Gardacid P 4309

Hazard statements (CLP)

H272, H302, H314, H315, H317, H318, H332, H334, H341, H350i, H360D, H372, H400, H410

Code

Statements

H272

May intensify fire; oxidiser

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Concentration Registration num- (EC) No ber 1272/2008) Zinc bis (dihydrogen 13598-37-3 Xn; R22 use. Aquatic Acute >= 2.5 - 10 Dhosphate) 237-067-2 other 1; H400 01-21 19485974- N; R50 any 19-0000 only. for Acute Tox. 4; 01-21 19485974- H302 19-0001 purposes 01 -21 19485974- required 19-0002 owner 01-21 19485974- inspection copyright 19-0003 For 3rthophosphoric acid 7664-38-2 of C; R34 Skin Corr. IB; > = 5 - < 1 0 Consent 231 -633-2 H314 Nota B 0 Vickel(l1) nitrate 1 31 38-45-9 Carc.Cat.1; R49 0; R 8 ox. Sol. 2; > = 5 - < 1 0 236-068-5 H272 Carc. IA; H350i Repr.Cat.2; R61 Muta. 2; H341 Mut.Cat.3; R68 Repr. IB; T; R48/23 H360D Xn; R20122 STOT RE 1; H372 Xi; R38-R41 Acute Tox. 4; R42/43 H332 N; R50-R53 Acute Tox. 4; H302 3 / 2 6 - EN Iota E Skin Irrit. 2; H315 Eye Dam. 1; H318 Resp. Sens. 1; H334 Skin Sens. 1; H317 Aquatic Acute 1; H400 Aquatic Chronic use. 1; H410 other WEL substance only. any : for Manganese 1871 8-07-5 Not a hazard- >= 2.5 - < 10 bis(dihydrogen phos- 242-520-2 purposes required ous substance inspection Regulation (EC) phate) or mixture ac- owner cording to copyright For No. 127212008. For the full text of the R-phrases mentioned in this Section, see Section 16. of For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the Notas mentioned Consent in this Section, see Section 16. 1. First aid measures ..1 Description of first aid measures 0 General advice Take off contaminated clothing and shoes immediately. First-aid crew: Ensure self-protection. Move out of dangerous area. If inhaled Move to fresh air. If symptoms persist, call a physician. In case of skin contact : Wash off immediately with plenty of water for at least 15 min- Utes. Call a physician immediately. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately. 4 / 2 6 I-^-- - Eh If swallowed Rinse mouth with water. Immediately give large quantities of water to drink. Do NOT induce vomiting. Call a physician immediately. ..2 Most important symptoms and effects, both acute and delayed Symptoms : Erythema Blistering Pain Risks : corrosive effects 0 ..3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. For specialist advice physicians should contact the Poisons Information Service. use. other only. any i. Fire-fighting measures for i.1 Extinguishing media purposes required Suitable extinguishing media : Use extinguishing owner measures that are appropriate to local cir- cumstances inspection and the surrounding environment. For Unsuitable extinguishing : High copyright volume water jet media of Specific hazards during fire Consent : Combustion may cause: i.2 Special hazards arising from the substance or mixture fighting nitrogen oxides (NOx) 0 Special protective equipment : In the event of fire, wear self-contained breathing apparatus. i.3 Advice for firefighters for fire-fighters Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 5. Accidental release measures ;.I Personal precautions, protective equipment and emergency procedures Personal precautions : Wear personal protective equipment. 5.2 Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. 5126 - Eh Avoid subsoil penetration. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Ensure adequate ventilation. Soak up with liquid binder (sand, kieselguhr, acid binder, uni- versal binder). Sweep up and shovel into suitable containers for disposal. 6.4 Reference to other sections See chapter 8 and 13 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. use. Have eye wash bottle or eye other rinse ready at the work place. Avoid contact with skin any only. and eyes. Do not breathe vapours, for aerosols. Advice on protection against : Normal measures purposes required for preventive fire protection. 7.2 Conditions for safe storage, including any incompatibilities fire and explosion inspection owner Requirements for storage : Store For at room temperature in the original container. areas and containers Keep of copyright container tightly closed in a dry and well-ventilated Further information on stor- Consent place. : Avoid contact with metals. age conditions 7.3 Specific end uses Specific use(s) : Phosphating solution for metal surfaces 0 8. Exposure controlslpersonal protection 8.1 Control parameters Components CAS-No. Value Control pa- Update Basis rameters Orthophos- 7664-38-2 TWA 1 mg/m3 2000-06-1 6 2000/39/EC phoric acid Further informa- Indicative tron STEL 2mglm3 2000-06-1 6 2000/39/EC 6 / 2 6 - El Further informa- : Indicative tion TWA 1 rng/rn3 2005-04-06 GB EH40 STEL 2rng/rn3 2005-04-06 GB EH40 Manganese 1871 8-07- TWA 0.5 rnglrn3 As 2006-09-01 GB EH40 bis(dihydroge 5 Mn 0 n phosphate) Further informa- : 2: Where no specific short-term exposure limit is listed, a figure three times the long-term expo- tion sure should be used As Mn use. 9 Nickel(l1) 1 for nitrate Nickel other only. any Further informa- : 68: Substances that can cause occupational asthma (also known as asthmagens and respira- tion tory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunologi- purposes cal, irritant or other mechanisms. Once required the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symp- toms. These symptoms can range owner in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser inspection will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. . Substances that can cause occu- For pational asthma are classified under the "Chemicals (Hazard information and Packaging for copyright of Consent 0 7 / 2 6 - Eh Nickel DNEL/DMEL