Toluene Standardization Fuel 94.8

SECTION 2: Hazards identification

GHS Classification ************************************************************************************************************** EMERGENCY OVERVIEW Clear non-viscous liquid with strong gasoline odor.

NFPA Ratings

Health: 2 Flammability: 3 Reactivity: 0

2.1 Classification of the substance or mixture

and Labeling Flammable liquid: Category 2. Acute aquatic toxicant Category 2. Chronic aquatic toxicant Category 2 Aspiration toxicant Category 1. Skin irritation Category 2. Target organ toxicant (repeated exposure) Category 2 Reproductive toxicant Category 2. Target organ toxicant (central nervous system) Category 3. Target organ toxicant respiratory irritant) Category 3. Acute inhalation toxicant Category 4

Signal word

Danger Danger

Hazard pictograms

Target Organ: May cause damage to organs (Auditory System, Nervous System) through prolonged or repeated exposure.

Physical hazards

Highly flammable liquid and vapor

Environmental hazards

Toxic to aquatic life. Toxic to aquatic life with long lasting effects

Health hazards

May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child Causes skin irritation. Harmful if inhaled. May cause drowsiness or dizziness. May cause respiratory irritation. Precautionary Hazard - Prevention: Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/equipment. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Avoid release to the environment. Precautionary Hazard - Response IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Take off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Wash with plenty of soap and water. Do NOT induce vomiting. Get medical advice/attention. Specific treatment (see Notes to Physician on this label). In case of fire: Use manufacturer/supplier or the competent authority to specify appropriate media for extinction. Collect spillage. Precautionary Hazard - Storage: Store in a well-ventilated place. Keep cool. Store locked up. Precautionary Hazard - Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Hazard statements

R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66: Repeated exposure may cause skin dryness or cracking. R63: Possible risk of harm to the unborn child. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation R65 Harmful may cause lung damage if swallowed R36/38: Irritating to eyes and skin. R11: Highly flammable. R67: Vapors may cause drowsiness and dizziness. Additional Hazards: MAY CAUSE DAMAGE TO: - - - - - NERVOUS SYSTEM - - - - - AUDITORY SYSTEM

Precautionary statements

S9: Keep container in a well-ventilated place. S24/25: Avoid contact with skin and eyes. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S38: In case of insufficient ventilation, wear suitable respiratory equipment. S51: Use only in well-ventilated areas. S16: Keep away from sources of ignition - No smoking. S2: Keep out of the reach of children. S62 If swallowed do not induce vomiting seek medical advice immediately and show this container or label S36/37: Wear suitable protective clothing and gloves. ************************************************************************************************************** IMMEDIATE HEALTH EFFECTS: Eye: Contact with the eyes causes irritation. Symptoms may include pain, tearing, reddening, swelling and impaired vision. Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin causes irritation. Prolonged or repeated skin contact may cause drying or defatting of the skin. Symptoms may include pain, itching, discoloration, swelling, and blistering. Contact with the skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: This material can directly enter the lungs, if swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death. Inhalation: Breathing of high vapor concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and difficulty in breathing. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness, coma or death. DELAYED OR OTHER HEALTH EFFECTS: Reproduction and Birth Defects: Contains material that may be harmful to the developing fetus based on animal data. Target Organs: Repeated inhalation of this material at elevated concentrations may cause damage to the following organ(s) based on animal data: - Nervous System - Auditory SystemSee Section 11 for additional information. Risk depends on duration and level of exposure.