5044

Hazard statements (CLP)

H226, H312, H314, H317, H332, H333, H361, H370

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA EMERGENCY OVERVIEW: ..... Corrosive. Clear, colorless, basic liquid with an amine (ammonia) odor. Product is corrosive to eyes, skin, and respiratory system. Skin absorption, inhalation, or ingestion may also result in toxic effects. May react with acids. Container head space gases may be flammable if exposed to a source of ignition.

Precautionary statements

P262: Do not get in eyes, on skin, or on clothing. P280: Wear protective gloves/protective clothing/eye protection/face protection; when conditions warrant use, add face shield, apron, and/or rubber boots. P260: Do not breathe dust/fume/gas/mist/vapors/spray. P264: Wash ... thoroughly after handling, wash gloves and contaminated surfaces. P272: Contaminated work clothing should not be allowed out of the workplace. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P234: Keep only in original packaging. P370+378 In case of fire Use whatever extinguishing media is appropriate for extinction P305+351+338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing for 15 min. call a doctor. P303+361+353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately, call a doctor. P332+313 If skin irritation occurs Get medical advice/attention P363: Wash contaminated clothing before reuse. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P301+330+331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P501: Dispose of contents/container in accordance with local state and federal regulations.

2.3 Other hazards

Headspace gases in open units or residual gases in empty units may represent a fire hazard if exposed to a source of ignition. Product contains 5-20% cyclohexylamine. Cyclohexylamine has a flash point of 79 degrees F. The lower explosive limit (LEL) is 1.6% (V). Product contains 5-20% morpholine. Morpholine has a flash point of 98 degrees F. The lower explosive limit (LEL) is 1.4% (V).

Environmental effects

Significant contamination of small bodies of surface water or localized areas at the point of a spill may elevate pH levels above tolerable levels for aquatic organisms or expose organism to toxic effects of amine ingredients.

2.1 Classification of the substance or mixture

Corrosive to skin ............................. Category 1, Subcategory 1B Serious eye damage ......................... Category 1 STOT-SE (single target organ toxicity - single exposure), digestive system (ingestion) Category 1 STOT-SE (single target organ toxicity - single exposure), respiratory system (inhalation) Category 2 Skin sensitizer ................................. Category 1B Toxic to Reproduction ..................... Category 2 Flammable liquid ............................ Category 3 GHS SIGNAL WORD: ................. Danger GHS HAZARD STATEMENTS:. H314: Causes severe skin burns and eye damage H312: Harmful in contact with skin. H317: May cause an allergic skin reaction. H332: Harmful if inhaled. H370: Causes damage to organs: causes damage to gastrointestinal system by ingestion. H333: May be harmful if inhaled: may cause damage to respiratory system by inhalation (aerosol or mist). H361: Suspected of damaging fertility or the unborn child based on oral exposures to rats reported in the literature. H226: Flammable liquid and vapor.