Apafix

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP shoes. Consult a physician if discomfort continues. Classification of the substance or mixture If swallowed: Clean mouth with water and drink afterwards

2.2 Label elements

The most important symptoms and effects are described in

Hazard statements

4.3 Indication of any immediate medical attention and NC Not Classified special treatment needed

Precautionary statements

Notes to physician: Treat symptomatically. Have facilities in P261 – Avoid breathing vapour/spray place to wash skin and eyes in case of exposure. Severe cases P280 - Wear protective gloves/protective clothing/eye of exposure should receive prompt medical attention. protection/face protection. Eye contact – May cause eye irritation. May cause redness.

Contains

Acetic Acid Skin Contact – May irritate the skin.

2.3 Other hazards

No data available. Ingestion – May irritate the mouth and throat. Small amounts will leave taste in mouth, larger amounts may cause nausea

2.1 Classification of the substance or mixture

If swallowed: Clean mouth with water and drink afterwards Classification according to Regulation (EC) No 1272/2008 plenty of water. Consult a physician. [CLP]: If inhaled: Move to fresh air. Consult a physician if discomfort The mixture does not present a physical or chemical hazard. continues. See Section 16 for the full text of H-Statements mentioned in 4.2 Most important symptoms and effects, both acute and this section. delayed 2.2 Label elements The most important symptoms and effects are described in Labelling according to Regulation (EC) No 1272/2008 [CLP] the labelling Section 2.2 and/or Section 11. Hazard statement(s) 4.3 Indication of any immediate medical attention and NC Not Classified special treatment needed Precautionary statements: Notes to physician: Treat symptomatically. Have facilities in P261 – Avoid breathing vapour/spray place to wash skin and eyes in case of exposure. Severe cases P280 - Wear protective gloves/protective clothing/eye of exposure should receive prompt medical attention. protection/face protection. Eye contact – May cause eye irritation. May cause redness. Contains Acetic Acid Skin Contact – May irritate the skin. 2.3 Other hazards No data available. Ingestion – May irritate the mouth and throat. Small amounts will leave taste in mouth, larger amounts may cause nausea SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS and vomiting. 3.2 Mixtures Inhalation – Acute: May irritate the respiratory system and Hazardous ingredients according to Regulation (EC) cause coughing. Delayed: Prolonged exposure to vapours or No 1272/2008 mists can cause damage to the mucous membranes of the Component: Acetic Acid respiratory system. CAS No: 64-19-7 EC No: 200-580-7 SECTION 5 FIRE FIGHTING MEASURES Index No: 607-002-00-6 5.1 Extinguishing media Registration No: - This product is non-combustible. Water spray, dry powder, Classification: Skin Corr. 1A (H314), Flam. Liq. 3 (H226), Eye carbon dioxide or alcohol resistant foam. Dam. 1 (H318) 5.2 Special hazards arising from the substance or mixture Concentration: < 10% In case of fire, toxic or irritating fumes or vapours may be Component: Menthol formed. Contact with metals may form hydrogen gas which is CAS No: 89-78-1 flammable and can result in explosion. EC No: 201-939-0 5.3 Advice for firefighters Index No: 603-001-00-x Wear self-contained breathing apparatus for firefighting. Registration No: 01-2119433307-44-xxxx Classification: Flam. Liq. 2 (H225), Acute Tox 3 (H301 + H311 + H331), STOT SE 1 (H370) Concentration: < 1% SECTION 6: ACCIDENTAL RELEASE MEASURES Acetic Acid 6.1 Personal precautions, protective equipment and 64-19-7 emergency procedures Germany STEL: 20ppm Use personal protective equipment, gloves and protective eye STEL: 50 mg/m3 glasses. Ensure adequate ventilation, especially in confined TWA: 10ppm areas. TWA: 25 mg/m3 6.2 Environmental precautions Ireland STEL: 15ppm Should not be released into the environment. Prevent