Electrically conductive ink Ag 520 El

Hazard statements (CLP)

H319, H400, H410

Code

Statements

H319

Causes serious eye irritation

2.1 Classification of the substance or mixture

and indication Classification 1272/2008 Eye irritation, category 2 H319 Causes serious eye irritation. Hazardous to the aquatic environment, acute toxicity, H400 Very toxic to aquatic life. category 1 Hazardous to the aquatic environment, chronic toxicity, H410 Very toxic to aquatic life with long lasting effects. category 1

67/548/EEC

and 1999/45/EC Directives and following amendments and adjustments

Hazard pictograms

N E

R-phrase(s)

50/53 The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P264 Wash... thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: get medical advice. P391 Collect spillage.

2.3 Other hazards

Information not available. 3.1. Substances. Information not relevant. 3.2. Mixtures.

Contains

Identification. Conc. %.

Prevention

gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Normal fire fighting clothing i¡.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). 6.1. Personal precautions, protective equipment and emergency procedures. Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in emergency procedures. 6.2. Environmental precautions. The product must not penetrate into the sewer system or come into contact with surface water or ground water. 6.3. Methods and material for containment and cleaning up. Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 6.4. Reference to other sections. Any information on personal protection and disposal is given in sections 8 and 13. 7.1. Precautions for safe handling. Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they may be pressurised. Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. 7.2. Conditions for safe storage, including any incompatibilities. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details. 7.3. Specific end use(s). Information not available. 8.1. Control parameters. Regulatory References: ITA Italia Decreto Legislativo 9 Aprile 2008, n.81 Threshold Limit Value. Type Country TWA/8h STEL/15min mg/m3 ppm mg/m3 ppm TLV ITA 0,1 Predicted no-effect concentration - PNEC. Normal value in fresh water 0,00004 mg/L Normal value in marine water 0,00086 mg/L Normal value for fresh water sediment 438,13 mg/kg Normal value for marine water sediment 438,13 mg/kg Normal value of STP microorganisms 0,025 mg/L Normal value for the terrestrial compartment 0,794 mg/kg Legend: (C) = CEILING INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. VND = hazard identified but no DNEL/PNEC available NEA = no exposure expected NPI= no hazard identified. 8.2. Exposure controls. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. When choosing personal protective equipment, ask your chemical substance supplier for advice. Personal protective equipment must be CE marked, showing that it complies with applicable standards. Provide an emergency shower with face and eye wash station. HAND PROTECTION Protect hands with category lll work gloves (see standard EN 374). The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use. SKIN PROTECTION Wear category | professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with soap and water after removing protective clothing. EYE PROTECTION Wear airtight protective goggles (see standard EN 166). RESPIRATORY PROTECTION If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type filter whose class (1, or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. ENVIRONMENTAL EXPOSURE CONTROLS. The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. 9.1. Information on basic physical and chemical properties. Appearance viscous liquid Colour black Odour characteristic of solvent Odour threshold. Not available. pH. Not available. 9. Physical and chemical properties. Melting point / freezing point. Not available. Initial boiling point. Not available. Boiling range. Not available. Flash point. 60 ec. Evaporation Rate Not available. Flammability of solids and gases flammable gas Lower inflammability limit. Not available. Upper inflammability limit. Not available. Lower explosive limit. Not available. Upper explosive limit. Not available. Vapour pressure. Not available. Vapour density Not available. Relative density. Not available. Solubility insoluble Partition coefficient: n-octanol/water Not available. Auto-ignition temperature. Not available. Decomposition temperature. Not available. Viscosity 30 Pa.s Explosive properties Not available. Oxidising properties Not available.

