8/27/10

Health hazards

OSHA Hazards INHALATION SHORT TERM OVEREXPOSURE BY IHALATION TO TITANIUM DIOXIDE MAY CAUSE IKRITATICN OF NOSE, THROAT, AND LUNGS WITH COUGH, DIFFICULTY BREATHING OR SHORTNESS OF BREATH. STUDIES SHOWED THAT EMPLOYEES WHO HAD REEN EXPOSED To TITANIUM DIOXIDE WERE AT NO GREATER RISK OF DEVELOPING LUNG CANCER THAN WERE EMPLOYEES WHO HAD NOT BEEN EXPOSED TO TITANIUM DIOXIDE, INHALATION OF AMORPHOUS SILICA MAY CAUSE DRYING OF MUCOUS MEMBRANES AND IRRITATION OF NOSE, THROAT, AND LUNGS WITH NOSEBLEEDS, COUGH AND DIFFICULTY BREATHING OR SHORTNESS OF BREATH. SKIN NOT EXPECTED TO BE IRRITATING INGESTION SINGLE DOES ORAL TOXICITY IS EXTREMELY LOW. NO HAZARDS ANTICIPATED FROM SWALLOWING SMALL AMOUNTS INCIDENTAL TO NORMAL HANDLING OPERATIONS. EYE CONTACT AS WITH ALL POWDERS, MAY CAUSE MILD IRRITATION To THE EYES. IS ANY CHEMICAL IN THIS PRODUCT AT A CONCENTRATION OF 0.1 4% OR MORE CLASSIFIED AS A CARCINOGEN BY IARC, NIP,

Acute Health Hazards

CONT) NICKEL COMPOUNDS CONSIDERED To BE CARCIOGENIC. REPEATED OVEREXPOSURE TO THIS COMPOUND MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. CARBON BLACK: POSSIBLE TEMPORARY DISCOMFORT DUE TO INHALATION OF HIGH DUST CONCENTRATIONS. LISTED AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B). TITANIUM BPIOXIDE, ALUMINUM OXIDE! TITANIUM DIOXIDE HAS BEEN LISTED BY IARC AS A GROUP 2(B) POSSIBLE CARCINOGEN To HUMANS. MAY CAUSE IRRITATION To EYES, SKIN AND RESPIRATORY TRACT AND MAY AGGRAVATE PRE-EXISTING RESPIRATORY CONDITIONS. MAY ALSO CAUSE TEMPORARY DRYING EFFECT. CALCIUM CARBONATE: MAY CAUSE MECHANICAL IRRITATION WITH EYE CONTACT. MAY CAUSE MILD MECHANICAL IRRITATION To THE NOSE, THROAT AND RESPIRATORY TRACT (CONT) ee ee ee ee EMERGENCY FIRST AID: INGESTION IF INGESTED, SEEK MEDICAL ASSISTANCE EMERGENCY FIRST AID: EYE CONTACT IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER EYELIDS. SEEK PROMPT MEDICAL ATTENTION IF REDNESS OR IRRITATION OCCURS. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE: HANDLING: SPILLAGE WEARING APPROPRIATE PERSONNEL PROTECTIVE BOQUIPMENT, CONTAIN SPILL, COLLECT IN A SUITABLE CONTAINER. HANDLING: WASTE DISPOSAL PELLET DISPOSAL SHOULD BE IN COMPLIANCE WITH LAWS AND REGULATIONS. DO NOT ALLOW LOST PELLETS TO ENTER A MARINE ENVIRONMENT. PREFERRED DISPOSAL: RECYCLE OR INCINERATE. HANDLING

