CITGO Biodiesel (B33)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous system (CNS)) - Category 2

Aspiration hazard

Category 1

Signal word

Danger

Hazard statements

Flammable liquid and vapor. Harmful if inhaled. Causes skin irritation. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. (central nervous system (CNS))

Precautionary statements

General : Diesel engine exhaust can cause upper respiratory tract irritation and reversible pulmonary effects. Long-term exposure to diesel engine exhaust may cause cancer. Do not syphon by mouth.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention.

Storage

Store locked up. Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and receiving equipment. These alone may be insufficient to remove static electricity. Do not taste or swallow. Avoid contact with skin and clothing. Wash thoroughly after handling.

2.3 Other hazards

Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor may cause flash fire or explosion. Causes digestive tract burns. Prolonged or repeated contact may dry skin and cause irritation.