CERNIT ALCOHOL INK

Hazard statements (CLP)

H225, H226, H319

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour H319 Causes serious eye irritation

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403+P235 Store in a well-ventilated place. Keep cool.

Supplemental label elements

None

PBT Substances

- This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. vPvB-substance. - This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. 3.1 - Substances Not applicable 3.2 - Mixtures Chemical name No. % Class(es) Specific concentration limit ethanol CAS No. 64-17-5 70 - 80 Eye Irrit. 2 - H319 Not applicable Index No. 603-002-00-5 Flam. Liq. 2 - H225 EC No. 200-578-6 2-(propyloxy)ethanol, EGPE CAS No. 2807-30-9 8 - 14 Acute Tox. 4 Dermal - H312 Not applicable Index No. 603-095-00-2 Eye Irrit. 2 - H319 EC No. 220-548-6 propan-2-ol, isopropyl alcohol, CAS No. 67-63-0 2 - 4 Eye Irrit. 2 - H319 Not applicable isopropanol Index No. 603-117-00-0 Flam. Liq. 2 - H225 EC No. 200-661-7 STOT SE 3 - H336 SECTION�4:�First�aid�measures 4.1 - Description of first aid measures Following inhalation - Provide fresh air. Following skin contact - Wash immediately with: Water - When in doubt or if symptoms are observed, get medical advice. After eye contact - Rinse immediately carefully and thoroughly with eye-bath or water. - In case of eye irritation consult an ophthalmologist. After ingestion - Rinse mouth thoroughly with water. 4.2 - Most important symptoms and effects, both acute and delayed Symptoms and effects - - No information available. Following inhalation Symptoms and effects - - No information available. Following skin contact Symptoms and effects - After - Causes eye irritation. eye contact Symptoms and effects - After - No information available. ingestion 4.3 - Indication of any immediate medical attention and special treatment needed - Treat symptomatically. SECTION�5:�Firefighting�measures 5.1 - Extinguishing media Suitable extinguishing media - ABC-powder - Carbon dioxide (CO2) - Foam - Extinguishing powder Unsuitable extinguishing - Full water jet media 5.2 - Special hazards arising from the substance or mixture Special hazards arising from - No information available. the substance or mixture Hazardous decomposition - No information available. products 5.3 - Advice for firefighters - Wear a self-contained breathing apparatus and chemical protective clothing. - Move undamaged containers from immediate hazard area if it can be done safely. SECTION�6:�Accidental�release�measures 6.1 - Personal precautions, protective equipment and emergency procedures For non-emergency personnel - Use personal protection equipment. - Provide adequate ventilation. - Remove all sources of ignition. For emergency responders - Wear personal protection equipment (refer to section 8). 6.2 - Environmental precautions - Do not allow to enter into surface water or drains. 6.3 - Methods and material for containment and cleaning up Methods and material for - Collect in closed and suitable containers for disposal. containment Methods and material for - Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or cleaning up universal binding agents). - Wash with plenty of water. Inappropriate techniques - No information available. 6.4 - Reference to other sections

Disposal

see section 13 - Personal protection equipment: see section 8 SECTION�7:�Handling�and�storage 7.1 - Precautions for safe handling Recommendation - Avoid: Eye contact - Vapours can form explosive mixtures with air. - When using do not smoke. - Use only in well-ventilated areas. Advices on general - When using do not eat, drink, smoke, sniff. occupational hygiene - Wash hands before breaks and after work. - Use only in well-ventilated areas. 7.2 - Conditions for safe storage, including any incompatibilities - Storage class Flammable liquids - Keep container tightly closed and in a well-ventilated place. - Do not store together with: Combustible substance - Protect against: Heat 7.3 - Specific end use(s) SECTION�8:�Exposure�controls/personal�protection 8.1 - Control parameters 8.2 - Exposure controls Appropriate engineering - No information available. controls Individual protection - Suitable eye protection: Eye glasses with side protection measures, such as personal protective equipment - Suitable protective clothing: lab coat SECTION�9:�Physical�and�chemical�properties 9.1 - Information on basic physical and chemical properties Physical state Liquid Appearance Liquid Colour Odour Alcool Odour threshold No data available pH No data available Melting point No data available Freezing point No data available Boiling point 76 °C Flash point 21,5 °C Evaporation rate No data available flammability No data available Lower explosion limit No data available Upper explosion limit No data available Vapour pressure No data available Vapour density No data available Relative density No data available Density 0,8 kg/l < V < 0,95 kg/l Solubility (Water) Partially soluble with formation of a precipitate Solubility (Ethanol) No data available Solubility (Acetone) No data available Solubility (Organic solvents) No data available Log KOC No data available Auto-ignition temperature No data available Decomposition temperature No data available Kinematic viscosity No data available Dynamic viscosity No data available Particle characteristics Particle size No data available Dustiness No data available Specific surface area No data available Shape No data available

Further information

VOC content No data available Minimum ignition energy No data available Conductivity No data available Refractive index No data available Solids content No data available Surface tension No data available Saturation concentration No data available SECTION�10:�Stability�and�reactivity 10.1 - Reactivity - This material is considered to be non-reactive under normal use conditions. 10.2 - Chemical stability - The product is chemically stable under recommended conditions of storage, use and temperature. 10.3 - Possibility of hazardous reactions - No hazardous reaction when handled and stored according to provisions. 10.4 - Conditions to avoid - In case of warming: Ignition hazard 10.5 - Incompatible materials - No information available. 10.6 - Hazardous decomposition products - No information available. SECTION�11:�Toxicological�information

