DIATOMACEOUS self-contained Does - The

CLP) «για την τροποποίηση της οδηγίας

Revision date : 2023-07-12

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GHS08 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

272-489-0/68855-54-9

Name of the chemical

diatomaceous earth, soda ash flux-calcined

Concentration

66≤x<70

EC/CAS

215-222-5/1314-13-2

Name of the chemical

Zinc oxide; C.I. 77947

Concentration

1≤x<1,5

General Information

Version

6

Revision date

2023-07-12

Product name

DIATOMACEOUS self-contained Does - The

Substance name

properties

Icons in SDS

GHS07 GHS08 M004 M008 M009 M010 M011 M017

Company Information

company name

CLP) «για την τροποποίηση της οδηγίας

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H302, H315, H318, H319, H335, H373, H400, H410, H412

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Properties toxicological Seveso Category effects - Directive of exposure 2012/18/EU: to the product. Value None Information INDEX HUN - suitability Appearance CAS: Normal Chemical and value thoroughness in Abstract marine Magyarország Service water of provided Number 66 ≤ information x Az < 70 innovációért according és STOT powder technológiáért to each RE specific 2 H373 felelős use of miniszter the product. 5/2020. (II. 0,9 6.) ITM rendelete mg/l a kémiai kóroki 12.5. EC Product name REPRODUCTIVE - This CE50: Results Normal document Effective value of PBT must 272-489-0 for concentration TOXICITY and fresh not vPvB be water regarded assessment (required sediment as a to guarantee tényezők induce a hatásának ALGINMAJOR-ALGINMAX-ALGINKID-ALGENIUX-ALGINPLUS 50% on any effect) specific kitett product munkavállalók property. egészségének és biztonságának 0,766 védelméről mg/kg 2.1. 11.1. Colour Restrictions Classification Information relating on of hazard the to the substance product classes or or as contained mixture defined in substances Regulation white pursuant

