None

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335

2.1 Classification of the substance or mixture

STOT RE 2, H373 (respiratory system) (as inhalation)

Hazard categories

2,2'-methylenediphenyl diisocyanate

Hazard statements

Registration number (REACH) 01-2119927323-43-XXXX Eye Irrit. 2 H319-Causes serious eye irritation. Index 615-005-00-9 STOT SE 3 H335-May cause respiratory irritation. EINECS, ELINCS, NLP, REACH-IT List-No. 219-799-4 Skin Irrit. 2 H315-Causes skin irritation. CAS 2536-05-2 Resp. Sens. 1

Contains

H334-May cause allergy or asthma 0,1-<1

CLP CLASSIFICATION

Acute Tox. 4, H332 symptoms or breathing difficulties if inhaled. (CLP), M-factors Skin Irrit. 2, H315 Skin Sens. 1 H317-May cause an allergic skin reaction. Eye Irrit. 2, H319 Carc. 2 H351-Suspected of causing cancer. Resp. Sens. 1, H334 Skin Sens. 1, H317 STOT RE 2 H373-May cause damage to organs through Carc. 2, H351 prolonged or repeated exposure by STOT SE 3, H335 inhalation (respiratory system). STOT RE 2, H373 (respiratory system) (as inhalation) 2.2 Label elements Dibutyltin dilaurate Labeling according to Regulation (EC) 1272/2008 (CLP) Registration number (REACH) 01-2119496068-27-XXXX Index 050-030-00-3 EINECS, ELINCS, NLP, REACH-IT List-No. 201-039-8 CAS 77-58-7 content % 0,1-<0,25 Classification according to Regulation (EC) 1272/2008 Muta. 2, H341 (CLP), M-factors Repr. 1B, H360FD Skin Corr. 1C, H314 Aquatic Acute 1, H400 (M=1) Aquatic Chronic 1, H410 (M=1) Skin Sens. 1, H317 Danger STOT SE 1, H370 STOT RE 1, H372 (immune system) Eye Dam. 1, H318 H319-Causes serious eye irritation. H335-May cause respiratory irritation. H315-Causes skin Isophthaloyl dichloride irritation. H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317- Registration number (REACH) 01-2119493993-19-XXXX May cause an allergic skin reaction. H351-Suspected of causing cancer. H373-May cause Index --- damage to organs through prolonged or repeated exposure by inhalation (respiratory system). EINECS, ELINCS, NLP, REACH-IT List-No. 202-774-7 CAS 99-63-8 P201-Obtain special instructions before use. P260-Do not breathe vapours or spray. P280-Wear content % <0,25 protective gloves / protective clothing / eye protection / face protection. P284-Wear respiratory Classification according to Regulation (EC) 1272/2008 Acute Tox. 4, H312 protection. (CLP), M-factors Acute Tox. 3, H331 P302+P352-IF ON SKIN Wash with plenty of water / soap. P304+P340-IF INHALED Remove Skin Corr. 1A, H314 person to fresh air and keep comfortable for breathing. P305+P351+P338-IF IN EYES: Rinse Eye Dam. 1, H318 cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313-IF exposed or concerned: Get medical advice / attention. For the text of the H-phrases and classification codes (GHS/CLP), see Section 16. The substances named in this section are given with their actual, appropriate classification! EUH204-Contains isocyanates. May produce an allergic reaction. For substances that are listed in appendix VI, table 3.1 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may be given here for the named classification have been taken into account. Dibutyltin dilaurate SECTION 4: First aid measures Diphenylmethanediisocyanate, isomeres and homologues 4,4'-methylenediphenyl diisocyanate o-(p-isocyanatobenzyl)phenyl isocyanate 4.1 Description of first aid measures 2,2'-methylenediphenyl diisocyanate First-aiders should ensure they are protected! General hygiene measures for the handling of chemicals are applicable. Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Wash hands before breaks and at end of work. Revision date / version: 25.04.2019 / 0014 Keep away from food, drink and animal feedingstuffs. Replacing version dated / version: 08.01.2019 / 0013 Remove contaminated clothing and protective equipment before entering areas in which food is consumed. Valid from: 25.04.2019