product STEL: 37 mg/m3 from entering drains. Prevent further leakage or spillage if safe TWA: 10ppm to do so. TWA: 25 mg/m3 6.3 Methods and material for containment and cleaning up Italy TWA: 10ppm Absorb spill with inert material (e.g. dry sand or earth), then TWA: 25 mg/m3 place in a chemical waste container. After cleaning, flush away Poland STEL: 30 mg/m3 traces with water. TWA: 15 mg/m3 Portugal STEL: 10ppm 6.4 Reference to other sections TWA: 10ppm For disposal, see Section 13. TWA: 25 mg/m3 Spain STEL: 15ppm SECTION 7: HANDLING AND STORAGE STEL: 37 mg/m3 7.1 Precautions for safe handling TWA: 10ppm Do not breathe vapours or spray mist. Ensure that ventilation TWA: 25 mg/m3 is adequate before using this product. Avoid contact with skin Sweden STEL: 10ppm and eyes. Take necessary personal protective precautions STEL: 25 mg/m3 before using this product. Keep away from heat and flame. TWA: 5ppm 7.2 Conditions for safe storage, including any TWA: 13 mg/m3 incompatibilities Store in a cool place. Keep container tightly closed in a dry 8.2 Exposure controls well-ventilated place. Containers which are opened must be 8.2.1 Appropriate Engineering Controls carefully resealed and kept upright to prevent leakage. Handle in accordance with good industrial hygiene and safety 7.3 Specific end use(s) The identified uses for this product are detailed in Section 1.2. practice. Wash hands before breaks and at the end of the workday. Ensure adequate ventilation, especially in confined SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION areas. 8.1 Control parameters 8.2.2 Personal protective equipment This product, as supplied, does not contain any hazardous (a) Eye/face protection: Tightly fitting safety goggles. Face materials with occupational exposure limits established by the shield (8-inch minimum). Use equipment for eye protection region specific regulatory bodies. tested and approved under appropriate government Acetic Acid standards such as NIOSH (US) or EN 166(EU). 64-19-7 (b) Skin protection: Handle with gloves. Gloves must be Austria STEL: 20ppm inspected prior to use. Use proper glove removal technique STEL: 50mg/m3 (without touching glove's outer surface) to avoid skin contact TWA: 10ppm with this product. Dispose of contaminated gloves after use in TWA: 25 mg/m3 Belgium STEL: 15ppm accordance with applicable laws and good laboratory STEL: 38 mg/m3 practices. Wash and dry hands. The selected protective TWA: 10ppm gloves should satisfy the specifications of EU Directive TWA: 25mg/m3 89/686/EEC and the standard EN 374 derived from it. Denmark STEL: 20ppm (c) Body Protection: Complete suit protecting against STEL: 50 mg/m3 chemicals. The type of protective equipment must be selected TWA: 10ppm according to the concentration and amount of the dangerous TWA: 25 mg/m3 substance at the specific workplace. France STEL: 10ppm (d) Respiratory protection: Where risk assessment shows air- STEL: 25 mg/m3 purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face SECTION 11: TOXICOLOGICAL INFORMATION supplied air respirator. Use respirators and components tested 11.1 Information of toxicological effects Acute toxicity: and approved under appropriate government standards such Product: The mixture has not been tested for toxicological as NIOSH (US) or CEN (EU). properties. This information refers to acetic acid as a pure 8.2.3 Environmental exposure controls substance. See section 6.2 Inhalation: Industry – Dermal; Long term systemic effects 22mg/kg/day Haematological effects SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Eye contact: no data available 9.1 Information on basic physical and chemical properties Skin contact: no data available a) Appearance: Form: liquid Ingestion: Sodium salt of acetic acid, pH 6-7 Colour: Clear Skin corrosion/irritation: Dose: 0.5ml, 4 hr, Rabbit Primary b) Odour: pungent/acetic acid + distinct thyme smell dermal irritation index: 1.1 OECD Guideline 404 10% solution. c) Odour threshold: no data available Slightly irritating. d) pH: <1 Serious eye damage/eye irritation: OECD 405, e) Melting point / freezing point: no data available rabbit, 10% solution, 4 hour, 0.1ml. Erythema = f) Initial boiling point / boiling range: no data available g) Flash point: Not applicable. The mixture is non-flammable. 