CPP-BKS 45-1

Hazard statements (CLP)

H335

Code

Statements

H335

May cause respiratory irritation

Health hazards

(29 CFR 1910.1200) INHALATION TEMPORARY DISCOMFORT TO UPPER RESPIRATORY TRACT MAY OCCUR DUE TO MECHANICAL IRRITATION WHEN EXPOSURES ARE WELL ABOVE THE OCCUPATIONAL EXPOSURE LIMIT. SKIN DIRECT CONTACT WITH RESIN FINES MAY CAUSE SKIN IRRITATION IN SENSITIVE INDIVIDUALS. CONTACT WITH HOT MOLTEN RESIN WILL BURN UNPROTECTED SKIN. INGESTION INGESTION MAY RESULT IN CASTRIC DIGTURBANCES EYE CONTACT HIGH DUST CONCENTRATIONS MAY CAUSE MECHANICAL IRRITATION TO EYES. rr i ee ee ——— od IS ANY CHEMICAL IN THIS PRODUCT AT A CONCENTRATION OF 0.1 % OR MORE CLASSIFIED AS A CARCINOGEN BY IARC, NIP,

Medical Conditions Generally Aggravated by Exposure

* THE FOLLOWING INFORMATION PROVIDED ON THE BELOW HAZARDOUS INGREDIENT (S) APPLIES TO THE INGREDIENT(S) IN THE PURE DRY FORM. THE FORM OF THE INGREDIENT (S) PROVIDED To YOU IS ENCAPSULATED IN PLASTIC, AND THEREFORE, THE LIKELIHOOD OF EXPOSURE IS MUCH LESS, EVEN To THE POINT OF NEGLIGIBLE. WE THEREFORE CONSIDER THE LEVEL OF HAZARD TO BE NEGLIGIBLE. CARBON BLACK: ASTHMA, RESPIRATORY DISORDER Page of ~~----------------~--------------- ~~ --------------- Date: PAGE: 675 WEGNER DRIVE WEST CHICAGO IL 60185 PHONE: 630-562-9000 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH .COM

Product definition

PP PP COPOLY 050.000:1 Lego Black PRODUCT CODE: CPP-BK9 45-1 SECTION VI PP PP COPOLY 050.000:1 Lego Black PRODUCT CODE: CPP-BKS 45-1 SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE: (CONT) ——_ a eon HANDLING: OTHER PRECAUTIONS AVOID BREATHING PROCESSING FUMES OR VAPORS. STORE AND PROCESS USING ADEQUATE VENTILATION. ec em ee a FS se Se en ee ee SECTION VIII - CONTROL MEASURES: CONTROL: RESPIRATORY PROTECTION USE NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS CONTROL: VENTILATION PROVIDE AN ADEQUATE EXHAUST SYSTEM THAT IS FILTERED To AVOID CONTAMINATING THE ENVIRONMENT AND MEETS THE TLV REQUIREMENTS IN THE WORK AREA, CONTROL: GLOVES USE GLOVES WHEN POLYMER IS HOT TO MINIMIZE SKIN CONTACT. CONTROL: EYE PROTECTION GOGGLES CONTROL: CTHER CLOTHING WEAR LONG SLEEVED SHIRTS AND PANTS TO MINIMI2ZE SKIN CONTACT, CONTROL: WORK/HYGIENE OBSERVE PROPER INDUSTRIAL HYGIENIC PRACTICES ACCORDING TO REGULATIONS, SARA - THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL (S) SUBJECT To THE REPORTING OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: THIS INFORMATION SHOULD BE INCLUDED IN ALL MSDS'S THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL, DOES NOT CAS EXCEED (%) DESCRIPTION 557-05-1 2.00 PROPRIETARY PROCESSING AID Page 8 of SHEET PAGE: 675 WEGNER DRIVE WES T CHICAGO IL 60185 PHONE: 630-562-9000 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH.COM PP PP COPOLY 050.000:1 Lego Black PRODUCT CODE: CPP-BKS 45-1 SECTION IX - OTHER REGULATORY INFORMATION: (CONT) A =a — ee REACH REGULATION —- THE SVHC REPORTED IN THE PROPOSAL LIST FOR INCLUSION IN ANNEX XIV {ART 59.4) AND ACCORDING TO OUR KNOWLEDGE AND THE REACH REGULATION ITSELF. DETAILS ABOUT SVHC CONTAINED IN OUR MB ARE HEREUNDER REPORTED AS OF FEBRUARY 2010. DOES NOT CAS # EXCEED (&) DESCRIPTION NONE TSCA ~ ALL INGREDIENTS USED To PRODUCE THE ABOVE FORMULATION ARE IN COMPLIANCE WITH THE TOXIC SUBSTANCES AND CONTROL ACT INVENTORY AS REQUIRED BY FEDERAL LAW. REGULATORY INFORMATION: CA PROPOSITION 65: WARNING -— ANY COMPONENT OF THIS PRODUCT WHICH CONTAINS MATERIALS KNOWN TO THE STATE OF CALIFORNIA To CAUSE CANCER ARE LISTED BELOW: THIS PRODUCT CONTAINS A COMPONENT(S) THAT IS LISTED ON CALIFORNIA PROPOSITION 65 LISTED SUBSTANCE. PLEASE NOTE THAT ALL THREE LISTING QUALIFIERS (AIRBORNE, UNBOUND (NOT BOUND WITH A MATRIX), AND RESPIRABLE SIZE (10 MICROMETERS OR LESS IN DIAMETER)) MUST BE MET FOR THIS SUBSTANCE TO BE CONSIDERED A PROPOSITION 65 SUBSTANCE. CARBON BLACK Ch PROPOSITION 65: WARNING - ANY COMPONENT OF THIS PRODUCT WHICH CONTAINS MATERIALS KNOWN TO THE STATE OF CALIFORNIA To CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM ARE LISTED BELOW: 7 NONE CANADIAN WHMIS: ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS GIVEN IN WHMIS IS SHOWN BELOW: D2A (CARBON BLACK) FLORIDA: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE FLORIDA HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT Page 9 of 9 awa -~-- =~ =~ = =~ - === = DATE: SHEET PAGE: 675 WEGNER DRIVE WEST CHICAGO IL 60185 PHONE: 630-562-9000 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH.COM PRODUCT DESCRIPTION: PP PP COPOLY 050.000:1 Lego Black PRODUCT CODE: CPP-BK545-1 SECTION X - STATE REGULATORY INFORMATION: (CONT) i i i in ooo os SHOWN IN SECTION II ARE AS FOLLOWS: NONE MASSACHUSETTS: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT CE THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE MASSACHUSETTS HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE NEW JERSEY: NON-HAZARDSUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE NEW JERSEY HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE PENNSYLVANIA: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE PENNSYLVANIA HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE RHODE ISLAND:ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL CHEMICAL AS LISTED IN THE RHODE ISLAND SUBSTANCE LIST I& SHOWN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION IT ARE AS POLLOWS: NONE THIS INFORMATION IS ACCURATE AND RELIABLE TO THE BEST OF OUR KNOWLEDGE. IT IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED. CLARIANT CORPORATION ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OF, OR RELIANCE UPON, THESE DATA FOR HAZARDS WHICH MIGHT BE ASSOCIATED WITH THE USE OF THIS MATERIAL OR FOR THE RESULTS OBTAINED. IT IS THE RESPONSIBILITY OF THE USER To COMPLY WITH ALL APPLICABLE LAWS

