 6/10/2023 Date of previous issue ‘5/2/2023 Version :20.02 9/13 150(11) Section 12. Ecological information Product/ingredient name Aquatic half-life Photolysis Biodegradability c thylene Glycol Readily Bioaccumulative potential Not available. obility in soil Soil/water partition : Not available. coefficient (Koc) Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains ( and sewers. |Section 14. Transport information DOT TDG Mexico IATA IMDG Classification UN number Noi regulated. Not regulated. UN proper shipping name Transport hazard class(es) Packing group Environmental No. hazards Additional information Date of issue/Date of revision : 6/10/2023 Date of previous issue 3/2/2023 Version : 20.02 11/13 150(11) Section 16. Other information Classification Justification y CARCINOGENICITY - Category 1A Calculation method . 3PECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) i - Category 2 Calculation method History . Date of printing : 6/10/2023 Date of issue/Date of : 6/10/2023 revision Date of previous issue : 5/2/2023 Version : 20.02 Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United. Nations Indicates information that has changed from previously issued version. Notice to reader It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, aS necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate 48 of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision : 6/10/2023 Date ofpreviousissue _ 7 5/2/2023 Version :20.02 13/13 150(41)

Signal word

_ Danger

Hazard statements

May cause cancer. May cause damage to organs through prolonged or repeated exposure. Precautionary stat nts General Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Do not breathe vapor.

Response

IF exposed or concerned: Get medical advice or attention. Date of issue/Date of revision 6/10/2023 Date of previous issue 1 8/2/2023 Version :20.02 V/13 150(11)