Zinc bis (dihydrogen phos- : End Use: DNEL, Workers phate) Exposure routes: Skin contact Potential health effects: Chronic effects, Local effects 8.3 mg/kg The result refers to Zn - ion. End Use: DNEL, Workers Exposure routes: Ingestion 0 Potential health effects: Chronic effects, Local effects 0.83 mgkg The result refers to Zn - ion. use. PNEC other Zinc bis (dihydrogen phos- : Fresh water only. any phate) Value: 20.6 mg/l for required The result refers to Zn - ion. purposes Value: 6.1 owner inspection mg/l Marine water Fresh water sediment copyright The result refers to Zn - ion. For of Consent Value: 117.8 mglkg The result refers to Zn - ion. Marine sediment Value: 56.5 mgkg The result refers to Zn - ion. Behaviour in waste water treatment plants Value: 0.052 mg/l The result refers to Zn - ion. 1.2 Exposure controls Engineering measures Ensure adequate ventilation, especially in confined areas. Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Recommended Filter type: NO-P3 Hand protection : Neoprene 8 I 2 6 - Eh Protective gloves complying with EN 374. The exact break through time can be obtained from the pro- tective glove producer and this has to be observed. Protective gloves have to be replaced at the first sign of dete- rioration. Eye protection Tightly fitting safety goggles Eye protection (EN 166) Skin and body protecti n Chemical resistant protective clothing according to DIN EN 13034 (Type 6) 0 Take off contaminated clothing and shoes immediately. Hygiene measures Do not breathe spray, vapour. Avoid contact with skin and eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and use. immediately after handling the product. other Protective measures Handle in accordance only. with good industrial hygiene and safety any practice. for Facilities storing or utilizing this material should be equipped purposes with an eyewash required facility and safety shower. Environmental exposure controls inspection owner Avoid subsoil penetration. copyright General advice Do For not flush into surface water or sanitary sewer system. of Consent j. Physical and chemical properties ).I Information on basic physical and chemical properties 0 Appearance : liquid Colour : green Odour : odourless Flash point : not applicable Lower explosion limit : no explosion risk Autoignition temperature : not auto-flammable PH : < 2 at 20 "C (undiluted) 9 / 2 6 - Eh Solidification tempera- : <O"C turehange Boiling point/boiling range : no data available Vapour pressure : no data available Density : 1.39 - 1.43 g/cm3 at 20 "C Method: DIN 51 757 0 Water solubility : completely miscible use. other Flow time : c a . 1 5 ~ only. any at 23 "C for 4 mm purposes Method: IS0 2431 required inspection owner copyright 1.2 Other information For Corrosion : Corrosive of to metals Explosivity Consent : no explosion risk 0.1 Reactivity IO. Stability and reactivity 0 No decomposition if stored and applied as directed. 0.2 Chemical stability Stable under recommended storage conditions. 0.3 Possibility of hazardous reactions Hazardous reactions : Gives off hydrogen by reaction with metals. 0.4 Conditions to avoid Conditions to avoid : To avoid thermal decomposition, do not overheat. 10.5 Incompatible materials Materials to avoid : Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic). - EF Incompatible with bases. 0.6 Hazardous decomposition products Risk of decomposition. : nitrogen oxides (NOx) 1. Toxicological information 1.1 Information on toxicological effects Acute toxicity 0 Acute oral toxicity : no data available use. Acute oral toxicity other Zinc bis (dihydrogen phos- phate) : Species: rat LD50: > 300 - 2,000 mg/kg only. any Method: OECD Test Guideline 423 for required GLP: yes purposes Species: rat inspection owner Orthophosphoric acid : LD50: 1,530 mg/kg Method: copyright Converted acute toxicity point estimate Nickel(l1) nitrate : Acute toxicity estimate: 500 mg/kg For of Acute inhalation toxicity Consent Orthophosphoric acid : LC50: 100 - 1,000 mg/l Exposure time: 96 h 0 Species: rat Acute dermal toxicity Zinc bis (dihydrogen phos- LD50: > 2,000 mg/kg phate) Species: rat Method: OECD Test Guideline 402 GLP: yes Test substance: Similar substance Orthophosphoric acid : LD50: 2,740 mg/kg Species: rabbit Skin corrosionlirritation Skin irritation : Causes burns. Serious eye damageleye irritation 11 /26 - Er\ Eye irritation : Causes burns. Respiratory or skin sensitization Sensitisation May cause sensitization by inhalation and skin contact. Germ cell mutagenicity Zinc bis (dihydrogen phos- Ames test phate) Result: negative Method: Mutagenicity (Escherichia coli - reverse mutation assay) GLP: yes use. Human experience If swallowed, severe burns in the oral cavity and throat as well as danger of perforation other of the digestive tract and stom- ach. only. any for Target Organ Systemic Toxicant - Repeated purposes exposure required Zinc bis (dihydrogen phos- : Species: rat owner phate) Application Route: Oral inspection Exposure time: (90 d) For NOAEL: copyright 53.5 mg/kg Method: of OECD Test Guideline 408 GLP: yes Consent The result refers to Zn - ion. Further information : May cause cancer by inhalation. May cause harm to the unborn child. Possible risk of irreversible effects. Also toxic: danger of serious damage to health by prolonged 0 exposure through inhalation. 