DIMETHOATE 400 g/l + GAMMA-CYHALOTHRIN 6.4 g/l EC

CHEMINOVA A/S

Revision date : 2011-02-02

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GHS02 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 2
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

616-373-3/76703-62-3

Name of the chemical

gamma-Cyhalothrin

Concentration

N/A

Listed in

EC/CAS

215-535-7/1330-20-7

Name of the chemical

Xylene

Concentration

N/A

Listed in

EC/CAS

265-199-0/64742-95-6

Name of the chemical

Solvent naphtha (petroleum), light arom

Concentration

N/A

General Information

Revision date

2011-02-02

Product name

DIMETHOATE 400 g/l + GAMMA-CYHALOTHRIN 6.4 g/l EC

Icons in SDS

GHS02 GHS07 GHS08 GHS09 M004 M009 M010 M017

Company Information

company name

CHEMINOVA A/S

e-mail address of the competent person responsible for the Safety Data Sheet

sds@cheminova.dk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H302, H304, H315, H319, H332, H400, H410

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

See section 16 for full text of R-phrases and hazard statements. DPD classification of the product R10 Xn;R20/21/22 N;R50/53 according to Dir. 1999/45/EC as amended CLP classification of the product Flammable liquid: Category 3 (H226) according to Reg. 1272/2008 as amended Acute oral toxicity: Category 4 (H302) Inhalation toxicity: Category 4 (H332) Skin irritation: Category 2 (H315) Eye irritation: Category 2 (H319) Aspiration toxicity: Category 1 (H304) Hazards to the aquatic environment: Acute Category 1 (H400) Chronic Category 1 (H410) WHO classification ...................... Class II: Moderately hazardous Guidelines to Classification 2009

Other physicochemical hazards

The product is flammable.

Health hazards

The product is harmful by inhalation and by ingestion. It may be moderately irritating to skin and eyes. The active ingredient dimethoate is a poison (cholinesterase inhibitor). It rapidly enters the body on contact with all skin surfaces and eyes. Repeated exposures to cholinesterase inhibitors such as dimethoate may, without warning, cause increased susceptibility to doses of any cholinesterase inhibitor. Gamma-cyhalothrin is very toxic by inhalation and toxic if swallowed. Chronic exposure may cause functional changes in the central and peripheral nervous systems (see section 11).

Environmental hazards

The product is very toxic to aquatic organisms. Contains dimethoate, cyclohexanone, xylene

2.2 Label elements

According to Dir. 1999/45/EC as amended

Hazard pictograms

Xn N Harmful Dangerous for the (GHS02, GHS07, GHS08, GHS09)

R-phrase(s)

R10 ................................................ Flammable. R20/21/22 ...................................... Harmful by inhalation, in contact with skin and if swallowed. R50/53 ........................................... Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S24/25 ........................................... Avoid contact with skin and eyes. S28 ................................................ After contact with skin, immediately wipe off with dry cloth followed by washing with plenty of water and soap. S36/37 ........................................... Wear suitable protective clothing and gloves. S45 ................................................ In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 ................................................ This material and its container must be discarded as hazardous waste. S61 ................................................ Avoid release to the environment. Refer to special instructions/safety data sheets. Other mentions .............................. Contains gamma-cyhalothrin. May produce an allergic reaction. To avoid risks to man and the environment, comply with the instructions of use. Additional phrases for final use of the product for plant protection S2 .................................................. Keep out of the reach of children. S13 ................................................ Keep away from food, drink and animal feedingstuffs. S23 ................................................ Do not breathe spray. S29 ................................................. Do not empty into drains. SP1 ................................................ Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads). According to EU Reg. 1272/2008 as amended

Product definition

Dimethoate 400 g/l + Gamma-cyhalothrin 6.4 g/l EC Contains dimethoate, gamma-cyhalothrin, cyclohexanone, xylene

Signal word

Danger

Hazard statements

H226 .............................................. Flammable liquid and vapour. H302 .............................................. Harmful if swallowed. H332 .............................................. Harmful if inhaled. H315 .............................................. Causes skin irritation. H319 .............................................. Causes serious eye irritation. H304 .............................................. May be fatal if swallowed and enters airways. H410 .............................................. Very toxic to aquatic life with long lasting effects.

Supplemental label elements

EUH208 ........................................ Contains gamma-cyhalothrin. May produce an allergic reaction. EUH401 ........................................ To avoid risks to human health and the environment, comply with the instructions of use. Supplementary phrase for final use of the product for plant protection: SP1 Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads).

Precautionary statements

P261 .............................................. Avoid breathing vapours. P280 .............................................. Wear protective gloves and eye/face protection. P310 .............................................. Immediately call a POISON CENTER or doctor/physician. P302+P335+P352 .......................... IF ON SKIN: Brush off loose particles from skin, thereafter wash with plenty of water and soap. P305+P351+P338 .......................... IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 .............................................. Dispose of contents/container in accordance with local regulation.

2.3 Other hazards

The product does not meet the criteria for being PBT or vPvB.

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