Dimethyl Disulfide

Hazard statements (CLP)

H225, H301+H331, H305, H315+H320, H317, H335, H336, H361, H370, H372, H411

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

GHS Classification and Labeling: Follow GB 13690, GB 15258 and GB 30000.2 to GB 30000.29 (GHS 2011) Emergency Overview Danger Form liquid Physical state liquid Color Yellow Odor Mildly unpleasant : Highly flammable liquid and vapor. Toxic if swallowed. Toxic if inhaled. Causes skin irritation. Causes eye irritation. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. Causes damage to organs if inhaled. May cause respiratory irritation., May cause drowsiness or dizziness. Causes damage to organs through prolonged or repeated exposure. May be harmful if swallowed and enters airways. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Classifications

Flammable liquids, Category 2 Acute toxicity, Category 3, Oral Acute toxicity, Category 3, Inhalation Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2B Skin sensitization, Category 1 Reproductive toxicity, Category 2 Specific target organ toxicity - single exposure, Category 1, Inhalation, Respiratory Tract Specific target organ toxicity - single exposure, Category 3, respiratory tract irritation, Narcotic effects Specific target organ toxicity - repeated exposure, Category 1 Aspiration hazard, Category 2 Short-term (acute) aquatic hazard, Category 2 Long-term (chronic) aquatic hazard, Category 2

Signal word

Danger

Hazard statements

H225: Highly flammable liquid and vapor. H301 + H331: Toxic if swallowed or if inhaled. H305: May be harmful if swallowed and enters airways. H315 + H320: Causes skin and eye irritation. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H361: Suspected of damaging fertility or the unborn child. H370: Causes damage to organs (Respiratory Tract) if inhaled. H372: Causes damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330: IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311: IF exposed or concerned: Call a POISON CENTER/ doctor. P331: Do NOT induce vomiting. P333 + P313: If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/ attention. P362+P364: Take off contaminated clothing and wash it before reuse. P370+P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391: Collect spillage.

Storage

P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.