Toluene - Commercial Grade

CITGO Petroleum Corporation

Revision date : 2012-06-26

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

1330-20-7

Name of the chemical

Xylene

Concentration

N/A

Listed in

EC/CAS

100-41-4

Name of the chemical

Ethylbenzene

Concentration

N/A

Listed in

General Information

Revision date

2012-06-26

Product name

Toluene - Commercial Grade

Icons in SDS

Company Information

company name

CITGO Petroleum Corporation

Section 2

SECTION 2: Hazards identification

Major Route(s) of Entry Skin contact. Eye contact. Inhalation. Ingestion. Signs and Symptoms of Acute Exposure Inhalation Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Breathing this material may cause central nervous system depression with symptoms including nausea, headache, dizziness, fatigue, drowsiness, or unconsciousness. Breathing high concentrations of this material, for example, in an enclosed space or by intentional abuse, can cause irregular heartbeats which can cause death. Eye Contact This material can cause eye irritation with tearing, redness, or a stinging or burning feeling. Further, it can cause swelling of the eyes with blurred vision. Effects may become more serious with repeated or prolonged contact. Skin Contact May cause mild skin irritation with redness and/or an itching or burning feeling. Effects may become more serious with repeated or prolonged contact. It is likely that some components of this material are able to pass into the body through the skin and may cause similar effects as from breathing or swallowing it. Ingestion Swallowing this material may be harmful. Swallowing this material may cause stomach or intestinal upset with pain, nausea, and/or diarrhea. This material can get into the lungs during swallowing or vomiting. Small amounts in the lungs can cause lung damage, possibly leading to chronic lung dysfunction or death. Swallowing this material may cause effects similar to those described in the inhalation section (see "inhalation" above).

Potential chronic health

of ingestion and subsequent aspiration into the lungs may cause Summary pneumatocele (lung cavity) formation and chronic lung dysfunction. Reports have associated repeated and prolonged occupational overexposure to solvents with irreversible brain and nervous system damage (sometimes referred to as "Solvent or Painter's Syndrome"). This material (or a component) may cause harm to the human fetus based on tests with laboratory animals.Prolonged or repeated overexposure to toluene, a component of this product, has been associated with reproductive effects in experimental animals and in long-term chemical abuse situations. Long-term overexposure to toluene has been associated with impaired color vision. Also, long-term overexposure to toluene in occupational environments have been associated with hearing damage. Benzene, a component of this product, is associated with blood disorders and may damage bone marrow, causing certain types of anemia. The International Agency for Research on Cancer (IARC) (1987, 2004, 2007) and the U.S. EPA (IRIS 2007) have determined that benzene is a human carcinogen. It is also capable of causing changes in living cells' genetic material (chromosomes) and is considered to be a mutagen. Prolonged or repeated overexposure to xylene, a component of this product, has been associated with hearing damage in laboratory animals.Repeated overexposure may cause injury to bone marrow, blood cells, kidney, and liver. See Toxicological Information (Section 11) Conditions Aggravated Disorders of the following organs or organ systems that may be aggravated by significant by Exposure exposure to this material or its components include: Skin, Respiratory System, Central Nervous System (CNS), Heart (Cardiac) Target Organs May cause damage to the following organs: blood, kidneys, lungs, the nervous system, liver, mucous membranes, heart, brain, upper respiratory tract, skin, auditory system, central nervous system (CNS), eye, lens or cornea Carcinogenic Potential This material contains Benzene and Ethylbenzene at concentrations above 0.1%. Benzene is considered to be a known human carcinogen by OSHA, IARC and NTP. IARC identified Ethylbenzene as a Group 2B Carcinogen (possibly carcinogenic to humans) based on laboratory animal studies.

OSHA HCS Classification

is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present, the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR 1910.1200). OSHA Health Hazard Classification OSHA Physical Hazard Classification Irritant X Sensitizer Combustible Explosive Pyrophoric Toxic Highly Toxic Flammable X Oxidizer Water-reactive Corrosive Carcinogenic X Compressed Gas Organic Peroxide Unstable

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