Environmental hazards

pracy formation of are dust systemic 324 (EU) mg/kg 2017/745 (Class I) given in sections 11 and 12 of this sheet systemic local systemic CAS ROU Does Based Chemical Wear Upper Information IATA Inhalation not DGR suitable explosive on meet the and International on protective available physical likely the 16919-27-0 limit routes equipment classification România hazards data, Air Transport of exposure the criteria Product product Association including personal for classification does this Hotărârea not hazard contain Dangerous not protective nr class derives available equipment referred to under Section 8 of the safety data sheet) to prevent 53/2021 substances from Goods pentru criteria Regulation listed modificarea established in the main hotărârii 2,5 by European the guvernului CLP lists Regulation, of 2,5 nr. potential 1.218/2006, Annex or 1,5 suspected I, Part precum The endocrine și 1,5 pentru data for Identified REACH disruptors evaluation IC50: Immobilization Reg with Uses of chemical-physical environmental effects under modificarea 01-2119978268-20-XXXX Concentration properties 50% are reported in section 9 evaluation. Industrial și completarea hotărârii guvernului Professional mg/m3 nr. 1.093/2006 mg/m3 Consumer mg/m3 Hazard any Flash Substances Dental contamination point classification in Candidate device of and skin, indication List eyes (Art. and 59 personal REACH) clothing. not These applicable indications apply for both processing staff and those involved in emergency SU: 10 SWE STOT - medical SODIUM Health IMDG: hazards REPEATED International PHOSPHATE Product EXPOSURE Sverige Maritime TRIBASIC classification Code ANHYDROUS for is dangerous based on calculation Hygieniska gränsvärden, goods methods as per Annex I of föreskrifter procedures Auto-ignition Information On Specific Arbetsmiljöverkets the basis target not temperature of available available organ toxicity CLP, Part och data, the 3, unless repeated product exposure, allmänna determined does not not råd om hygieniska contain otherwise in Section available any SVHC in H373 percentage ≥ than ERC: 2, 3 May cause 0,1%. damage to organs through prolonged or 12.7. INDEX IMO Decomposition Other category 2 temperature International adverse effects Maritime Organization ≤ x < gränsvärden 1,5 not available AFS Eye 2018:1) Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335 repeated exposure EC SVK May Environmental INDEX cause Identifier damage hazards 231-509-8 in to Slovensko Annex organs Product VI of classification CLP DIATOMACEOUS NARIADENIE is based on VLÁDY calculation EARTH, Slovenskej SODA methods ASH republiky as FLUX PROC: 1, 3, 5 per Annex z CALCINATED augusta I of CLP, 2020, Part ktorým 4, unless sa mení determined a dopĺňa otherwise in pH Delayed Substances Environmental Eye irritation, and subject immediate category precautions to authorisation effects as well (Annex as chronic XIV REACH) effects not available from short and H319 long-term exposure PC: 32 Causes serious eye irritation CAS Threshold Information Section Kinematic None Hazardous LC50: Lethal Limit viscosity not Concentration to the aquatic environment, chronic available 7601-54-9 Value 50% nariadenie vlády Slovenskej republiky č. 356/2006 Z. z. o ochrane zdravia zamestnancov pred not available H412 Harmful to aquatic life with long lasting effects REACH ASPIRATION LD50 Type Lethal Reg. HAZARD dose 01-2119489800-32-XXXX 50% Country TWA/8h rizikami súvisiacimi STEL/15min s expozíciou karcinogénnym Remarks a mutagénnym Observations faktorom pri práci v znení The Solubility Information toxicity, product category not must available not 3 penetrate into the sewer system not or available come into contact with surface water or ground water ZINC Changes Partition Substances OEL: OXIDE Occupational coefficient to previous Exposure subject to n-octanol/water review exportation reporting pursuant not Level mg/m3 neskorších ppm to Regulation predpisov available (EU) 649/2012 mg/m3 ppm SECTION INDEX SVN Does The PBT: RCP Details of 13 following not Persistent, TLV meet sections the supplier the 030-013-00-7 Disposal bioaccumulative classification Slovenija were modified of the considerations criteria safety data sheet and 1 ≤ toxic for x < this Pravilnik 1,5 hazard o varovanju class Aquatic delavcev Acute pred 1 H400 tveganji M=1, zaradi RESP Aquatic izpostavljenosti Chronic respirable H410 kemičnim dust M=1 snovem pri delu Vapour Interactive None Methods pressure effects and material for containment and cleaning not available up 13.1. Density EC Predicted 01 PEC Label Waste elements 03 Predicted 08. no-effect and/or treatment relative methods 215-222-5 environmental concentration density Concentration PNEC (Uradni list RS, št. 100/01, 39/05, 53/07, 102/10, 43/11 – ZVZD-1, 38/15, 78/18 in 78/19) 2,29 CAS Name EU PEL Information Normal Predicted value on 1314-13-2 exposure of other STP OEL microorganisms hazards EU level Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) MAJOR PRODOTTI DENTARI S.P.A 100 2019/130; mg/l Directive (EU) Collect Relative Information Substances Full address the vapour leaked not subject available density product to the and Rotterdam place it Convention in containers for not recovery available or disposal. If there are no contraindications, use jets of water to eliminate REACH Health PMT: Persistent, Hazard product Particle Reuse, None Reg labelling when residues characteristics Derived 01-2119463881-32-XXXX possible pursuant Product no-effect mobile and level to EC residues toxic - DNEL / DMEL Regulation should 2019/983; Via Parliament it complies with applicable standards. Fumuri not available acute toxicity, category 1 EC50 - for DIATOMACEOUS Algae / Aquatic Plants Chronic EARTH, SODA ASH FLUX CALCINATED Hazardous to the aquatic Iceland 100 mg/l/72h 354 543 22 chronic 22 toxicity, category 1 Aquatic Provide EC10 for LD50 NGV/KGV Regulation an emergency SWE Crustacea Oral) EU) 2016/1179 shower with IX Atp face CLP) and eye wash station 200 > mg/l/48h 2000 mg/kg rat SECTION Contains: 5. Firefighting (X Atp LC50 8. (Inhalation Exposure The Aquatic Exposure mists/powders) NPEL levels must SVK Regulation powders controls/personal DIATOMACEOUS measures Chronic are potentially EU) 2017/776 be kept as low 1 as possible to avoid significant explosive EARTH, protection Hazardous CLP) SODA when to mixed 2,6 mg/l/4h ASH