Medical Conditions Generally Aggravated by Exposure

THE FOLLOWING INFORMATION PROVIDED ON THE BELOW HAZARDOUS INGREDIENT (S) APPLIES TO THE INGREDIENT(S} IN THE PURE DRY FORM. THE FORM OF THE INGREDIENT (S) PROVIDED TO YOU IS ENCAPSULATED IN PLASTIC, AND THEREFORE, THE LIKELIHOOD OF EXPOSURE IS MUCH LESS, EVEN TO THE POINT OF NEGLIGIBLE. WE THEREFORE CONSIDER THE LEVEL OF HAZARD TO BE NEGLIGIBLE. PIGMENT YELLOW 53: RESPIRATORY AND SKIN DISORDERS. CARBON BLACK: RESPIRATORY CONDITIONS TITANIUM DIOXIDE AND ALUMINUM OXIDE: MAY AGGRAVATE PRE-EXISTING RESPIRATORY CONDITIONS, CALCIUM CARBONATE: NONE KNOWN EMERGENCY FIRST AID: INHALATION NOT AN INHALATION HAZARD DUE TO AN EXTREMELY LOW VAPOR PRESSURE. EMERGENCY FIRST AID: SKIN REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15 20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. Page of 10 on Date: 6/27/19 SHEET PAGE: CODE: OCNNG6 4856 SECTION VI