2.67, corneal swelling = 87%. h) Evaporation rate: no data available Respiratory or skin sensitisation: no data available i) Flammability (solid, gas): no data available Germ cell mutagenicity: no data available j) Upper/lower flammability or explosive limits: Not Carcinogenicity: no data available applicable. The mixture is non-flammable. Reproductive toxicity: no data available k) Vapour pressure: no data available Specific target organ toxicity - single exposure: no data l) Vapour density: no data available available m) Relative density: no data available Specific target organ toxicity - repeated exposure: no data n) Solubility (ies): soluble in water available o) Partition coefficient: n-octanol/water: no data available Aspiration hazard: no data available p) Auto-ignition temperature: no data available q) Decomposition temperature: no data available SECTION 12: ECOLOGICAL INFORMATION r) Viscosity: no data available 12.1 Toxicity s) Explosive properties: no data available The mixture has not been tested for ecotoxicological t) Oxidising properties: no data available properties. 9.2 Other information The following information contained in section 12 refers to No data available acetic acid as a pure substance. Acute toxicity – fish: LC50, 96 hours: > 1000 mg/l, Onchorhynchus mykiss (Rainbow trout) SECTION 10: STABILITY AND REACTIVITY OECD 203 (Fish, Acute Toxicity Test) 10.1 Reactivity Freshwater, semi-static. Reactions characteristic of weak acids. Mortality 10.2 Chemical stability Acute toxicity – aquatic invertebrates: EC₅₀, 48 hours: > Stable under recommended handling and storage conditions 300.82 mg/l, Daphnia magna under Section 7. OECD Guideline 202. 10.3 Possibility of hazardous reactions Static, freshwater. May react vigorously or exothermically. Pressure may build up Mobility. if reaction occurs in a sealed container. Will not polymerise. Test substance potassium acetate; result based on the acetate 10.4 Conditions to avoid ion. Avoid heat, direct sunlight and moisture. Avoid storage in Acute toxicity – aquatic plants: EC₅₀, 72 hours: > 300.82 mg/l, freezing conditions. Avoid storage with incompatible Static, saltwater, Skeletonema costatum. materials. Avoid storage in an unstable manner or in a Test substance potassium acetate; result based on the acetate situation that would result in exposure to the product. It is ion. advisable to store the product within some form of Acute toxicity – microorganisms: EC₅₀: 850 mg/l, Industry - containment to prevent spillages reaching drainage systems. Dermal; Long term systemic effects 22 mg/kg/day 10.5 Incompatible materials Pseudomonas putida, static, freshwater, 16 hour Alkalis. Oxidising agents. Metals. Acute toxicity – terrestrial: Not available. 10.6 Hazardous decomposition products Chronic toxicity – fish early life stage: Not available. Under normal use – none Short term toxicity – embryo and sac fry stages: Industry - amended). Dermal; Long term systemic effects 22 mg/kg/day Regulation (EC) No 1272/2008 of the European No supplied or registered information. Parliament and of the Council of 16 December 2008 on Chronic toxicity – aquatic invertebrates: Not available. classification, labelling and packaging of substances and Toxicity to soil: Not available. mixtures (as amended). Toxicity to terrestrial plants: Not available. Regulation (EU) 453/2010. 12.2 Persistence and degradability 15.2 Chemical Safety Assessment Phototransformation: Water - DT₅₀: 26.7 days A chemical safety assessment was not carried out for this Degradation by hydroxyl radicals. mixture. Calculated value. Stability (hydrolysis): Scientifically unjustified. SECTION 16: OTHER INFORMATION Biodegradation: Water – Degradation (%) 96%: 20 days The information in this datasheet is based on our current level Readily biodegradable – Half life: 2 days of knowledge and on national and international regulations. Biological oxygen demand: No information available. The mixture must not be used for other purposes than those Chemical oxygen demand: No information available. specified in Section 1. It is at all times the responsibility of the 12.3 Bioaccumulative potential use to take all necessary measures to comply with legal BCF: 3.16, QSAR calculation. Fish, freshwater. Not requirements and local regulations. The information in this bioaccumulating. safety data sheet must be regarded as a description of the 12.4 Mobility in soil safety requirements relating to the mixture and not as a No information available. 12.5 Results of PBT and vPvB assessment guarantee of the properties thereof. PBT or vPvB not classified according to current EC criteria. 12.6 Other adverse effects Full text of H-Statements referred to under sections 2 and 3 No information available. H226 – Flammable liquid and vapour 12.7 Additional information H314 - Causes severe skin burns and eye damage No information available. H318 - Causes serious eye damage P261 – Avoid breathing vapour/spray SECTION 13: DISPOSAL CONSIDERATIONS P280 - Wear protective gloves/protective clothing/eye Proper waste management of the mixture and its container protection/face protection. must be determined in accordance with directive The above information is believed to be correct but does not 2008/98/EC. purport to be all inclusive and shall be used as a guide. Apacor 13.1 Waste treatment methods shall not be held liable for any damages resulting from 13.1.1 Product/packaging disposal handling or from contact with the above product, since the Do not pour into drains or waterways. Recycle of dispose of user’s working conditions are not known by Apacor. waste in compliance with current, local legislation, preferably via a certified waste company. MDSS GmbH SECTION 14: TRANSPORT INFORMATION Schiffaraben 41 IATA/DOT/IMDG/TDG - Not regulated 30175 Hanover 14.1 UN number: Not applicable 14.2 UN proper shipping name: Not applicable Germany 14.3 Transport hazard class(es): Not applicable 14.4 Packing group: Not applicable 14.5 Environmental hazards: Not applicable 14.6 Special precautions for user: Not applicable SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/ legislation specific for the substance or mixture National regulations: Industry – Dermal; Long term systemic effects 22mg/kg/day EU legislation: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as SECTION 1 IDENTIFICATION OF THE SUBSTANCE/ MIXTURE P501 Dispose of contents/container in accordance with AND THE COMPANY/UNDERTAKING national regulations. 1.1 Product Identifier: Ethyl Acetate Supplemental Label Information 145003, 145400, 145420, 145501, 145900, 146004, 146400, EUH066 Repeated exposure may cause skin dryness or 146501, 1473, 900000, 901000, 903000, 905000, 906000, cracking. 908000 2.3 Other hazards Synonyms, Trade Names: ETHYL ACETATE 98 - 100%, ACETIC Not classified as PBT/vPvB by current EU criteria. ACID ETHYL ESTER, ACETOXYETHANE REACH Registration Number: 01-2119475103-46-XXXX SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS CAS-No: 141-78-6 3.1 Substances EU Index No: 607-022-00-5 Hazardous ingredients according to Regulation (EC) No EC No: 205-500-4 1272/2008 1.2 Relevant identified uses of the substance or mixture and Product Name: ETHYL ACETATE uses advised against: laboratory chemical for the removal of REACH Registration Number: 01-2119475103-46-XXXX fat from faecal samples. CAS-No: 141-78-6 1.3 Details of the supplier of the Safety Data Sheet: Apacor EU Index No: 607-022-00-5 Limited, Unit 5 Sapphire Centre, Fishponds Road, Wokingham, EC No: 205-500-4 Berkshire, RG41 2QL, United Kingdom Composition Comments: The data shown are in accordance +44 (0) 118 979 5566 with the latest EC Directives. technical@apacor.com SECTION 4 FIRST AID MEASURES 1.4 Emergency telephone number: 4.1 Description