FLUX the aquatic with Ireland rat CALCINATED air. environment, 35318092566 build-up in the organism chronic toxicity, category 3 RESP Manage personal protective equipment so as to Packing H302 guarantee MV Regulation maximum group EU) 2018/669 SVN protection (XI (e.g Harmful if swallowed. Latvia +371 67032600 Atp. 5 reduction CLP) in replacement times) 20 RESP Persistence and degradability Conditions H373 to media avoid through No prolonged data available or repeated 10.4. HAND Control parameters Extinguishing TLV-ACGIH Regulation PROTECTION ALUMINUM OXIDE EU) 2019/521 (XII May Atp cause CLP) damage to Liechtenstein organs 10 RESP exposure In not the H318 Delegated applicable case of prolonged LD50 (Dermal) Regulation contact UE) 2018/1480 Causes with the serious product, XIII Atp eye protect CLP) Lithuania damage the hands 2,3 mg/kg 370 with 70662008 penetration-resistant work gloves (see standard EN 374) SUITABLE Avoid H319 Work Regulation environmental glove EXTINGUISHING references material EU) 2019/1148 dust build-up must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity EQUIPMENT Causes serious eye Luxembourg irritation Regulatory 352 24785551 Other SODIUM LC50 hazards PHOSPHATE Inhalation TRIBASIC mists/powders) ANHYDROUS 2000 mg/l/4h rat The H315 reactions Delegated Regulation (UE) 2020/217 (XIV Atp. CLP) extinguishing equipment should Causes be of skin the irritation conventional Malta +356 kind: 2395 carbon 2000 dioxide, foam, powder and water spray 14.5. UNSUITABLE Solubility in water Incompatible Environmental H335 EXTINGUISHING materials hazards May EQUIPMENT cause respiratory Netherlands irritation 10000 mg/l 31 88 75 585 61 BGR SKIN Delegated On SKIN Degradability the CORROSION PROTECTION basis of information Regulation available IRRITATION България data, UE) 2020/1182 (XV НАРЕДБА not available the product does not contain any PBT or vPvB in percentage ≥ than 0,1% Atp. CLP) № 13 ОТ 30 ДЕКЕМВРИ 2003 Г. ЗА ЗАЩИТА НА РАБОТЕЩИТЕ ОТ РИСКОВЕ, None H400 Wear 20. Delegated in particular category Regulation II professional UE) long-sleeved 2021/643 (XVI СВЪРЗАНИ Very toxic to aquatic Norway overalls Atp. CLP) and С safety life ЕКСПОЗИЦИЯ 4573580500 footwear (see НА Regulation ХИМИЧНИ 2016/425 АГЕНТИ and ПРИ standard РАБОТА EN (изм ISO ДВ 20344) бр.5 Wash от 17 body Information not H410 with 21. Delegated applicable soap and water not available Regulation after removing UE) 2021/849 Very toxic to aquatic Poland protective XVII clothing Януари Atp. CLP) 2020г.) life with +48 long 42 lasting 2538 effects 400 Special The Does ZINC product H412 hazards arising from Harmful not OXIDE meet does the not classification contain substances criteria for with the substance to aquatic or life mixture this endocrine hazard Portugal class disrupting properties in concentration ≥ 0.1% with long +351213303271 lasting effects CZE EYE 22. Delegated Solubility in water PROTECTION Regulation Česká (UE) Republika 2022/692 (XVIII NAŘÍZENÍ Atp. CLP) VLÁDY ze dne 10. května 2021, kterým se mění nařízení vlády č. 361/2007 Sb., kterým 2,9 mg/l Hazardous decomposition products Wear 23. Delegated airtight protective Regulation goggles UE) 2023/707 see standard se stanoví EN ISO podmínky Romania +40213183606 16321). ochrany zdraví při práci HAZARDS SERIOUS NOT rapidly EYE Use Special descriptor CAUSED precautions degradable system: BY EXPOSURE DAMAGE / IRRITATION for user IN THE EVENT Slovakia OF FIRE +421 2 5465 2307 SECTION DEU RESPIRATORY Composition/information PROTECTION Deutschland Forschungsgemeinschaft on ingredients MAK- und BAT-Werte-Liste 2022 Ständige Senatskommission zur Do Information The ERC Use a Merck not breathe type P Index not available filtering - 10th combustion products facemask, Edition whose class Prüfung Formulation The product into mixture 1, 2 or gesundheitsschädlicher is Slovenia combustible +38614006051 and effective need, Arbeitsstoffe and, when the powder is released into the air in sufficient concentrations must be defined Mitteilung according 58 to the outcome of risk assessment Causes DIPOTASSIUM and not ERC applicable in the presence serious eye HEXAFLUOROTITANIUM(2-) irritation of a source Formulation of ignition, it into can solid create Spain matrix explosive 34 917689800 mixtures with air. Fires may start or get worse by leakage of the solid Handling DNK see standard Solubility in water Chemical EN 149). Danmark Safety Bekendtgørelse om grænseværdier for stoffer og materialer - BEK nr 1458 af 13/12/2019 1270 mg/l product INRS ENVIRONMENTAL PC from 32 the container, when it reaches high temperatures Fiche Toxicologique EXPOSURE toxicological Polymer CONTROLS preparations sheet) Sweden +46104566750 and compounds or through contact with sources of ignition ESP RESPIRATORY OR SKIN SENSITISATION España Límites de exposición profesional para agentes químicos en España 2023 14.7. The Bioaccumulative potential Patty EST Maritime PROC emissions Industrial transport generated Hygiene Eesti in by bulk and manufacturing Toxicology according Chemical production to processes, Ohtlike kemikaalide ja neid sisaldavate materjalide IMO instruments United or including refinery Kingdom in those closed +44 generated process 121 507 by without 4123 ventilation likelihood kasutamise equipment, of exposure töötervishoiu should or be processes checked with ja tööohutuse to ensure equivalent nõuded Advice for firefighters compliance N.I. Sax - Dangerous with environmental properties standards containment conditions of Industrial ning Materials-7, töökeskkonna Switzerland/Conf. Suisse/Schweizerische Eidgenossenschaft/Conf. Svizzera 145 1989 keemiliste Edition ohutegurite piirnormid [RT I, 21.12.2022, 14] Does not meet the classification criteria for this hazard class Information PROC 3 not relevant Manufacture or formulation USA - Poison in the chemical Control industry Center - in (800) closed 222-1222 batch processes with occasional controlled FRA Product IFA GESTIS residues website must France not be indiscriminately Valeurs disposed limites of with d'exposition waste water professionnelle or by dumping aux in agents waterways chimiques en FranceDécret n° 2021-1849 Australia: Phone: +613 9795 9599 - Address: 1-5 Overseas Drive, Noble Park North VIC 3174 New Zealand: Phone: +649 914 9999 - Address: 12 Omega Street, Rosedale, Auckland Hazards identification Classification of the substance or mixture

