OXNILON 6-30 004.0008 Q716

Hazard statements (CLP)

H316

Code

Statements

H316

Causes mild skin irritation

Appearance/Odor

COLORED PLASTIC PELLET - NO SIGNIFICANT ODOR SECTION IV - FIRE AND EXPLOSION HAZARD DATA: Fiylos Page 4of10"" * Stanbyamepdsl'sier 20 13-01-26°07 21 19 (GMT) POURRA fe 19284411960" From: bpes bpes ~ += ---------------------~------ -~ -—--- Date: 1/26/13 MATERIAL SAFETY DATA SHEET PAGE: 3 SHIPPED FROM: CLARIANT CORPORATION, MASTERBATCHES DIVISION ALBION-CLARIANT MASTERBATCHES 926 ELLIOTT ROAD ALBION MI 49224 PHONE: 517-629-9101 EMERGENCY TELEPHONE: 269~753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH .COM

Product definition

NY OXNILON 6-30 004,000% 9716 2-1 PRODUCT CODE: ABO2 631591 FLASH POINT (METHOD USED) THERE IS A COMPONENT IN THIS PRODUCT WITH A FLASH POINT OF 350 C. THE METHOD USED TO DETERMINE THIS IS: NA ALL OTHER COMPONENTS USED IN THIS PRODUCT EITHER HAVE A HIGHER FLASH POINT OR ARE NOT COMBUSTIBLE AND DO NOT HAVE A FLASH POINT. EXTINGUISHING MEDIA: WATER SPRAY, FOAM, CARBON DIOXIDE, OR DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED POSITIVE PRESSURE BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: IT MAY NOT BE OBVICUS THAT CARBON BLACK IS BURNING UNLESS THE MATERIAL IS STIRRED AND SPARKS ARE APPARENT. CARBON BLACK THAT HAS BEEN ON FIRE SHOULD BE OBSERVED CLOSELY FOR AT LEAST 48 HOURS TO ENSURE NO SMOLDERING MATERIAL IS PRESENT. SECTION V - REACTIVITY DATA: STABILITY: STABLE -> X UNSTABLE —> STABILITY (CONDITIONS TO AVOID): TEMPERATURES ABOVE 350C/662F. INCOMPATILBILITY (MATERIALS TO AVOID): AVOID CONTACT WITH STRONG ALKALI, AMINES. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HAZARDOUS FUMES OF TITANIUM OXIDE. HAZARDOUS POLYMERIZATION: WILL OCCUR -> WILL NOT OCCUR -> X HAZARDOUS POLYMERIZATION (CONDITIONS TO AVOID): AVOID CONTACT WITH STRONG CHEMICAL OXIDIZING AGENTS. To: Page 5 of 10 A etieceny ees 8 2043-01-26 07 21 19 (GMT) si SRE O9284411960 From: bpcs bpos*einrnt Sania iaiaeecatateieeteteianatatanatenanatanetamanatenananatarenateteneeiatatatetmeatatemmene Date: 1/26/13 MATERIAL SAFETY DATA SHEET PAGE: 4 SHIPPED FROM; CLARIANT CORPORATION, MASTERBATCHES DIVISION ALBION-CLARTANT MASTERBATCHES 926 ELLIOTT ROAD ALBION MI 49224 PHONE: 517-629-9101 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH .COM NY OXNILON 6-30 004.0008 Q716 2-1 PRODUCT CODE: ABO2631591 SECTION VI NY OXNILON 6-30 004.000% Q716 2-1 PRODUCT CODE: ABOZ2 631591 SECTION VI

Health hazards

(ACUTE AND CHRONIC): INHALATION SHORT TERM OVEREXPOSURE BY IHALATION TO TITANIUM DIOXIDE MAY CAUSE IRRITATION OF NOSE, THROAT, AND LUNGS WITH COUGH, DIFFICULTY BREATHING OR SHORTNESS OF BREATH. STUDIES SHOWED THAT EMPLOYEES WHO HAD BEEN EXPOSED TO TITANIUM DIOXIDE WERE AT NO GREATER RISK OF DEVELOPING LUNG CANCER THAN WERE EMPLOYEES WHO HAD NOT BEEN EXPOSED TO TITANIUM DIOXIDE. INHALATION OF AMORPHOUS SILICA MAY CAUSE DRYING OF MUCOUS MEMBRANES AND IRRITATION OF NOSE, THROAT, AND LUNGS WITH NOSEBLEEDS, COUGH AND DIFFICULTY BREATHING OR SHORTNESS OF BREATH. SKIN MAY CAUSE IRRITATION TO SKIN INGESTION THIS PRODUCT IS NOT EXPECTED TO BE TOXIC BY INGESTION. LARGE QUANTITIES OF MATERIALS INGESTED MAY CAUSE DISCOMFORT OR OBSTRUCTION OF THE DIGESTIVE SYSTEMS. EYE CONTACT HIGH DUST CONCENTRATIONS MAY CAUSE MECHANICAL IRRITATION TO EYES. IS ANY CHEMICAL IN THIS PRODUCT AT A CONCENTRATION OF 0.1 % OR MORE CLASSIFIED AS A CARCINOGEN BY IARC, NTP,

Acute Health Hazards

(CONT) TITANIUM DIOXIDE: IARC HAS LISTED TITANIUM DIOXIDE AS 2(B) POSSIBLE CARCINOGENIC TO HUMANS. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. LIMESTONE: CAN BE TRRITATING TO THE RESPIRATORY TRACT. SYMPTOMS INCLUDE SNEEZING AND SLIGHT NOSE TRRITATION. MILD EYE IRRITATION, SYMPTOMS INCLUDE WATERING AND IRRITATION. MAY CAUSE MILD SKIN IRRITATION. REPEATED OR PROLONGED EXPOSURE MAY HAVE A DRYING EFFECT ON THE SKIN. SYMPTOMS INCLUDE REDNESS AND IRRITATION. INGESTION MAY RESULT IN INTESTINAL OBSTRUCTION AND/ OR CONSTIPATION. CHRONIC EXPOSURE MAY INCREASE THE RISK OF DEVELOPING PNEUMOCONIOSIS (LUNG DISEASE). THESE PRODUCTS CONTAIN CRYSTALLINE SILICA IARC HAS CONCLUDED THERE IS SUFFICIENT EVIDENCE IN HUMANS FOR CARCINOGENICITY.

Medical Conditions Generally Aggravated by Exposure

THE FOLLOWING INFORMATION PROVIDED ON THE BELOW HAZARDOUS INGREDIENT (3S) APPLIES TO THE INGREDIENT(S) IN THE PURE DRY FORM. THE FORM OF THE INGREDIENT{S} PROVIDED TO YOU IS ENCAPSULATED IN PLASTIC, AND THEREFORE, THE LIKELIHOOD OF EXPOSURE IS MUCH LESS, EVEN TO THE POINT OF NEGLIGIBLE, WE THEREFORE CONSIDER THE LEVEL OF HAZARD TO BE NEGLIGIBLE. PIGMENT YELLOW 53: RESPIRATORY AND SKIN DISORDERS. CARBON BLACK: UPPER RESPIRATORY DISORDERS, SUCH AS BRONCHITIS OR ASTHMA. TITANIUM DIOXIDE, ALUMINUM OXIDE, AMORPHOUS SILICA, ZIRONIUM OXIDE: NO DATA LIMESTONE: NONE KNOWN EMERGENCY FIRST AID: INHALATION REMOVE TO CLEAN, FRESH AIR AND TREAT SYMPTOMATICALLY. EMERGENCY FIRST AID