CHEMLINER

Hazard statements (CLP)

H226, H315, H317, H319, H334, H335, H340, H350, H360, H373

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

Flammable Liquids - Category 3 H226 Flammable liquid and vapour. Skin Irritation - Category 2 H315 Causes skin irritation. Eye Irritation - Category 2A H319 Causes serious eye irritation. Respiratory Sensitizer - Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Sensitizer - Category 1 H317 May cause an allergic skin reaction. Germ Cell Mutagenicity - Category 1B H340 May cause genetic defects. Carcinogenicity - Category 1B H350 May cause cancer. Reproductive Toxicity - Category 1 H360 May damage fertility or the unborn child. Specific Target Organ Toxicity - Single Exposure - H335 May cause respiratory irritation. Category 3 Specific Target Organ Toxicity - Repeated Exposure - H373 M a y ca u s e d a m a g e t o o r g a n s t h ro u g h Category 2 prolonged or repeated exposure.

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS)

Hazard pictograms

d ~dd~ GHS02 GHS07 GHS08

Signal word

Danger

Hazardous Ingredients

4,4'-methylenediphenyl diisocyanate Solvent naphtha (petroleum), light arom. 4-methyl-m-phenylene diisocyanate 2-methyl-m-phenylene diisocyanate

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H340 May cause genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. · WHMIS-symbols: B2 - Flammable liquid D2A - Very toxic material causing other toxic effects :__=

Precautionary statements

Keep out of reach from children. P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 Use explosion-proof [electrical/ventilating/lighting] equipment. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P284 [In case of inadequate ventilation] wear respiratory protection. P280 Wear protective gloves/protective clothing/eye protection/face protection. P240 Ground and bond container and receiving equipment. P242 Use non-sparking tools. P243 Take actions to prevent static discharges. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P308+P313 IF exposed or concerned: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P370+P378 In case of fire Use for extinction CO2, powder or water spray P362+P364 Take off contaminated clothing and wash it before reuse. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification system

NFPA ratings (scale 0 - 4) Health = 3 3 Fire = 3 3 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 3 Fire = 3 REACTIVITY 0 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable