CHEMTHANE 3725 PART B

Hazard statements (CLP)

H302, H315, H319, H336, H401, H412

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Classification of the substance or mixture

Signal word

WARNING

Hazard statements

H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H302 - Harmful if swallowed H401 - Toxic to aquatic life H412 - Harmful to aquatic life with long lasting effects

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash skin thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P281 - Use personal protective equipment as required. P302+352 - IF ON SKIN: Wash with soap and water. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 - IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308+313 - IF exposed or concerned: Get medical advice/attention. P310 - Immediately call a POISON CENTER or doctor/physician. P314 - Get Medical advice/attention if you feel unwell. P332+313 - If skin irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370+378 - In case of fire: Use dry chemical, foam, carbon dioxide or water for extinction. P403+233 - Store in a well ventilated place. Keep container tightly closed. P403+235 - Store in a well ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to a licensed waste disposal facility.

Principle Routes of Exposure

Inhalation; Skin; Eyes; Target Organs: Eyes; Respiratory system; Skin; Inhalation: Due to the low vapor pressure of the major components used in this product, it is unlikely that inhalation exposure will occur when handling this product under normal working conditions and at room temperature. However, during heating, spray application or processing of this product, it is possible that an exposure could occur. This product as a whole may then be expected to cause irritation of the upper respiratory tract and mucous membranes of the mouth, nose and throat. Symptoms may include coughing, headache, nausea, vomiting, and chest pain. This product contains an aromatic diamine, diethyltoluenediamine, inhalation exposure can cause methemoglobinemia with symptoms of cyanosis, a purplish-blue color of the skin, fingernails and lips. Skin Contact: Upon contact, irritation and defatting of the skin are possible. The hindered amine and aliphatic amine components are considered to be fairly strong skin sensitizers and may cause an allergic skin reaction. The diethyltoluenediamine (DETDA) component of this product is fat-soluble and can penetrate the skin. Based on animal tests, DETA is expected to be toxic. Skin contact and skin absorption of DETA can cause methemoglobinemia with symptoms of cyanosis, a purplish-blue color of the skin, fingernails and lips. Contact can cause irritation with redness, and severe swelling and blistering. Eye Contact: This product as a whole can cause severe irritation to the eyes. Diethyltoluenediamine (DETDA) is considered severely irritating and corrosive to the eyes. The vapors have also been reported to cause transient fogging of the eyes as a result of corneal edema.

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS): Health, Skin corrosion/irritation, 2 Health, Serious Eye Damage/Eye Irritation, 2 A Health, Specific target organ toxicity - Single exposure, 3 Health, Acute toxicity, 4 Oral Environmental, Hazards to the aquatic environment - Acute, 2 Environmental, Hazards to the aquatic environment - Chronic, 3