Further information

Information not available. 10.1. Reactivity. There are no particular risks of reaction with other substances in normal conditions of use. 10.2. Chemical stability. The product is stable in normal conditions of use and storage. 10.3. Possibility of hazardous reactions. No hazardous reactions are foreseeable in normal conditions of use and storage. 10.4. Conditions to avoid. None in particular. However the usual precautions used for chemical products should be respected. 10.5. Incompatible materials. Information not available. 10.6. Hazardous decomposition products. In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. 11.1. Information on toxicological effects. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product. Acute effects stinging eyes. Symptoms may include rubescence, edema, pain and lachrymation Vapour inhalation may moderately irritate the upper respiratory trait. Contact with skin may cause slight irritation. Ingestion may cause health problems, including stomach pain and sting, nausea and sickness. Silver powder LD50 (Oral). > 2000 mg/kg bw Rat gavage (OECD 401) (Allen 1993a) LC50 (Inhalation). > 5,16 mg/L OECD 436) (Haferkorn 2012) Diethylene glycol monoethyl ether acetate LD50 (Oral). 11 mg/Kg rat LD50 (Dermal). 15,281 mg/Kg rabbit This product is dangerous for the environment and highly toxic for aquatic organisms. In the long term, it have negative effects on aquatic environment. 12.1. Toxicity. Silver powder LC5O0 - for Fish. 0,0012 mg/l/96h Pimephaleas promelas; Test material: AgNO3 EC5O0 - for Crustacea. 0,00022 mg/l/48h Daphnia Magna; Test material: AyNO3 12.2. Persistence and degradability. Information not available. 12.3. Bioaccumulative potential. Information not available. 12.4. Mobility in soil. Information not available. 12.5. Results of PBT and vPvB assessment. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 12.6. Other adverse effects. Information not available. 13.1. Waste treatment methods. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Avoid littering. Do not contaminate soil, sewers and waterways. Waste transportation may be subject to ADR restrictions. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. These goods must be transported by vehicles authorized to the carriage of dangerous goods according to the provisions set out in the current edition of the Code of International Carriage of Dangerous Goods by Road (ADR) and in all the applicable national regulations. These goods must be packed in their original packagings or in packagings made of materials resistant to their content and not reacting dangerously with it. People loading and unloading dangerous goods must be trained on all the risks deriving from these substances and on all actions that must be taken in case of emergency situations. Road and rail transport: ADR/RID Class: 9 UN: 3082 Packing Group: HI Label: 9 Nr. Kemler: 90 <> Limited Quantity. 5L Tunnel restriction code. (E) Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANGCE, LIQUID, N.O.S. (Silver powder) Carriage by sea (shipping): IMO Class: 9 UN: 3082 Packing Group: HI Label: 9 EMS: F-A, S-F Marine Pollutant. YES Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver powder) Transport by air: ATA: 9 UN: 3082 Packing Group: HI Label: 9 Cargo: Packaging instructions: 964 Maximum quantity: Pass.: Packaging instructions: 964 Maximum quantity: 450 L Special Instructions: A97,A158, A197 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver powder) 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. 9i Restrictions relating to the product or contained substances pursuant to Annex XVI! to EC Regulation 1907/2006. Product. Point. 3 Substances in Candidate List (Art. 59 REACH). None. Substances subject to authorisarion (Annex XIV REACH). None. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: None. Substances subject to the Rotterdam Convention: None. Substances subject to the Stockholm Convention: None. Healthcare controls. Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected. 15.2. Chemical safety assessment. A chemical safety assessment has been performed for the following contained substances. Silver powder Text of hazard (H) indications mentioned in section 2-3 of the sheet: Eye Irrit. 2 Eye irritation, category 2 Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1 Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1 H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUHO19 May form explosive peroxides. Text of risk (R) phrases mentioned in section 2-3 of the sheet: R19 MAY FORM EXPLOSIVE PEROXIDES. R36 IRRITATING TO EYES. R50/53 VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT. LEGEND: - ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE5O0: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive of existing substances) Paxen. s/8 - CLP: EC Regulation 1272/2008 - DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System of classification and labeling of chemicals - ¡ATA DGR: International Air Transport Association Dangerous Goods Regulation - 1250: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI of CLP - LC5O: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level