7/23/13

Acute Health Hazards

(CONT) CLAY CAS# 1332-58-7: PRE-EXISTING RESPIRATORY DISORDERS AND DISORDERS INVOLVING ANY OTHER TARGET ORGANS MENTIONED AS BEING AT RISK MAY BE AGGRAVATED BY OVER-EXPOSURE TO THIS PRODUCT. CARBON BLACK: ASTHMA, RESPIRATORY DISORDER TITANIUM DIOXIDE: PRE-EXISTING DISORDERS INVOLVING ANY TARGET ORGANS MENTIONED IN THIS MSDS AS BEING AT RISK MAY BE AGGRAVATED BY OVER-EXPOSURE TO THIS PRODUCT. ETHYLENE BISSTEARAMIDE: NONE KNOWN STYRENE MONOMER (CAS# 100-42-5}: NONE NOTED STYRENE: A GROUP 2B CARCINOGEN BY IARC INCREASED NASAL LESIONS IN MICE AND RATS RELEVANCE TO HUMANS REMAINS UNCERTAIN. EMERGENCY FIRST AID: INHALATION REMOVE TO CLEAN, FRESH AIR AND TREAT SYMPTOMATICALLY. EMERGENCY FIRST AID: SKIN REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15 - 20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. EMERGENCY FIRST AID: INGESTION IF CONSCIOUS, GIVE WATER AND THEN INDUCE VOMITING. NEVER GIVE FLUIDS OR INDUCE VOMITING IF THE VICTIM IS UNCONSCIOUS OR HAVING CONVULSIONS. GET IMMEDIATE MEDICAL ATTENTION. EMERGENCY FIRST AID: EYE CONTACT WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15 - 20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE: To: 19284411960 From: bpcs bpes S enataiaTatatatamenaladiatemataracanetatataratatanatatanenatatatessntaatare aeaasiaamenmeneat Date: 7/23/13 MATERIAL SAFETY DATA SHEET 7 PAGE: SHIPPED FROM: CLARIANT CORPORATION, MASTERBATCHES DIVISION HOLDEN-CLARTANT MASTERBATCHES 85 HOLDEN INDUSTRIAL PARK HOLDEN MA 01520 PHONE: 508-829-6321 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH .COM

Product definition

ABS HFO690M W/INEOS 004 .0008 PANG641U BLUE PRODUCT CODE: SB53 620246 HANDLING: SPILLAGE SPILLS SHOULD BE PLACED IN SUITABLE CONTAINERS FOR DISPOSAL IN A LICENSED FACILITY. WEAR APPROPRIATE RESPRITORY PROTECTION AND PROTECTIVE CLOTHING AND PROVIDE ADEQUATE VENTILATION DURING CLEAN-UP. HANDLING: WASTE DISPOSAL DISPOSE IN CLOSED CONTAINERS. COMPLY WITH LOCAL, STATE, AND FEDERAL REGULATIONS. HANDLING: ABS HFO690M W/INEOS 004 .000% PANG641U BLUE PRODUCT CODE: SB53 620246 SECTION VIII - CONTROL MEASURES: (CONT) APRON, WORKPANTS, LONG SLEEVE WORKSHIRT, OR DISPOSABLE COVERALLS. CONTROL: WORK/HYGI ENE OBSERVE PROPER INDUSTRIAL HYGIENIC PRACTICES ACCORDING TO REGULATIONS. SARA ~ THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) SUBJECT TO THE REPORTING OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: THIS INFORMATION SHOULD BE INCLUDED IN ALL MSDS'S THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL. DOES NOT CAS EXCEED(%) DESCRIPTION 100-42-5 34 STYRENE REACH REGULATION - THE SVHC REPORTED IN THE PROPOSAL LIST FOR INCLUSION IN ANNEX XIV (ART 59.4) AND ACCORDING TO OUR KNOWLEDGE AND THE REACH REGULATION ITSELF. DETAILS ABOUT SVHC CONTAINED IN OUR MB ARE HEREUNDER REPORTED AS OF FEBRUARY 2010. DOES NOT CAS EXCEED(%) DESCRIPTION NONE TSCA - ALL INGREDIENTS USED TO PRODUCE THE ABOVE FORMULATION ARE IN COMPLIANCE WITH THE TOXIC SUBSTANCES AND CONTROL ACT INVENTORY AS REQUIRED BY FEDERAL LAW. THES -MSbS—ADHERES—TO. THE REGULATORY RIQUIREMENTS OF THE..USA. AND MAY Nop —__ MEET THE REGULATORY REQUIREMENTS IN OTHER COUNTRIES. SECTION - STATE REGULATORY INFORMATION: CA PROPOSITION 65: WARNING - ANY COMPONENT OF THIS PRODUCT WHICH CONTAINS MATERIALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER ARE LISTED BELOW: PLEASE NOTE IT IS THE RESPONSIBILITY OF THE END USER TO DETERMINE IF ITS FINISHED PRODUCTS REQUIRE LABELING UNDER CALIFORNIA PROPOSITION 65. To: 19284411960 From: bpes bpecs I DATE: 7/23/13 MATERIAL SAFETY DATA SHEET PAGE: 9 SHIPPED FROM: CLARIANT CORPORATION, MASTERBATCHES DIVISION HOLDEN-CLARIANT MASTERBATCHES 85 HOLDEN INDUSTRIAL PARK HOLDEN MA 01520 PHONE: 508-829-6321 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWW.CLARIANTMASTERBATCH .COM PRODUCT DESCRIPTION: ABS HFOG9OM W/INEOS 004 .000% PAN641U BLUE PRODUCT CODE: SB53620246 SECTION X - STATE REGULATORY INFORMATION: (CONT) PCB'S UP TO 25 PPM HEXACHLOROBENZENE 178 PPB THIS PRODUCT CONTAINS CARBON BLACK THAT IS LISTED ON CALIFORNIA PROPOSITION 65 LISTED SUBSTANCE. PLEASE NOTE THAT ALL THREE LISTING QUALIFIERS (AIRBORNE, UNBOUND (NOT BOUND WITH A MATRIX), AND RES PIRABLE SIZE (10 MICROMETERS OR LESS IN DIAMETER)) MUST BE MET FOR THIS SUBSTANCE TO BE CONSIDERED A PROPOSITION 65 SUBSTANCE. TITANIUM DIOXIDE (AIRBORNE, UNBOUND PARTICLES OF RESPIRABLE SIZE) IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. THIS LISTING DOES NOT COVER TITANIUM DIOXIDE WHEN IT REMAINS BOUND WITHIN THE POLYMER MATRIX. ACRYLONITRILE ACRYLONITRILE CAS# 107-13-1 <75 PEM CA PROPOSITION 65: WARNING - ANY COMPONENT OF THIS PRODUCT WHICH CONTAINS MATERIALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM ARE LISTED BELOW: PLEASE NOTE IT IS THE RESPONSIBILITY OF THE END USER TO DETERMINE IF ITS FINISHED PRODUCTS REQUIRE LABELING UNDER CALIFORNIA PROPOSITION 65. PCB’S UP TO 25 PPM CANADIAN WHMIS: ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS GIVEN IN WHMIS IS SHOWN BELOW: CARBON BLACK: D2A VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS CARCINOGENICITY: IARC GROUP 2B TITANIUM DIOXIDE: CLASS D-2A: MATERIAL CAUSING OTHER TOXIC EFFECTS (VERY TOXIC). FLORIDA: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET — INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE FLORIDA HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: NONE MASSACHUSETTS :NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE MASSACHUSETTS HAZARDOUS To: 19284411960 From: bpcs bpes SS ee rer er en DATE: 7/23/13 MATERIAL SAFETY DATA SHEET PAGE: SHIPPED FROM: CLARIANT CORPORATION, MASTERBATCHES DIVISION HOLDEN-CLARIANT MASTERBATCHES 85 HOLDEN INDUSTRIAL PARK HOLDEN MA 01520 PHONE: 508-829-6321 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WWwW.CLARIANTMASTERBATCH . COM PRODUCT DESCRIPTION: ABS HFO690M W/INEOS 004 .000%8 PAN641U BLUE PRODUCT CODE: SB53 620246 SECTION X - STATE REGULATORY INFORMATION: (CONT) LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: STYRENE CAS# 100-42-5 <0.108% NEW JERSEY: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE NEW JERSEY HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: COPPER COMPOUNDS 108 STYRENE CAS# 100-42-5 <0.10% PENNSYLVANIA: NON-HAZARDOUS INGREDIENTS ARE BEING WITHHELD AS TRADE SECRET INFORMATION. ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL AS LISTED ON THE PENNSYLVANIA HAZARDOUS LIST IS GIVEN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: COPPER COMPOUNDS 108% TITANIUM DIOXIDE, ALUMINUM OXIDE STYRENE CAS# 100-42-5 <0.10%& RHODE ISLAND: ANY COMPONENT OF THIS PRODUCT WHICH IS A HAZARDOUS CHEMICAL CHEMICAL AS LISTED IN THE RHODE ISLAND SUBSTANCE LIST IS SHOWN IN SECTION II OF THIS MSDS. ANY LISTED CHEMICALS NOT SHOWN IN SECTION II ARE AS FOLLOWS: THIS INFORMATION IS ACCURATE AND RELIABLE TO THE BEST OF OUR KNOWLEDGE. IT IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED. CLARIANT CORPORATION ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OF, OR RELIANCE UPON, THESE DATA FOR HAZARDS WHICH MIGHT BE ASSOCIATED WITH THE USE OF THIS MATERIAL OR FOR THE RESULTS OBTAINED. IT IS THE RESPONSIBILITY OF THE USER

