PROTOVIL D4

Hazard statements (CLP)

H314

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) RESPIRATORY PROTECTION contact with eyes and/or ingestion. No chemical safety assessment has been processed for the mixture and the substances it contains. If the threshold value (if available) for one or more of the substances present in the preparation for daily exposure in the workplace or to a 5. Firefighting measures. fraction established by the company’s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2

2.1 Classification of the substance or mixture

11.1. Information on toxicological effects. or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141). The use of respiratory tract protection equipment, such as masks like that indicated above, is necessary to reduce worker exposure in the 5.1. Extinguishing media. Text of hazard (H) indications mentioned in section 2-3 of the sheet: The product is not classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC absence of technical measures. The protection provided by masks is in any case limited. ALLUMINIO CLORURO The product is not classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC SUITABLE EXTINGUISHING MEDIA Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). However, since the product contains hazardous substances in If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, LD50 (Oral): Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). However, since the product contains hazardous substances in The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water. 3450 mg/kg ratto or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, Skin Corr. 1B Skin corrosion, category 1B concentrations such as to be declared in section no. 3, it requires a safety data sheet with appropriate information, compliant to EC Regulation EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half H314 Causes severe skin burns and eye damage.

ECOLOGICAL INFORMATION

1907/2006 and subsequent amendments. None in particular. 1907/2006 and subsequent amendments. mask or mouthpiece (ref. standard EN 138). Text of risk (R) phrases mentioned in section 2-3 of the sheet: EYE PROTECTION

2.2 Label elements

5.2. Special hazards arising from the substance or mixture. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or Use of protective airtight goggles (ref. standard EN 166) recommended. sewers or contaminate soil or vegetation. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE R34 CAUSES BURNS. This product is not subject to hazard labeling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc). 9. Physical and chemical properties. 12.1. Toxicity. supplements. 5.3. Advice for firefighters. Information not available. GENERAL BIBLIOGRAPHY 9.1. Information on basic physical and chemical properties. GENERAL INFORMATION 1. Directive 1999/45/EC and following amendments 12.2. Persistence and degradability. Warning symbols: None. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Appearance Warning symbols: None. 2. Directive 67/548/EEC and following amendments and adjustments liquid Colour Information not available. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament white Hazard sentences (R): None. Odour Hazard sentences (R): None. water used for extinction and the remains of the fire according to applicable regulations. 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament Not available. 12.3. Bioaccumulative potential. Odour threshold. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament Not available. Caution recommendations (S): None. pH. Information not available. Caution recommendations (S): None. Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof 6. Regulation (EC) 453/2010 of the European Parliament Not available. Melting or freezing point. and antistatic), a depressurised mask with facemask covering the whole of the operator’s face or a self-respirator (self-protector) in the event 7. The Merck Index. - 10th Edition Not available. 12.4. Mobility in soil. Initial boiling point. of large quantities of fume. 8. Handling Chemical Safety Not available. Safety data sheet available for professional users on request. Boiling range. Information not available. Safety data sheet available for professional users on request. Not available. 9. Niosh - Registry of Toxic Effects of Chemical Substances Flash point. > 61 °C. 6. Accidental release measures. 10. INRS - Fiche Toxicologique (toxicological sheet) Evaporation Rate Not available.

Results of PBT and vPvB assessment

11. Patty - Industrial Hygiene and Toxicology

2.3 Other hazards

6.1. Personal precautions, protective equipment and emergency procedures. Flammability of solids and gases Information not available. 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Not available. Lower inflammability limit. Not available. Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in 13. ECHA website

Other hazards

Information not available. Upper inflammability limit. Information not available. emergency procedures. Not available. Lower explosive limit. Information not available. Not available.