12. Ecological information 12.1 Toxicity Toxicity to fish : no data available Toxicity to fish Zinc bis (dihydrogen phos- : flow-through test NOEC: 0.199 mg/l phate) Exposure time: 30 d Species: Oncorhynchus mykiss (rainbow trout) Test substance: Similar substance 12/26 - - EF Method: OECD Test Guideline 21 5 GLP: yes Toxicity to daphnia and other aquatic invertebrates. Zinc bis (dihydrogen phos- : Immobilization EC50: 9.04 mg/l phate) Exposure time: 48 h Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202 GLP: yes Immobilization NOEC: 3.13 mg/l 0 Species: Daphnia magna (Water flea) Exposure time: 48 h Method: OECD Test Guideline 202 GLP: yes use. Toxicity to algae other Zinc bis (dihydrogen phos- : Growth inhibition ErC50: only. 0.37 mgll any phate) Exposure time: 72 h for Method: OECD required Test Guideline 201 Species: Pseudokirchneriella subcapitata (green algae purposes inspection owner GLP: yes Growth inhibition LOEC: 0.32 mg/l For Exposure time: 72 h copyright Species: of Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201 Consent GLP: yes Growth inhibition NOEC: 0.18 mg/l Exposure time: 72 h 0 Method: OECD Test Guideline 201 Species: Pseudokirchneriella subcapitata (green algae) GLP: yes Nickel(l1) nitrate : M-Factor: 12.2 Persistence and degradability Biodegradability : no data available 12.3 Bioaccumulative potential Bioaccumulation no data available 12.4 Mobility in soil 13 / 26 - Eh Mobility : no data available 2.5 Results of PBT and VPVB assessment no data available 2.6 Other adverse effects Additional ecological informa- : highly water endangering tion : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Even leakage of small amounts in the subsoil can contaminate drinking water. Toxic to aquatic organisms, may cause long-term adverse 0 effects in the aquatic environment. use. 13. Disposal considerations other only. any 13.1 Waste treatment methods for Product : Dispose of as hazardous waste in compliance with local and purposes national regulations. required Contaminated packaging : Dispose of owner inspection as hazardous waste in compliance with local and Waste Code : Waste copyright codes should be assigned by the user, preferably in national regulations. For of Consent discussion with the waste disposal authorities. 14. Transport information ADR 0 UN number : 3264 UN proper shipping name : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- phosphoric acid, Nickel(l1) nitrate Transport hazard class(es) : 8 Packing group : Ill Classification Code : c 1 Hazard identification No : 80 Packing instruction (LQ) : LQ19 Labels : 8 Tunnel restriction code : (E), Environmentally hazardous : yes IATA UN number : 3264 Description of the goods : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- 14 I 2 6 --- - E\ phosphoric acid Class : 8 Packing group : Ill Labels : 8 Packing instruction (cargo : 820 aircraft) IATA-C Environmentally hazardous no Packing instruction (passen- : 818 ger aircraft) 0 Environmentally hazardous : no IATA-P IMDG UN number : 3264 use. Description of the goods : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- other phosphoric acid, Nickel dinitrate any Class : 8 only. for Packing group : Ill Labels : 8 purposes Ems Number 1 : F-A required Ems Number 2 : S-B owner Marine pollutant : no inspection For RID copyright UN number : 3264 of Description of the goods : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- Consent phosphoric acid , Nickel(l1) nitrate Transport hazard class(es) : 8 Packing group : Ill Classification Code : c1 0 Labels : 8 Hazard identification No : 80 Packing instruction (LQ) : LQ19 Environmentally hazardous : yes 5. Regulatory information 5.1 Safety, health and environmental regulationsllegislation specific for the substance or mixture Water contaminating class : WGK 3 highly water endangering (Germany) WVWVS A4 Other regulations German regulation: Soluble nickel salts are carcinogenic sub- stances, category 1. 15/26 - Eh : The product is classified and labelled in accordance with EC directives or respective national laws. Regional or national implementations of GHS may not imple- ment all hazard classes and categories. 5.2 Chemical Safety Assessment A Chemical Safety Assessment has been carried out for one or more substances in this product. 6. Other information 0 Full text of R-phrases referred to under sections 2 and 3 R 8 Contact with combustible material may cause fire. R20122 Harmful by inhalation and if swallowed. R22 Harmful if swallowed. use. R34 Causes burns. other R38 R4 1 Irritating to skin. Risk of serious damage to eyes. only. any R42143 May cause sensitization by inhalation and skin contact. for R48123 Toxic: danger of serious damage to health by prolonged exposure purposes through inhalation. required R50 Very toxic to aquatic organisms. inspection owner R49 May cause cancer by inhalation. R51 153 Toxic to aquatic organisms, may cause long-term adverse effects in the For aquatic environment. copyright R53 May cause of long-term adverse effects in the aquatic environment. R61 May cause harm to the unborn child. R68 Possible risk of irreversible effects. Consent Full text of H-Statements referred to under sections 2 and 3. H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. 0 H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if in- haled. H341 Suspected of causing genetic defects. H350i May cause cancer by inhalation. H360D May damage the unborn child. H372 Causes damage to organs through prolonged or repeated exposure if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Full text of Notas referred to under section 3 16 I 2 6 - Er Nota B Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solu- tions require different labelling since the hazards vary at different con- centrations. In Annex I entries with Note B have a general designation of the following type: nitric acid .... %. In this case the manufacturer or any other person who markets such a substance in aqueous solution must state the percentage concentration of the solution on the label. Example: nitric acid 45 %. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis. The use of additional data (e.g. specific gravity, degrees Baume) or descriptive phrases (e.g. fuming or glacial) is permissible. Nota E 0 Substances with specific effects on human health (see Chapter 4 of reproduction in categories 1 or 2 are ascribed Note E if they are also Annex VI) that are classified as carcinogenic, mutagenic and/or toxic for classified as very toxic (T+), toxic (T) or harmful (Xn). For these sub- stances, the risk phrases,R 20, R 21, R 22, R 23, R 24, R 25, R 26, R 27, R 28, R 39, R68 (harmful), R 48 and R 65 and all combinations of use. these risk phrases shall be preceded by the word "Also". Examples: R other 45-23 "May cause cancer. Also toxic by inhalation". R 46-27/28 "May any cause heritable genetic damage. only. Also very toxic in contact with skin and for purposes required if swallowed". The information provided is based on our current knowledge and experience and apply to the product inspection Further information owner datasheet does not free the recipient of the product from his own responsibility to follow the relevant copyright as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety For rules and regulations concerning this product. of Consent 0 17 I 2 6 - EN . Short title of Exposure Scenario: GES Zn(H2P04)2 andlor Zn(N03)2-7 : Industrial and pro- essional use of surface treatment products containing Zn(H2P04)2 and/or Zn(NO3)P Main User Groups SU 3: Industrial uses: Uses of substances as such or in prepa- rations at industrial sites 'roduct Category PC1 4: Metal surface treatment products, including galvanic and electroplating products 3rocess category PROC: 2 Use in closed, continuous process with occasional controlled exposure PROC: 3 Use in closed batch process (synthesis or formula- 0 tion) PROC: 4 Use in batch and other process (syn-thesis) where opportunity for exposure arises use. PROC: 8a Transfer of substance or preparation (charg- other PROC: 7 Industrial spraying ingldischarging) only. from/to vesselsllarge containers at non- any dedicated facilities for ing/discharging) purposes required from/to vessels/large containers at dedicated PROC: 8b Transfer of substance or preparation (charg- PROC: owner inspection 9 Transfer of substance or preparation into small con- facilities PROC: 13 Treatment of articles by dipping and pouring copyright tainers (dedicated filling line, including weighing) For PROC: 10 Roller application or brushing of Consent PROC: 24 High (mechanical) energy work-up of substances PROC: 23 Open processing and transfer operations with min- erals/metals at elevated temperature bound in materials and/or articles Environmental Release Category ERC4: Industrial use of processing aids in processes and 0 products, not becoming part of articles Activity Use at workplace !.l Contributing scenario controlling environmental exposure for: ERC4: Industrial use of wocessing aids in processes and products, not becoming part of articles 'roduct characteristics Concentration of the Substance in : Information on the concentration may be found in chapter 3 of MixturelArticle the MSDS. imount used Amount of substance in the prod- : 100,000 kg uct per year. Amount of the substance which : 400,000 kg . 18/26 - Eh may be safely used within the lim- its of the exposure scenario. (Msafe) 3wironment factors not influenced by risk management Flow rate : 18,000 m3/d Dilution Factor (River) : 10 Remarks : Calculated worst case river - this may be adapted using scal- ing criteria to the local receiving environment. Xher given operational conditions affecting environmental exposure 0 Number of emission days per year : 365 Emission to aqueous environment. Emission or Release Factor: Air : 0 O/O Emission or Release Factor: Water : 100 % Emission or Release Factor: Soil : 0 % use. Remarks : All process and non-process waters should be recycled inter- other produced, some only. non-process water containing zinc can be for nally as much as possible. Even when no process waters are any formed in a required contained area. All residues containing zinc are generated (e.g. from cleaning). In industrial and professional settings, all processes are per- purposes inspection recycled, or treated as hazardous wastes. owner For :onditions and measures related to municipal sewage treatment plant copyright Type of Sewage Treatment Plant : of Chemical precipitation and public sewage-treatment plant. Flow rate of sewage treatment : 2,000 m3/d plant effluent Consent Effectiveness (of a measure) : 99.8 Yo Percentage removed from waste : 99.8 YO eater Sludge Treatment : Use sludge treatment techniques for disposal or recovery. 0 Procedures to limit air emissions : Not relevant from Sewage Treatment Plant :onditions and measures related to external treatment of waste for disposal Waste treatment : All contaminated waste water must be processed in an indus- trial or municipal wastewater treatment plant that incorporates both primary and secondary treatments. Disposal methods : Can be landfilled after chemical and physical treatment, when in compliance with local regulations. (Effectiveness: 99 %) !.2 Contributing scenario controlling worker exposure for: PROC: 2 Use in closed, continu- )us process with occasional controlled exposure 'ROC: 3 Use in closed batch process (synthesis or formulation) 'ROC: 4 Use in batch and other process (synthesis) where opportunity for exposure arises 'ROC: 8a Transfer of substance or preparation (charging/discharging) fromlto vessels/large :ontainers at non-dedicated facilities - Eh 'ROC: 8b Transfer of substance or preparation (chargingldischarging) from/to vesseldlarge ontainers at dedicated facilities 'ROC: 9 Transfer of substance or preparation into small containers (dedicated filling line, in- luding weighing) 'ROC: 10 Roller application or brushing 'ROC: 13 Treatment of articles by dipping and pouring 'ROC: 23 Open processing and transfer operations with mineralshetals at elevated tempera- Jre 'ROC: 24 High (mechanical) energy work-up of substances bound in materials and/or articles ctivity : Use at workplace a 'roduct characteristics Concentration of the Substance in Information on the concentration may be found in chapter 3 of use. Mixture/Article the MSDS. other only. for Physical Form (at time of use) : Liquid mixture any imou n t used required Used amount per day : 50 kg purposes Amount of the substance which : 50,000 kg owner may be safely used within the lim- inspection its of the exposure scenario. For 'requency and duration of use copyright Frequency of use : of 8 hourslday luman factors not influenced by risk management Consent Exposed skin area : Uncovered body parts: (potentially) face Hher operational conditions affecting workers exposure Outdoor / Indoor : Indoor Remarks : Room temperature, room size and air exchange rate are not 0 relevant for this exposure scenario. 'echnical conditions and measures In industrial and professional settings the following applies: Process enclosures where relevant and possible local exhaust ventilation on furnaces and other work areas with potential dust generation. Dust capturing and removal techniques are applied. Containment of liquid volumes in sumps to collectlprevent accidental spillage. Irganisational measures to prevent /limit releases, dispersion and exposure In general, emissions are controlled and prevented by implementing an appropriate management sys- tem. This would involve: informing and training workers, regular cleaning of equipment and floors, procedures for process control and maintenance, treatment and monitoring of releases to outside air and exhaust gas streams, according to national regulations. SEVESO 2 compliance, if applicable. 20 I 2 6 - Eh :onditions and measures related to personal protection, hygiene and health evaluation For personal protection see section 8. 1.3 Contributing scenario controlling worker exposure for: PROC7: Industrial spraying ictivity : Spraying 'roduct characteristics Concentration of the Substance in Information on the concentration may be found in chapter 3 of Mixture/Article the MSDS. Physical Form (at time of use) : Liquid mixture Process Temperature : 25°C use. Remarks : During use, aerosols are formed. other imount used only. any Used amount per day : 1,500 kg for Amount of the substance which : M-Safe has required purposes not been derived. its of the exposure scenario. inspection owner may be safely used within the lim- kequency and duration of use For Workers : copyright 620 min Frequency of use : of 5days/week iuman factors not influenced by ris.. management Consent Exposed skin area : Uncovered body parts: (potentially) face : 0.3 mg/d Ither operational conditions affecting workers exposure Outdoor / Indoor : Indoor Temperature : 25°C Ventilation rate per hour : 10 Remarks : Engineering controls, e.g. exhaust ventilation, general ventila- tion; specify effectiveness of measure Industrial /professional: Local exhaust ventilation systems and process enclosures are generally applied Cyclones/filters (for minimizing dust emissions): efficiency 70%-90% (cyclones); dust filters (50-80%) LEV in work area: efficiency 84% (generic LEV) Dermal exposure, Inhalation exposure 'echnical conditions and measures In industrial and professional settings the following applies: 21 /26 - Et' Process enclosures where relevant and possible local exhaust ventilation on furnaces and other work areas with potential dust generation. Dust capturing and removal techniques are applied. Containment of liquid volumes in sumps to collect/prevent accidental spillage. Irganisational measures to prevent /limit releases, dispersion and exposure In general, emissions are controlled and prevented by implementing an appropriate management sys- tem. This would involve: informing and training workers, regular cleaning of equipment and floors, procedures for process control and maintenance, treatment and monitoring of releases to outside air and exhaust gas streams, according to national regulations. SEVESO 2 compliance, if applicable. Zonditions and measures related to personal protection, hygiene and health evaluation For personal protection see section 8. (Effectiveness: > 75 YO) use. Exposure estimation and reference to its source other only. any Invironment for Contributing Exposure Specific conditions required purposes Com- Type: Level of Risk Scenario Assessment part- Exposure charac- Method inspection owner ment terisa- For tion copyright ratio of (PEC/P r NEC): ~ ERC5 ~ Ecetoc TRA Standard Consent parameters where used ~ (ater TPEC 5.lpg/L 1 0.25 Contributing Exposure Specific conditions Type: Level of Risk Scenario Assessment Exposure c h a rac- 0 Method terisa- tion ratio (PECIP NEC): 2.2 MEASE MEASE parameters were set as follows: Total systemic < 0.4 mgld < 0.04 aqueous solution; Content in preparation: exposure 525%; Process category (PROC): as indicated; Process T: 25°C; Scale of (mg/d) operation: professional; Duration of expo- sure: >240 minutes; Pattern of use: wide dispersive; Patter of exposure control: direct handling; Contact level: extensive; Implemented RMMs: LEVgeneric (in- door); no RMM (outdoor);Efficiency based on: median estimate; No RPE, unless indicated otherwise; Use of gloves: prop- erly designed 22 I 2 6 - El 2.3 MEASE MEASE parameters were set as follows: Total systemic aqueous solution; Content in preparation: exposure 5-25%; Process category (PROC): as indicated; Process T: 25°C; Scale of (mgW operation: professional; Duration of expo- sure: >240 minutes; Pattern of use: wide dispersive; Patter of exposure control: direct handling; Contact level: extensive; Implemented RMMs: LEV generic (in- door); no RMM (outdoor);Efkiency based on: median estimate; No RPE, unless indicated otherwise; Use of gloves: prop- erly designed ERC5: Industrial use resulting in inclusion into or onto a matrix Uses with a risk characterisation ratio (RCR) 1 are considered to be use. safe uses. other only. any 4. Guidance to Downstream User to evaluate whether for he works inside the boundaries purposes required set by the Exposure Scenario If your uses are within the limits of the provided exposure scenario, you may use scaling options to adapt inspection owner copyright the exposure scenario to your local conditions. For For further information on safe use, ask our of technical specialists. Consent - E . Short title of Exposure Scenario: GES Zn(H2P04)2 andlor Zn(N03)2-7 : Industrial and pro- essional use of surface treatment products containing Zn(H2P04)Z and/or Zn(N03)2 Main User Groups : SU 3: Industrial uses: Uses of substances as such or in prepa- rations at industrial sites Environmental Release Category : ERC5: Industrial use resulting in inclusion into or onto a matrix Activity : Corrosion inhibitors !.I Contributing scenario controlling environmental exposure for: ERC4: Industrial use of 0 wocessing aids in processes and products, not becoming part of articles use. Concentration of the Substance in : Information on the concentration may be found in chapter 3 of 'roduct characteristics other MixturelArticle the MSDS. only. any for Amount of substance in the prod- : 200,000 kg required purposes imount used uct per year. Amount of the substance which : 200,000 owner inspection kg may be safely used within the lim- For its of the exposure scenario. copyright (Msafe) of kvironment factors not influenced by risk management Consent Flow rate : 18,000 m3ld Dilution Factor (River) : 10 Remarks : Calculated worst case river - this may be adapted using scal- ing criteria to the local receiving environment. 0 Ither given operational conditions affecting environmental exposure Emission to aqueous environment. Number of emission days per year : 350 Emission or Release Factor: Air : 0 % Emission or Release Factor: Water : 100 YO Emission or Release Factor: Soil : 0 YO Remarks : All process and non-process waters should be recycled inter- nally as much as possible. Even when no process waters are produced, some non-process water containing zinc can be generated (e.g. from cleaning). In industrial and professional settings, all processes are per- formed in a contained area. All residues containing zinc are recycled, or treated as hazardous wastes. 24 I 2 6 - EN onditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant : Chemical precipitation and public sewage-treatment plant. Flow rate of sewage treatment : 2,000 m3/d plant effluent Effectiveness (of a measure) : 99.1 % Percentage removed from waste : 99.1 % eater Sludge Treatment : Use sludge treatment techniques for disposal or recovery. Procedures to limit air emissions : Not relevant from Sewage Treatment Plant onditions and measures related to external treatment of waste for disposal Waste treatment : All contaminated waste water must be processed in an indus- trial or municipal wastewater treatment plant that incorporates both primary and secondary treatments. Disposal methods : Dispose of as hazardous waste in compliance with local and national regulations. use. other ~ _ _ _ _ _ _ , Exposure estimation and reference to its source any only. ~ for required I 1 nvironment purposes Sontributing ~~ Exposure Specific conditions Com- Type: Eve1 of Risk Scenario Assessment inspection owner charac- copyright ratio Method For terisa- tion of Consent (PEC/P NEC): E RC5 Chemetall General Input Data : Modifiers; Produc- 0.0006 pre- tion rate: 100 units I h; Average body surface: 100 m2; Production: 22 hours I treatment day; Production: 350 days I year; Con- calculation ductivity in Phosphate tank: 20000 tool pSIcm; Conductivity in final rinse tank: 50 pS/crn; Drag out (standard = 100mUm2): 100 mum’; Number of rinse stages: 3 RC5: Industrial use resulting in inclusion into or onto a matrix kes with a risk characterisation ratio (RCR) < 1 are considered to be safe uses. . Guidance to Downstream User to evaluate whether he works inside the boundaries et by the Exposure Scenario ‘ou may get the Chemetall pretreatment uses calculation tool on our homepage, 25 / 26 M - El from your technical contact to assess your local installation. 0 use. other only. any for purposes required inspection owner copyright For of Consent 0 26 I 2 6 -- - El English Product information Commercial Product Name Gardobond R 2604E Recommended use: Phosphating solution for metal surfaces. Company: Chemetall plc Denbigh Road Bletchley Milton Keynes MK 1 PB 0 Contact person: Lead Organisation: Telephone: 01908649333 Telefax: 01908373939 use. Product safety: other E-mail address: ukinfo@chemetall.com only. for Telephone: +44(0)1908 649333 any Emergency telephone: 01 908 649333 purposes required I. HAZARDS IDENTIFICATION inspection owner ~ For Risk advice to man and the environment of copyright Carcinogenic Category 1 Consent R49 May cause cancer by inhalation. Classification: toxic R48/23 Toxic: danger of serious damage to health by 0 prolonged exposure through inhalation. Toxic to Reproduction R61 May cause harm to the unborn child. , Category 2 Corrosive

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage. referred to under sections owner 2 and 3 R22 Harmful if swallowed. For R35 Causes severe copyright burns. R37 Irritating to of respiratory system. R40 Limited evidence of a carcinogenic effect. R4 1 Risk Consent of serious damage to eyes. R43 May cause sensitization by skin contact. referred to under sections 2 and 3 0 H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H351 Suspected of causing cancer. Full text of Notas referred to under section 3 12 I 1 3 - EF Nota B Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solu- tions require different labelling since the hazards vary at different con- centrations. In Annex I entries with Note B have a general designation of the following type: nitric acid .... %. In this case the manufacturer or any other person who markets such a substance in aqueous solution must state the percentage concentration of the solution on the label. Example: nitric acid 45 %. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weighvweight basis. The use of additional data (e.g. specific gravity, degrees Baume) or descriptive phrases (e.g. fuming or glacial) is permissible.

Prevention

P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves1 protective clothing1 eye protection1 face protection.

Response

0 P301 + P330 + P331 P303 + P361 + P353 IF SWALLOWED: rinse mouth. Do IF ON SKIN (or hair): Remove/ Take NOT induce vomiting. off immediately all contaminated clothing. Rinse skin with water1 shower. P305 + P35 + P338 IF IN EYES: use. Rinse cautiously with wa- ter for several minutes. Remove contact other lenses, if present and easy to do. Continue any rinsing. only. for P312 Call a POISON CENTER or doctor1 physi- purposes cian if you feel unwell.

Disposal

required inspection owner proved waste disposal plant. P501 Dispose of contents1 container to an ap- copyright For of

Hazardous Ingredients

7664-93-9 Sulphuric acid Consent 7664-93-9 Sulphuric acid 0 13138-45-9 Nickel(l1) nitrate

Additional information

EUH208 Contains: DiethylthioureaMay produce an allergic reaction. 0 Labelling according to EC Directives (1999/45/EC)

Hazard pictograms

Corrosive R-phrase( s) R35 Causes severe burns. Toxic Dangerous 0 for the envi- ronment R-phrase( s) R49 May cause cancer by inhalation. R61 May cause harm to the unborn child. R48/23 Also toxic: use. danger of serious damage to health by prolonged exposure through in- other R34 only. halation. Causes burns. any R68 Possible risk of irreversible effects. for required skin contact. R42/43 purposes May cause sensitization by inhalation and inspection owner long-term adverse effects in the aquatic R51/53 Toxic to aquatic organisms, may cause copyright Avoid exposure - obtain special instruc- For environment. S-phrase( s) s53 of tions before use. Consent S23 Do not breathe spray. s24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immedi- ately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves 0 and eyelface protection. s45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets.

S-phrase(s)

s24125 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immedi- ately with plenty of water and seek medical advice. S30 Never add water to this product. S36137139 Wear suitable protective clothing, gloves and eyelface protection. - 2 I 1 3 - EF s45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste.

Special rules for supplemental label elements for certain mixtures

Ingredients according to Regulation (EC) No.648/2004 on detergents: Sensitising components Diethylthiourea 0 May produce an allergic reaction. use. Restricted to professional users. Ingredients according to Regulation (EC) No.648/2004 on detergents: Amphoteric surfactants, 5 % Non ionic surfactants 5% EDTA, 5 % Zardoclean S 5174 fersion: 2 18.07.2008 Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. ~ ~~ ~

2.3 Other hazards

other The information required is contained in this Material Safety only. Data Sheet. any for 1. Compositionlinformation on ingredients purposes required inspection 1.1 Substances owner Identification: Gardacid P 4309 For 1.2 Mixtures copyright Chemical nature Aqueous solution of Consent inorganic acids Hazardous components Chemical Name 2 / 2 6 -- - El The information required is contained in this Material Safety Data Sheet. 3. Compositionlinformation on ingredients 3.1 Substances Identification: Gardobond R 2600 A 3.2 Mixtures Chemical nature Aqueous solution of inorganic salts. Hazardous components 0 EC-NO. (67/548/E EC) (REGULATION ["/I Chemical Name CAS-NO. Classification Concentration Registration num- EC) No ber

Classifications

Concentration EC-NO.