Hazard categories

EU) H) (1, 2020/878 EST or 3) must II mentioned Annex Causes serious eye irritation be 5 chosen of in REACH according Regulation) of to the the +38514686917 outcome of risk assessment. The above values are not TLVs, but guide values, 14.2. Conditions to 4. be Regulation UN proper for VLEP used for (EC) shipping particles safe storage, 790/2009 FRA that do (I Atp name including any incompatibilities not have CLP) their own TLV and that are insoluble or poorly soluble in water and have low toxicity the European Cyprus +35722405611 DIPOTASSIUM There Most H412 important Acute are Tox DIPOTASSIUM no particular HEXAFLUOROTITANIUM(2-) symptoms risks of reaction HEXAFLUOROTITANIUM(2-) and Harmful Acute toxicity, effects, with other to of aquatic both acute category substances life with Parliament Czech and long Republic delayed in normal +420267082257 lasting effects conditions of use Regulation LC50 - for LD50 VLEP Fish (Oral) EU) 286/2011 FRA II Atp. 10 CLP) of the European Parliament 172 324 mg/l/96h mg/kg dario rat rerio RESP 6. Exposure Store not STOT Regulation HTP applicable only RE in the controls EU) 618/2012 original container FIN III Atp. 2 CLP) of the European Parliament Specific Store target the containers organ Denmark toxicity sealed, repeated 10 45 in a 72 well 54 exposure, ventilated 40 00 category place, away from direct sunlight. Keep containers away from Chemical Precautionary Specific EC50 - for information Eye any Dam incompatible Crustacea stability statements on symptoms and effects caused by the 48,2 product materials, Serious see section eye 10 damage, for details Estonia category +3726943884 mg/l/48h are unknown Regulation EC50 P260 TLV for SODIUM Algae / ALGINATE EU) 487/2013 Aquatic Plants Do not breathe dust / fume 10,81 GRC IV Atp. 5 CLP) of the European Parliament gas mg/l/72h 10 mist / vapours short term spray Pseudokirchneriella subcapitata) As Regulation Eye Irrit. 2 AK the use of (EU) adequate 944/2013 HUN technical V Atp. equipment Eye irritation, category Finland CLP) of the must European always take Parliament 358 5052 000 priority over personal protective equipment, make sure that the workplace is Indication P280 LD50 of (Oral) any immediate Wear medical eye attention protection and face special protection 5000 treatment 14.3. The well Regulation mg/kg needed Specific Transport Skin GVI/KGVI product aired through rat Irrit. end is hazard stable EU) effective use(s) in class(es) 605/2014 HRV local normal conditions VI Atp Skin irritation, aspiration CLP) of the European Parliament of use category and France storage 33 3 83 85 21 92 10 RESP ALUMINUM P305+P351+P338 STOT SE 3 LC50 OXIDE Inhalation vapours) IF IN EYES: Rinse cautiously 4,72 Specific target organ Germany toxicity - single with mg/l 302106479250, water 1h for exposure, category rat several minutes. Remove contact lenses, if present and easy to 302106479450 When NDS/NDSCh Information LC50 - for Fish Regulation choosing (EU) not available personal 2015/1221 POL protective VII Atp do. Continue rinsing equipment, CLP) of ask the your European chemical 100 mg/l/96h 10 Parliament substance supplier for INHAL advice Na Zn Information not Possibility Personal TLV Aquatic Regulation applicable protective not Acute of available EU) equipment hazardous 2016/918 ROU reactions VIII must Atp Hazardous to the aquatic be CLP) CE marked, of the European showing that Hungary