Storage

TREAT AS A SCLID THAT CAN BURN. STORE AWAY FROM OXIDIZING MATERIALS, IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. PRODUCT HAS A TENDENCY TO ACUMMULATE STATIC DURING TRANSPORT, HANDLING AND PROCESSING. REDUCING THE VELOCITY OF TRANSPORT WILL REDUCE CHARGING, STATIC CHARGE BUILDUP CAN BE A POTENTIAL FIRE HAZARD WHEN USED IN THE PRESENCE oF VOLATILE OR FLAMMABLE MIXTURES. AVOID VAPORS FROM HEATED PRODUCTS. ADEQUATE VENTILATION OR ENGINEERING CONT ROLS MUST BE EMPLOYED IN HIGH TEMPERATURE TO PREVENT EXPOSURE TO POTENTIALLY TOXIC/IRRATATING FUMES. KEEP PRODUCT AWAY FROM FooD HANDLING: OTHER PRECAUTIONS DO NOT ALLOW PRODUCT TO ACCUMULATE IN PROCESSING AREA. Page 8 of 10 wee Date: 8/27/10 SHEET PAGE: CODE: OCNN66 4856 SECTION VIII - CONTROL MEASURES oe CONTROL: RESPIRATORY PROTECTION AVOID VAPORS FROM HEATED PRODUCTS. ADEQUATE VENTILATION AND/OR ENGINEERING CONTROLS MUST BE EMPLOYED IN HIGH TEMP PROCESSING TO PREVENT EXPOSURE TO POTENTIALLY TOXIC/IRRITATING FUMES. CONTROL: VENTILATION USE VENTILATION SYSTEM TO MAINTAIN EXPOSURE LEVELS WITHIN THE ACGIH TLV CONTROL: GLOVES HEAT RESISTANT GLOVES WITH LONG SLEEVES WHEN HANDLING MOLTEN MATERIALS. CONTROL: EYE PROTECTION SIDESHIELD SAFETY GLASSES CONTROL: OTHER CLOTHING EYE WASH STATION. CONTROL: WORK/HYGIENE DO NOT EAT, DRINK, OR SMOKE IN WORK AREAS. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. SECTION IX - OTHER REGULATORY INFORMATION: SARA — THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(8) SUBJECT TO THE REPORTING OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: THIS INFORMATION SHOULD BE INCLUDED IN ALL MSDS'S THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL. DOES NOT CAS # EXCEED (#) DESCRIPTION NICMPD 14 NICKEL COMPOUND (AS NI) &SBCMPD 14 ANTIMONY COMPOUND 7440-02-0 O01 NICKEL (AS NI) 7440~36-0 02 ANTIMONY (SB) METAL REACH REGULATION - THE SVHC REPORTED IN THE PROPOSAL LIST FOR INCLUSION IN ANNEX XIV (ART 59.4) AND ACCORDING TO OUR KNOWLEDGE AND THE REACH REGULATION ITSELF. DETAILS ABOUT SVHC CONTAINED IN OUR MB ARE HEREUNDER Page 9 of 10 ~---+-~- + == == == $e + === === === == Date: 8/27/10 DATA SHEET PAGE: 8 —— CODE: OCNNG6 4856 SECTION IX - OTHER REGULATORY INFORMATION: (CONT) Se ee ee | REPORTED AS OF FEBRUARY 2010. DOES NOT CAS # EXCEED(%) DESCRIPTION NONE TSCA - ALL INGREDIENTS USED To PRODUCE THE ABOVE FORMULATION ARE IN COMPLIANCE WITH THE TOXIC SUBSTANCES AND CONTROL ACT INVENTORY AS REQUIRED BY FEDERAL LAW. SECTION X - STATE REGULATORY INFORMATION: i ee CA PROPOSITION 65: WARNING - ANY COMPCNENT OF THIS PRODUCT WHICH CONTAINS MATERIALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER ARE LISTED BELOW: TRACES OF LEAD AND CHROMIUM (+6) AT LESS THAN 100PPM CARBON BLACK (AIRBORNE, UNBOUND PARTICLES OF RESPIRABLE SIZE) IS A CALIFORNIA PROPOSITION 65 SUBSTANCE. PLEASE NOTE THAT ALL THREE LISTING QUALIFIERS (AIRBORNE, UNBOUND (NOT BOUND WITHIN A MATRIX), AND RESPIRABLE SIZE (10 MICROMETERS OR LESS IN DIAMETER)) MUST BE MET FOR THIS SUBSTANCE To BE CONSIDERED A PROPOSITION 65 SUBSTANCE. THIS PRODUCT CONTAINS CARBON BLACK THAT IS LISTED ON CALIFORNIA PROPOSITION 65 LISTED SUBSTANCE. PLEASE NOTE THAT ALL THREE LISTING QUALIFIERS (AIRBORNE, UNBOUND (NOT BOUND WITH A MATRIX), AND RESPIRABLE SIZE (10 MICROMETERS OR LESS IN DIAMETER) MUST BE MET FOR THIS SUBSTANCE. CA PROPOSITION 65: WARNING -— ANY COMPONENT OF THIS PRODUCT WHICH CONTAINS MATERIALS KNOWN TO THE STATE OF CALIFORNIA To CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM ARE LISTED BELOW: NONE CANADIAN WHMIS: ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS GIVEN IN WHMIS IS SHOWN BELOW: CARBON BLACK: D2A D2B FLORIDA: NUN-HAZARKDWUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A anna nn DATE: 8/27/10 DATA SHEET PAGE: —— — ae ee CODE: OCNN66 4856 es a ee ——y SECTION X - STATE REGULATORY INFORMATION: (CONT) HAZARDOUS CHEMICAL AS LISTED ON THE FLORIDA HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE MASSACHUSETTS: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE MASSACHUSETTS HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE NEW JERSEY: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH I8 A HAZARDOUS CHEMICAL AS LISTED ON THE NEW JERSEY HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE PENNSYLVANIA: NON-HAZARDOUS INGREDIENTS ARE REING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE PENNSYLVANIA HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE RHODE ISLAND:ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL CHEMICAL AS LISTED IN THE RHODE ISLAND SUBSTANCE LIST Is SHOWN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE THIS INFORMATION IS ACCURATE AND RELIABLE TO THE BEST OF OUR KNOWLEDGE, IT IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED. CLARIANT CORPORATION ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OF, OR RELIANCE UPON, THESE DATA FOR HAZARDS WHICH MIGHT BE ASSOCIATED WITH THE USE OF THIS MATERIAL OR FOR THE RESULTS OBTAINED. IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH ALL APPLICABLE LAWS AND REGULATIONS. ri, 27 Aug 2010 01 37 58 -0400 18023751327 Page Clariant MS D5 CLARIANT MASTERBATCH 17 FOSS ROAD Fax#: 207-784-0667 FROM: LARRY POULIN DATE: 8/27/10 TIME: 1 37 57 TO: Mack Molding Elizabeth Richards This fax includes your Material Safety Data Sheet from Clariant Corp. Any problems regarding this fax, please contact your Clariant