Acute Health Hazards

(CONT) ZINC STEARATE: PERSONS WITH PRE-EXISTING SKIN DISORDERS, IMPAIRED RESPIRATORY FUNCTION, OR HISTORY OF PULMONARY DISEASE SHOULD NOT BE EXPOSED To DUSTS. EMERGENCY FIRST AID: INHALATION REMOVE TO UNCONTAMINATED AREA. IF NOT BREATHING, ADMINISTER ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SEEK MEDICAL ATTENTION EMERGENCY FIRST AID: SKIN IF MOLTEN POLYMER CONTACTS THE SKIN, COOL RAPIDLY WITH COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN. OBTAIN MEDICAL ATTENTION FOR THERMAL BURN. SKIN ABSORPTION OF REGROUND PELLETS IS UNLIKELY. EMERGENCY FIRST AID: INGESTION IF INGESTED, SEEK MEDICAL ASSISTANCE EMERGENCY FIRST AID: EYE CONTACT RINSE EYES THOROUGHLY WITH PLENTY OF WATER KEEPING EYELID OPEN. IF SYMPTOMS DEVELOP, SEEK MEDICAL ATTENTION. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE: ee ere es ee ee ee ee HANDLING: SPILLAGE PRODUCT IS CONSIDERED A HAZARDOUS MATERIAL. WEARING PROTECTIVE EQUIPMENT, CONTAIN SPILLAGE AND SCOOP UP OR VACUUM. AVOID DUSTING. NOTIFICATION oF THE NATIONAL RESPONSE CENTER (800-424-9802) MAY BE REQUIRED, REFER To EPA, DOT, AND APPLICABLE STATE AND LOCAL REGULATIONS FOR CURRENT RESPONSE INFORMATION. HANDLING: WASTE DISPOSAL DISPOSE OF IN AN APPROVED HAZARDOUS WASTE LANDFILL IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. HANDLING

Storage

CONCENTRATED DUST MAY PRESENT EXPLOSION HAZARD. PREVENT ACCUMULATION OF DUST ON FLOOR, WALLS AND EQUIPMENT. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES AND SKIN. TEMPERATURES NOT TO EXCEED 60 Page of eee Sanit Date: DATA SHEET PAGE: ee 675 WEGNER DRIVE WEST CHICAGO IL 601865 PHONE? 630-562-9000 EMERGENCY THLEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH.COM