Note: Ingredients listed on restricted chemical lists
EC/CAS
5989-27-5
Name of the chemical
(R)-p-mentha-1,8-diene
Concentration
15-40
General Information
Revision date
2014-09-26
Product name
VOLTZ RED
Emergency telephone
800-424-9300
Icons in SDS
Company Information
company name
CHEMSEARCH DIV. OF NCH CORP
GHS Information
Signal word
DANGER
Section 2
SECTION 2: Hazards identification
Color Red - Orange Physical State Liquid Odor Orange GHS Classification Physical Hazards Flammable liquids Category 4 Health Hazard Aspiration Toxicity Acute Dermal Toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Respiratory Sensitization Category 1 Category 4 Category 2 Category 2B Skin Sensitization Specific target organ systemic toxicity (single exposure) Specific target organ systemic toxicity (repeated exposure) Category 1 Category 3 Category 2
Other hazards
None
Signal word
DANGER
Hazard statements
H227 - Combustible liquid H315 - Causes skin irritation H312 - Harmful in contact with skin H317 - May cause an allergic skin reaction H320 - Causes eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H336 - May cause drowsiness or dizziness H304 - May be fatal if swallowed and enters airways H373 - May cause damage to organs through prolonged or repeated
Precautionary statements
P210 - Keep away from heat, sparks, open flames or hot surfaces. P280 - Wear protective gloves, protective clothing and eye protection. P264 - Wash face, hands and any exposed skin thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace P260 - Do not breathe mist or vapor. P271 - Use in a well-ventilated area. P302+ P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs, get medical attention P362 - Take off contaminated clothing and wash before reuse P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. exposure Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists, get medical attention. P304 + P340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P342 + P311 - If experiencing respiratory symptoms, call a physician P301+ P330 + P331 - IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Call a physician if unwell. P233 - Keep container tightly closed P403 + P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents and container in accordance with applicable regulations.
2.1 Classification of the substance or mixture
Physical Hazards Flammable liquids Category 4 Health Hazard Aspiration Toxicity Category 1 Acute Dermal Toxicity Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2B Respiratory Sensitization Category 1 Skin Sensitization Category 1 Specific target organ systemic toxicity (single exposure) Category 3 Specific target organ systemic toxicity (repeated exposure) Category 2 Other hazards None Labeling Signal Word DANGER Hazard Statements Precautionary Statements H227 - Combustible liquid P210 - Keep away from heat, sparks, open flames or hot surfaces. H315 - Causes skin irritation P280 - Wear protective gloves, protective clothing and eye protection. H312 - Harmful in contact with skin P264 - Wash face, hands and any exposed skin thoroughly after handling. H317 - May cause an allergic skin reaction P272 - Contaminated work clothing should not be allowed out of the workplace H320 - Causes eye irritation P260 - Do not breathe mist or vapor. H334 - May cause allergy or asthma symptoms or breathing difficulties if P271 - Use in a well-ventilated area. inhaled P302+ P352 - IF ON SKIN: Wash with plenty of soap and water H336 - May cause drowsiness or dizziness P333 + P313 - If skin irritation or rash occurs, get medical attention H304 - May be fatal if swallowed and enters airways P362 - Take off contaminated clothing and wash before reuse H373 - May cause damage to organs through prolonged or repeated P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. exposure Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists, get medical attention. P304 + P340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P342 + P311 - If experiencing respiratory symptoms, call a physician P301+ P330 + P331 - IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Call a physician if unwell. P233 - Keep container tightly closed P403 + P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents and container in accordance with applicable regulations. 3. COMPOSITION / INFORMATION ON INGREDIENTS Component CAS-No Weight % Petroleum distillates, hydrotreated light 64742-47-8 60-100 D-Limonene 5989-27-5 15-40 *** 4. FIRST AID MEASURES General advice Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms occur. Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if symptoms occur. Notes to physician Aspiration hazard if swallowed - can enter lungs and cause damage. May be fatal if swallowed and enters airways. 5. FIRE-FIGHTING MEASURES Flash Point > 142 °F / > 61 °C Method Seta closed cup Flammability Limits in Air % Solvent mixture. Upper 7.0 Lower 0.6 Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards arising from the chemical Combustible Liquid. Solvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 2 Instability 0 HMIS Health 2 Flammability 2 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Methods for Cleaning Up Use clean non-sparking tools to collect absorbed material. Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable. 7. HANDLING AND STORAGE Handling Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Storage Keep away from heat and sources of ignition. Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Storage Temperature Minimum 35 °F / 2 °C Maximum 120 °F / 49 °C Storage Conditions Indoor X Outdoor Heated Refrigerated 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH Petroleum distillates, hydrotreated light 525 mg/m3 TWA No data available Engineering Measures Ensure adequate ventilation, especially in confined areas. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection Wear suitable protective clothing, Impervious gloves. Respiratory Protection In case of insufficient ventilation wear suitable respiratory equipment. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General Hygiene Considerations Wear protective gloves/clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Remove and wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid