General Information
Revision date
2014-05-25
Product name
Hot Melt Adhesive REF.: 00087
1.2.1 Relevant identified uses
of the subs-
Icons in SDS
Company Information
company name
COMERSIM S.A.U
e-mail address of the competent person responsible for the Safety Data Sheet
export@grupodesa.es
Section 2
2.2 Label elements
1.4. Emergency telephone number: Company phone (M - R 9.00 to 17.00 and F 8.00 to 15.00): +34 948 33 04 12. European Emergency Number (24 hours):
SECTION 2: Hazards identification
IDENTIFICATION › This product is considered not hazard- This product must not be labelled accord- ous according to directive 1999/45/CE. ing to Directive 1999/45/CE. › Caution: Contact with molten adhesive may cause severe thermal burns prolonged
2.3 Other hazards
exposure to adhesive vapours may cause No data available. slight irritation of the eyes, skin or respira- tory system. 3 › Product made from the mixture of differ- › None of the components is classified as COMPOSITION AND INFORMATION ON ent polymeric materials.
Hazardous Ingredients
according to Regu- INGREDIENTS lation (CE) Nº 1907/2006. 4 4.1. Description of first aid measures: 4.2. Most important symptoms and effects, FIRST AID MEASURES › GENERAL CONSIDERATIONS: No both acute and delayed: special safety precaution is needed. Molten › This product is considered not hazard- product may cause severe thermal burns. ous in solid state. › INHALATION: Solid product does not › In molten state, the product may cause emit vapors. Continuous breathing of burns, and after prolonged exposure to vapors above molten product may irritate vapors, it may cause irritation of the respi- mucous membranes. If these symptoms ratory system, eyes or skin. are de- tected, move to fresh air. If symp- toms persist, get medical attention. 4.3. Indication of any immediate medical › EYE CONTACT: Contact with molten attention and special treatment needed: product may cause serious damage to the › No special treatment is needed. eye. Do not remove the product and cool immediately with clean water for at least 15 minutes. Seek medical attention. › SKIN CONTACT: Solid product has no hazards in normal conditions. In case of burn by contact with melted product, immediately flush the melted product on skin with plenty of cold water. Do not use solvents. Do not remove solidified prod- uct because skin can be easily torn. › INGESTION: It is difficult to occur in normal conditions of use. In any case, ingestion of solid product is not expected to be hazardous. If symptoms develop and persist, get medical attention. › NOTE FOR MEDICAL SERVICES: Burns must be treated as thermal burns. The product will remove during the cure, so it is advisable not to remove it immediately after the burn is produced. 5 5.1. Extinguishing media: 5.2. Special hazards arising from the FIREFIGHTING MEASURES › SUITABLE: Dry chemical, carbon dioxi- substance or mixture: de, foam. › Upon decomposition, the product can › UNSUITABLE: Direct application of water emit acetic acid, carbon dioxide, carbon may disperse the product. monoxide and/or low molecular weight hydrocarbons. 5.3. Advice for firefighters: › No special action is needed. 6 6.1. Personal precautions, protective 6.2. Environmental precautions: ACCIDENTAL RELEASE MEASURES equipment and emergency procedures: Isolate the spilled area and do not allow › Avoid contact with melted product ant the material to contaminate ground water inhalation of vapors. Evacuate unprotected system. Avoid dispersion. and untrained personnel from hazard area. › Protective equipment: heat insulating 6.3. Methods and material for contain- gloves and clothes to avoid contact with ment and cleaning up: melted product. If vapors are concentrated, Once cooled, spilled material must be use respiratory protection equipment. scrapped up to prevent slipping, and › Spilled material will cool and solidify. placed in closed containers for disposal. Once cooled, scrape the material up and place in a closed container for disposal. 7 7.1. Precautions for safe handling: 7.2. Conditions for safe storage, including HANDLING AND
Storage
No special caution is needed when using any incompatibilities: the product for its specified use. › Keep the product in its original closed › Recommended application tempera- package. Store the material between 0 ºC ture: 170 - 210 ºC. and 40 ºC. › Avoid direct contact with melted prod- › Prevention of fires and explosions: uct, and follow application temperature Avoid contact with oxidizing agents. recommendation. Minimize dust accumulation. › No eating, drinking or smoking in work- ing areas. 8 8.1. Control parameters: 8.2. Exposure controls: EXPOSURE CONTROLS AND The product does not contain significant › APPROPIATE ENGINEERING CON- PERSONAL amounts of substances with exposure TROLS: work should be done in an PROTECTION limits to be controlled in the working place. adequately ventilated area. Local exhaust › Threshold Limit Value (TLV). ACGIH: ventilation is recommended when general None. ventilation is not sufficient. The air in the › Germany (MAK): None. working area should be renovated at least › United Kingdom (OES): None. 10 times per hour. › Individual protection measures: › EYE AND FACE PROTECTION: not necessary under normal conditions. When potential risk of splashing or spraying of the product exists, wear safety glasses and even full face protection. › SKIN PROTECTION: when pro- longed contact with solid product, use vinyl polychloride or nitrile rubber gloves. Working with molten product, use insulating gloves to prevent burns. › RESPIRATORY PROTECTION: under normal use conditions, airborne exposures are not expected to be significant enough to require respira- tory protection. In case of vapor accu- mulation, use respiratory equipment with A-class filter. › TERMAL HAZARDS: use insulating gloves to prevent burns. 9 9.1. Information on basic physical and chemical properties: PHYSICAL AND CHEMICAL › APPEARENCE: Transparent PROPERTIES › ODOUR: Odorless in solid state Slight characteristic odor in molten state › ODOUR THRESHOLD: Not applicable › pH: Not applicable › MELTING POINT: 85 ºC (softening temperature) › BOILING POINT: Not applicable › FLASH POINT: > 250 ºC (open cup) › EVAPORATION RATE: Not applicable › FLAMMABILITY: Not available › FLAMMABILITY LIMITS: Not available › EXPLOSIVE LIMITS: Not available › VAPOUR PRESSURE: Not applicable › VAPOUR DENSITY: Not applicable › RELATIVE DENSITY: 0,98 › SOLUBILITY IN WATER: Insoluble › PARTITION COEFFICIENT N-OCTANOL / WATER: Not available › AUTO-IGNITION TEMPERATURE: Not available › DECOMPOSITION TEMPERATURE: 220 ºC › VISCOSITY: 10.000 cP a 180 ºC › EXPLOSIVE PROPERTIES: Not applicable 5 / 2014 9 9.2. Other information: