Chlorpyrifos 4E, Cyren, Nufos

Hazard statements (CLP)

H301, H304, H319, H332, H351, H400, H410

Code

Statements

H301

Toxic if swallowed

2.1 Classification of the substance or mixture

See section 16 for full text of R-phrases and hazard statements. DPD classification of the product Carc3;R40 Xn;R20/22 Xi;R38 R65 N;R50/53 according to Dir. 1999/45/EC as amended CLP classification of the product Acute oral toxicity: Category 3 (H301) according to Reg. 1272/2008 as amended Acute inhalation toxicity: Category 4 (H332) Eye irritation: Category 2 (H319) Carcinogenicity: Category 2 (H351) Aspiration toxicity: Category 1 (H304) Hazards to the aquatic environment: Acute Category 1 (H400) Chronic Category 1 (H410) WHO classification ...................... Class II: Moderately hazardous Guidelines to Classification 2009

Health hazards

The product is harmful by inhalation and by ingestion. It has irritating properties. Chlorpyrifos is a dangerous poison (cholinesterase inhibitor). It rapidly enters the body on contact with all skin surfaces and eyes. Exposed persons must receive prompt medical treatment. Repeated exposures to cholinesterase inhibitors such as chlorpyrifos may, without warning, cause increased susceptibility to doses of any cholinesterase inhibitor. The product contains max. 5% of naphthalene, which is a suspected carcinogen.

Environmental hazards

The product is very toxic to aquatic organisms. Contains chlorpyrifos and solvent naphtha (petroleum), heavy aromatic

2.2 Label elements

According to Dir. 1999/45/EC as amended

Hazard pictograms

Xn N Harmful Dangerous for the (GHS06, GHS08, GHS09)

R-phrase(s)

R40 ................................................ Limited evidence of a carcinogenic effect. R20/22 ........................................... Harmful by inhalation and if swallowed. R38 ................................................ Irritating to skin. R65 ................................................ Harmful: may cause lung damage if swallowed. R50/53 ........................................... Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S24 ................................................ Avoid contact with skin. S36/37 ........................................... Wear suitable protective clothing and gloves. S46 ................................................ If swallowed, seek medical advice immediately and show this container or label. S60 ................................................ This material and its container must be disposed of as hazardous waste. S61 ................................................ Avoid release to the environment. Refer to special instructions/safety data sheets. Other mention ............................... To avoid risks to man and the environment, comply with the instructions of use. Additional phrases for final use of the product for plant protection S2 .................................................. Keep out of the reach of children. S13 ................................................ Keep away from food, drink and animal feedingstuffs. S23 ................................................ Do not breathe spray. S29 ................................................. Do not empty into drains. SP1 ................................................ Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads). According to EU Reg. 1272/2008 as amended

Product definition

Chlorpyrifos 480 g/l EC Contains chlorpyrifos and solvent naphtha (petroleum), heavy aromatic

Signal word

Danger

Hazard statements

H301 .............................................. Toxic if swallowed. H332 .............................................. Harmful if inhaled. H319 .............................................. Causes serious eye irritation. H351 .............................................. Suspected of causing cancer. H304 .............................................. May be fatal if swallowed and enters airways. H410 .............................................. Very toxic to aquatic life with long lasting effects.

Supplemental label elements

EUH066 ........................................ Repeated exposure may cause skin dryness and cracking. EUH401 ........................................ To avoid risks to human health and the environment, comply with the instructions of use. Supplementary phrase for final use of Do not contaminate water with the product or its container (Do not the product for plant protection: SP1 clean application equipment near surface water/Avoid contamination via drains from farmyards and roads).

Precautionary statements

P261 .............................................. Avoid breathing vapours. P273 .............................................. Avoid release to the environment. P280 .............................................. Wear eye/face protection. P305+P351+P338 .......................... IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 .............................................. Immediately call a POISON CENTER or doctor/physician. P501 .............................................. Dispose of contents/container as hazardous waste.

2.3 Other hazards

None of the ingredients in the product meets the criteria for being PBT or vPvB.