3-Bromo-2-fluoro-5-nitrophenyl methyl sulphone

Hazard statements (CLP)

H302+H312+H332, H315, H319, H335

Code

Statements

H302+H312+H332

Harmful if swallowed, in contact with skin or if inhaled

SECTION 2: Hazards identification

Ingredient(s) with unknown acute toxicity

35.1% (oral), 35.1% (dermal), 61.6% (inhalation) This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).

Signal word

Danger

Hazard statements

Flammable liquid and vapor. Harmful if inhaled. May cause drowsiness or dizziness. May cause cancer.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor.

Response

IF exposed or concerned Get medical advice or attention. IF INHALED Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.

Storage

Store locked up. Store in a well-ventilated place. Keep container tightly closed.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

2.3 Other hazards

Prolonged or repeated contact may dry skin and cause irritation.

2.1 Classification of the substance or mixture

ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 35.1% (oral), 35.1% (dermal), 61.6% (inhalation) This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).