Polytanol

Hazard statements (CLP)

H260, H301, H315, H318, H330, H335, H400

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the mixture

Hazard pictograms

GHS02 GHS05 GHS06 GHS09

Signal word

Danger

Hazard statements

H260: In contact with water releases flammable gases which may ignite spontaneously. H301: Toxic if swallowed. H330: Fatal if inhaled. (see subsection 11.1.1.) H315: Causes skin irritation. H318: Causes serious eye damage. H335: May cause respiratory irritation. H400: Very toxic to aquatic life.

Supplemental label elements

EUH029: Contact with water liberates toxic gas. EUH032: Contact with acids liberates very toxic gas. EUH401: To avoid risks to human health and the environment, comply with the instructions for use.

Prevention

P102: Keep out of reach of children. P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire. P233: Keep container tightly closed. P261: Avoid breathing dust/fume/ gas/mist/vapours/spray. P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/ face protection. Reaction: P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P335+P334: Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. P304+P340+P310 IF INHALED Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P362+P364: Take off contaminated clothing and wash before reuse. P370+P378 In case of fire Use dry sand or dry powder for extinction

Storage

P402+P404: Store in a dry place. Store in a closed container.

Disposal

P501: Dispose of contents/container to the hazardous waste site or the manufacturer. 2.2.2. Regulation (EU) No 547/2011 (Labelling requirements for plant protection products) Safety phrases according to Annex III SP 1: Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads). SPo 1: After contact with skin, first remove product with a dry cloth and then wash the skin with plenty of water. SPo 2: Wash all protective clothing after use. SPo 4: The container must be opened outdoors and in dry conditions. SPe 3: To protect aquatic organisms/non-target plants/non-target arthropods/insects respect an unsprayed buffer zone of (distance to be specified) to non-agricultural land/surface water bodies. SPe 6: To protect birds/wild mammals remove spillages.

2.3 Other hazards

See subsections 15.1.1. and 15.1.2. The mixture does not meet the PBT / vPvB criteria as an inorganic substance according to Annex XIII of the REACH Regulation.

2.1 Classification of the substance or mixture

2.1.1 Classification according to Regulation (EC) No 1272/2008 (CLP Regulation) Water-react. 1, H260 Acute Tox. 3, H301 Acute Tox. 1, H330 (see subsection 11.1.1.) Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, RTI, H335 Aquatic Acute 1, H400