Storage

STORE BELOW 100 TO AVOID MELTING. HANDLING: OTHER PRECAUTIONS IN ACCORDANCE WITH GOOD MANUFACTURING PRACTICES, GOOD GENERAL VENTILATION OF THE POLYMER PROCESSING AREA IS RECOMMENDED. CONTROL: RESPIRATORY PROTECTION NIOSH/MSHA APPROVED DUST RESPIRATOR RECOMMENDED IF THE AIRBORNE DUST CONCENTRATION IS NEAR OR EXCEEDS THE NUISANCE DUST EXPOSURE LIMITS. IF VENTILATION IS NOT SUFFICIENT TO CONTROL PROCESSING GASES AND FUMES, NIOSH APPROVED RESPIRATOR SHOULD BE SELECTED AND WORN BASED ON THE CONTAMINATION LEVELS FOUND IN THE WORKPLACE. CONTROL: VENTILATION PROVIDE LOCAL EXHAUST VENTILATION. VENTILATION EQUIPMENT SHOULD BE EXPLOSTON-PROOF TF EXPLOSTVE CONCENTRATIONS OF DUST, VAPOR OR FUME ARE PRESENT. CONTROL: GLOVES IMPERVIOUS GLOVES CONTROL: EYE PROTECTION SIDESHIELD SAFETY GLASSES CONTROL: OTHER CLOTHING TO PREVENT SKIN CONTACT WEAR SKIN PROTECTION, SUCH AS IMPERVIOUS GLOVES, To: Page Qof11 49284411960 From: bpes bpcs oememe Date: 7/23/13 MATERIAL SAFETY DATA SHEET PAGE: SHIPPED FROM: CLARIANT CORPORATION, MASTERBATCHES DIVISION HOLDEN-CLARIANT MASTERBATCHES 85 HOLDEN INDUSTRIAL PARK HOLDEN MA 01520 PHONE: 508-829-6321 EMERGENCY TELEPHONE: 269-753-8434 CLARIANT WEBSITE: HTTP: \\WwWwW.CLARIANTMASTERBATCH .COM