Signal word

Warning

Hazard statements

H373 May cause damage to organs through prolonged or repeated exposure. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P260 Do not breathe dust / fume / gas / mist / vapours / spray. P280 Wear eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Contains

DIATOMACEOUS EARTH, SODA ASH FLUX CALCINATED

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.

2.1 Classification of the substance or mixture

relating on of hazard the to the substance product classes or or as contained mixture defined in substances Regulation white pursuant (EC) No to 1272/2008 Annex XVII to EC Regulation 1907/2006 CAS HRV - The Odour CE: Normal Contained substance use Identifier of value this in product 68855-54-9 for ESIS marine Hrvatska (European is not water subject archive sediment to our of Pravilnik direct existing control; o substances) characteristic izmjenama therefore, i dopunama users must, Pravilnika under their 1.2. SECTION o zaštiti REACH Health Does On - and CLP: Relevant identified own radnika the safety not Regulation responsibility, basis - Reg. Derived meet laws 6. Accidental of the 0,766 od izloženosti available 01-2119488518-22-XXXX and no-effect (EC) classification regulations. comply mg/kg uses of the release 1272/2008 data, level the opasnimkemikalijama with the current health criteria The - product substance measures DNEL producer for / this does DMEL na radu, or mixture and uses advised against is hazard not relieved graničnim contain class from any vrijednostima any PBT liability or vPvB arising izloženosti in percentage from improper i biološkim ≥ than uses. graničnim 0,1%. vrijednostima (NN 1/2021) The Melting Metabolism, Point product point toxicokinetics, is / freezing classified point as mechanism 75 hazardous of pursuant action and to the not other provisions available information set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent 6.1. amendments DIPOTASSIUM POL - Provide Initial DNEL: appointed Personal boiling precautions, Derived HEXAFLUOROTITANIUM(2-) point and supplements). No staff Effect Polska with Level protective Effects adequate The equipment on consumers training Rozporządzenie product thus and on how to use ministra requires not emergency applicable a safety procedures chemical rozwoju, datasheet that complies with the provisions of (EU) Regulation products. pracy i technologii Effects on z workers dnia 18 lutego 2021 r. Zmieniające 12.6. INDEX Intended use STOT - EmS: Endocrine Route - Emergency SINGLE of exposure disrupting EXPOSURE Schedule properties Acute 1 ≤ Acute x < rozporządzenie 1,5 Alginates Chronic w Acute sprawie for dental Tox. najwyższych Chronic 4 impressions H302, Eye dopuszczalnych Dam. Acute - ISO 1 local H318 21563:2021 stężeń Acute === i natężeń GMDN czynników Chronic 35863 ==== szkodliwych Chronic MEDICAL 2020/878. Flammability Information Regulation (EU) not available 2019/1148 - on the marketing and use not of available explosives precursors REGULATION EC - CALCULATION Any If Lower not there GHS: Globally 240-969-9 applicable additional explosive are no contraindications, information Harmonized METHODS local limit concerning FOR System spray the CLASSIFICATION of classification powder systemic risks with dla zdrowia DEVICE for health water and w labeling

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