Aspiration hazard

- Based on available data, the classification criteria are not met. 11.2 - Information on other hazards SECTION�12:�Ecological�information 12.1 - Toxicity Toxicity Mixture EC50 48 hr crustacea No data available LC50 96 hr fish No data available ErC50 algae No data available ErC50 other aquatic plants No data available NOEC chronic fish No data available NOEC chronic crustacea No data available NOEC chronic algae No data available NOEC chronic other aquatic plants No data available - The substance/mixture does not fullfill the criteria of the acute aquatic toxicity according to Regulation (EC) No

Results of PBT and vPvB assessment

- This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. 12.6 - Endocrine disrupting properties - This product does not contain a substance that has endocrine disrupting properties with respect to non-target organisms as no components meets the criteria. 12.7 - Other adverse effects - No information available. SECTION�13:�Disposal�considerations 13.1 - Waste treatment methods Waste treatment methods - Dispose of waste according to applicable legislation. Sewage disposal - Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Special precautions for waste - Collect the waste separately. treatment Community or national or - No information available. regional provisions SECTION�14:�Transport�information 14.1 - UN number or ID number

UN Number

(ADR) UN1263 (RID) UN1263 (ADN) UN1263 (IMDG) UN1263 (IATA) UN1263 14.2 - UN proper shipping name UN proper shipping name PAINT (ethanol) (ADR) UN proper shipping name PAINT (ethanol) (RID) UN proper shipping name PAINT (ethanol) (ADN) UN proper shipping name PAINT (ethanol) (IMDG) UN proper shipping name PAINT (ethanol) (IATA) 14.3 - Transport hazard class(es) ADR Transport hazard 3 class(es) ADR Classification code: F1

Hazard pictograms

Transport hazard class(es) 3 (RID) Transport hazard class(es) 3 (ADN) Transport hazard class(es) 3 (IMDG) Transport hazard class(es) 3 (IATA) 14.4 - Packing group Packing group II Packing group (RID) II Packing group (ADN) II Packing group (IMDG) II Packing group (IATA) II

Environmental hazards

No Marine pollutant No 14.6 - Special precautions for user ADR ADR Classification code: F1 ADR Special provisions 163+367+640C+650 ADR Limited quantity (LQ) 5L ADR Excepted quantities E2 ADR Packing instructions P001 ADR Special packing provisions PP1 ADR Mixed packing provisions MP19 Instructions for portable tanks and bulk containers T4 Special provisions for portable tanks and bulk containers TP1 TP8 TP28 ADR tank code L1.5BN ADR tanks special provisions Vehicle for tank carriage FL ADR Transport category 2 ADR Tunnel restriction code D/E ADR Special provisions loading, unloading and handling Special provisions - Packages Special provisions - Bulk Special provisions - Operation S2 S20 ADR Hazard identification number (Kemler No.) 33 RID

Special Provisions

Limited quantity (LQ) Excepted quantities ADN Limited quantity (LQ) Excepted quantities IMDG 163 367 Limited quantity (LQ) 5 L Excepted quantities E2 Packing instructions P001 Special packing provisions PP1 IBC instruction(s) IBC02 IBC provisions Instructions for portable tanks and bulk containers T4 Special provisions for portable tanks and bulk containers TP1 TP8 TP28 EmS codes F-E, S-E Stowage and handling Category B Segregation Properties and observations Miscibility with water depends upon the composition. IATA PCA - Excepted quantities E2 PCA - Limited Quantity - Packing Instructions Y341 PCA - Limited Quantity - Maximum Net Quantity per Package 1L PCA - Packing Instructions 353 PCA - Maximum Net Quantity per Package 5L CAO - Packing Instructions 364 CAO - Maximum Net Quantity per Package 60L Special Provisions A3 A72 A192 ERG Code 3L 14.7 - Maritime transport in bulk according to IMO instruments SECTION�15:�Regulatory�information 15.1 - Safety, health and environmental regulations/legislation specific for the substance or mixture Substances REACH None candidates Substances Annex XIV None Substances Annex XVII None VOC content No data available 15.2 - Chemical Safety Assessment Chemical safety assessment carried - No information available. out for the product SECTION�16:�Other�information SDS versions Version Issue date Author Description of the amendments 2,02 09/01/2025 Tahina Rakotonirainy 1.1 add CEASS009C, 976165C 2,01 20/12/2023 Tahina Rakotonirainy 14. Packing Group II 2 25/07/2023 Tahina Rakotonirainy 1 09/09/2021 Abbreviations and acronyms - Agreement concerning the International Carriage of Dangerous Goods by Road - CAS: Chemical Abstracts Service (division of the American Chemical Society) - EINECS: European Inventory of Existing Commercial Chemical Substances - ELINCS: European List of Notified Chemical Substances - GHS: Globally Harmonised System of Classification and Labelling of Chemicals - IATA: International Air Transport Association - IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) - ICAO: International Civil Aviation Organisation - ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO) - IMDG: International Maritime Code for Dangerous Goods - RID European treaty on the international transport of hazardous substances by rail Evaluation methods The classification of the product is based on the calculation methods set out in Annex I to the CLP Regulation, unless otherwise specified in sections 11 and 12. Data for the assessment of physicochemical properties are presented in Texts of the regulatory sentences Acute Tox. 4

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [CLP] Flam. Liq. 2 Flammable liquid and vapour. - Category 2 Eye Irrit. 2 Eye irritation - Category 2