of first aid measures +44 (0)118 979 5566 Consult a physician. Show this safety data sheet to the doctor (Monday-Friday 0900-1700 excluding UK Public Holidays) in attendance. SECTION 2 HAZARDS IDENTIFICATION If inhaled: Remove affected person from source of 2.1 Classification of the substance or mixture contamination. Get medical attention if any discomfort continues. Classification according to Regulation (EC) No 1272/2008 [CLP]: In case of skin contact: Remove contaminated clothing Flam. Liq. 2 - H225 immediately and wash skin with soap and water. Get medical STOT SE 3 - H336 attention if any discomfort continues. Eye Irrit. 2 – H319 In case of eye contact: Rinse immediately with plenty of See Section 16 for the full text of H-Statements mentioned in water. Remove any contact lenses and open eyelids wide this Section. apart. Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP] If swallowed: Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Rinse mouth thoroughly with water. Give plenty of water to Pictogram drink. Get medical attention if any discomfort continues. Signal word Danger 4.2 Most important symptoms and effects, both acute and Hazard Statements delayed H225 Highly flammable liquid and vapour. If inhaled: Central nervous system depression including H319 Causes serious eye irritation. narcotic effects such as drowsiness, narcosis, reduced H336 May cause drowsiness or dizziness. alertness, loss of reflexes, lack of coordination and vertigo. Precautionary Statements In case of skin contact: Prolonged contact may cause redness, P210 Keep away from heat/sparks/open flames/hot surfaces. irritation and dry skin. No smoking. P261 Avoid breathing vapour/spray. In case of eye contact: May cause temporary eye irritation. P303+361+353 IF ON SKIN (or hair): Take off immediately all 4.3 Indication of any immediate medical attention and contaminated clothing. Rinse skin with water/shower. special treatment needed P304+340 IF INHALED: Remove person to fresh air and keep Notes for doctor: No specific recommendations. If in doubt, get comfortable for breathing. medical attention promptly. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. SDS020 v7.7 – 26/01/2021 SECTION 5 FIRE FIGHTING MEASURES PNEC Freshwater 0.26 PNEC Soil 0.22mg/kg 5.1 Extinguishing Media: Suitable extinguishing media: PNEC Sediment 0.34mg/kg alcohol-resistant foam, carbon dioxide, dry powder or water PNEC STP 650mg/l fog. 8.2 Exposure controls 5.2 Special Hazards Arising from the Substance or Mixture 8.2.1 Appropriate engineering controls Specific Hazards: Carbon oxides. Handle in accordance with good industrial hygiene and safety 5.3 Advice for Fire-fighters practice. Wash hands before breaks and at the end of workday. Protective Equipment for Fire-fighters: Positive-pressure self- 8.2.2 Personal protective equipment contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6 ACCIDENTAL RELEASE MEASURES (a) Eye/face protection: Tightly fitting safety goggles. 6.1 Personal precautions, protective equipment and Faceshield (8-inch minimum). Use equipment for eye emergency procedures protection tested and approved under appropriate Follow precautions for safe handling described in this safety government standards such as NIOSH (US) or EN 166(EU). data sheet. Take precautionary measures against static discharges. Avoid inhalation of vapours and contact with skin (b) Skin protection: Handle with gloves. Gloves must be and eyes. inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact 6.2 Environmental precautions with this product. Dispose of contaminated gloves after use in Spillages or uncontrolled discharges into watercourses must accordance with applicable laws and good laboratory be immediately alerted to the Environmental Agency or other practices. Wash and dry hands. The selected protective appropriate regulatory body. gloves should satisfy the specifications of EU Directive 6.3 Methods and material for containment and cleaning up 89/686/EEC and the standard EN 374 derived from it. Butyl Absorb spillage with inert, damp, non-combustible material. rubber gloves are recommended. Flush contaminated area with plenty of water. Collect and (c) Body Protection: Complete suit protecting against place in suitable waste disposal containers and seal securely. chemicals. The type of protective equipment must be selected For waste disposal, see Section 13. according to the concentration and amount of the dangerous 6.4 Reference to other sections substance at the specific workplace. Other Protection: Wear Wear protective clothing as described in Section 8 of this rubber apron. Wear rubber footwear. safety data sheet. (d) Respiratory protection: Where risk assessment shows air- purifying respirators are appropriate use a full-face respirator SECTION 7 HANDLING AND STORAGE with multi-purpose combination (US) or type ABEK (EN 14387) 7.1 Precautions for safe handling respirator cartridges as a backup to engineering controls. If Avoid spilling. Avoid contact with skin and eyes. Keep away the respirator is the sole means of protection, use a full-face from heat, sparks and open flame. Provide adequate supplied air respirator. Use respirators and components tested ventilation. and approved under appropriate government standards such 7.2 Conditions for safe storage, including any as NIOSH (US) or CEN (EU), fitted with type A2 gas filter incompatibilities cartridge. Storage precautions: Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep away from heat, SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES sparks and open flame. 9.1 Information on basic physical and chemical properties Storage class: Flammable liquid storage. a) Appearance Form: colourless liquid 7.3 Specific end use(s) b) Odour Fruity The identified uses for this product are detailed in Section 1.2. c) Odour threshold no data available SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION d) pH no data available 8.1 Control parameters e) Melting point / freezing point -83.8°C Name STD TWA – 8 Hrs STEL – 15 Min Ethyl Acetate WEL 200 ppm 400 ppm f) Initial boiling point and boiling range 76-77°C WEL = Workplace Exposure Limit g) Flash point -4°C closed cup Ingredient Comments h) Evaporation rate 4.5 (diethyl ether=1) DNEL Industry Inhalation. 1468 mg/m3 DNEL Consumer Inhalation. 734 mg/m3 i) Flammability (solid, gas) no data available DNEL Industry Dermal Long Term 63mg/kg/day DNEL Industry Inhalation Long Term 734 mg/m3 j) Upper/lower flammability or explosive limits 2.2% lower, DNEL Consumer Dermal Long Term 37mg/kg/day 11.5% upper DNEL Consumer Inhalation Long Term 367mg/m3 SDS020 v7.7 – 26/01/2021 k) Vapour pressure no data available SECTION 12 ECOLOGICAL INFORMATION l) Vapour density 3.04 12.1 Toxicity Ecotoxicity: The product components are not classified as m) Relative density 0.899 – 0.903 @ 20°C environmentally hazardous. However, large or frequent spills n) Solubility (ies) soluble in water may have hazardous effects on the environment. o) Partition coefficient: n-octanol/water 0.68 Toxicity to Fish Ethyl Acetate p) Auto-ignition temperature 427°C LC50 96 hours 230 mg/l Pimephales promelas (Fat-head Minnow) q) Decomposition temperature no data available r) Viscosity 0.4508 mPas @ 20°C Toxicity to Daphnia and other Aquatic Invertebrates Ethyl Acetate NOEC 72 hours > 100 mg/l Daphnia magna s) Explosive properties no data available 12.2 Persistence and degradability t) Oxidising properties no data available The product is readily biodegradable. 9.2 Other information 12.3 Bioaccumulative potential Mol. Weight 88.11 No data available. Partition coefficient: 0.68 SECTION 10 STABILITY AND REACTIVITY 12.4 Mobility in soil 10.1 Reactivity The product is soluble in water. Surface Tension: 24 mN/m 20. No known reactivity hazards associated with this product. 12.5 Results of PBT and vPvB assessment 10.2 Chemical stability Not Classified as PBT/vPvB by current EU criteria. Stable under normal ambient temperature conditions and 12.6 Other adverse effects recommended use. Not determined.