67/548/EEC

REG U LATl ON [%I Registration num- (EC) No 0 ber I Sulphuric acid 7664-93-9 I C: R35 >= 65 - < 80 231 -639-5 H314 Nota B Diethylthiourea 105-55-5 Xn; Carc.Cat.3; Care. 2; H351 >= 0.1 - < 1 ~ 203-308-5 R40 Acute Tox. 4; Xn; R22 H302 Xi; R37-R41 STOT SE 3; H335 R43 Eye Dam. 1; H318 .--- 3 / 1 3 - EN Skin Sens. 1; H317 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the Notas mentioned in this Section, see Section 16. 1. First aid measures 1.1 Description of first aid measures General advice Take off contaminated clothing and shoes immediately. First-aid crew: Ensure self-protection. Move out of dangerous area. use. If inhaled Move to fresh air. other If symptoms persist, call any only. a physician. for In case of skin contact Wash off immediately with plenty of water for at least 15 min- Utes. purposes required Rinse inspection owner Call a physician immediately. In case of eye contact immediately with plenty of water, also under the eyelids, for For copyright at least 15 minutes. Call a physician immediately. of Consent Immediately give large quantities of water to drink. If swallowed Rinse mouth with water. Do NOT induce vomiting. Call a physician immediately. 1.2 Most important symptoms and effects, both acute and delayed Symptoms Erythema Blistering Pain Risks corrosive effects 1.3 Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. For specialist advice physicians should contact the Poisons Information Service. 5. Fire-fighting measures 5.1 Extinguishing media 4 1 13 - Et’ Suitable extinguishing media Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Unsuitable extinguishing High volume water jet media 2 Special hazards arising from the substance or mixture Specific hazards during fire May form toxic gases on heating or in case of fire. fighting 3 Advice for firefighters Special protective equipment In the event of fire, wear self-contained breathing apparatus. for fire-fighters 19991451EC) Carcinogenic Category 1 R49: May cause cancer by inhalation. toxic R48/23 Toxic danger of serious damage to health by prolonged exposure through inhalation. Toxic to Reproduction Category 2 R61: May cause harm to the unborn child. Corrosive R34: Causes burns. Mutagenic Category 3 R68: Possible risk of irreversible effects. Sensitising R42/43: May cause sensitization by inhalation and skin contact. Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environ- 1 I 2 6 - Eh ment.

Further information

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 0 Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. use. other , Accidental release measures for only. any required 1 Personal precautions, protective equipment and emergency procedures purposes Personal precautions Ensure adequate ventilation. Wear personal owner protective equipment. Evacuate inspection personnel to safe areas. For 2 Environmental precautions copyright of Environmental precautions Do not flush into surface water or sanitary sewer system. Consent Avoid subsoil penetration. 3 Methods and materials for containment and cleaning up versal binder). Methods for cleaning up Ensure adequate ventilation. 0 Soak up with liquid binder (sand, kieselguhr, acid binder, uni- Sweep up and shovel into suitable containers for disposal. 4 Reference to other sections See chapter 8 and 13 Handling and storage 1 Precautions for safe handling Advice on safe handling Provide sufficient air exchange and/or exhaust in work rooms. Have eye wash bottle or eye rinse ready at the work place. Avoid contact with skin and eyes. When diluting, always add the product to water. Never add water to the product. 51 13 - Eh Advice on protection against Normal measures for preventive fire protection. fire and explosion 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage Store at room temperature in the original container. areas and containers Keep container tightly closed in a dry and well-ventilated place. on stor- Avoid contact with metals. age conditions 7.3 Specific end uses Specific use(s) Acid pickling agent for metal surfaces. 8. Exposure controlslpersonal protection use. 8.1 Control parameters other only. any for rameters required Components CAS-No. Value Control pa- purposes Updated: Basis Sulphuric 7664-93-9 TWA 0.05 mgIrn3 owner 2009-12-19 2009/161/EU acid inspection For Further informa- (8): When selecting an appropriate exposure monitoring method, account should be taken of copyright tion potential limitations and interferences that may arise in the presence of other sulphur com- of Consent pounds. Indicative 8.2 Exposure controls Engineering measures Ensure adequate ventilation, especially in confined areas. Personal protective equipment Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Recommended Filter type: B-P2 Hand protection Viton (R) Protective gloves complying with EN 374. The exact break through time can be obtained from the pro- tective glove producer and this has to be observed. Protective gloves have to be replaced at the first sign of dete- rioration. - 6 / 1 3 - EF Eye protection Tightly fitting safety goggles Eye protection (EN 166) Skin and body protection Chemical resistant protective clothing according to DIN EN 13034 (Type 6) Hygiene measures Do not breathe spray. Take off contaminated clothing and shoes immediately. Avoid contact with the skin and the eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and immediately after handling the product . Protective measures Handle in accordance with good industrial hygiene and safety practice. Facilities storing or utilizing this use. material should be equipped with an eyewash facility and safety shower. other Environmental exposure controls only. any for Avoid subsoil purposes penetration. required General advice Do not flush into surface water or sanitary sewer system. inspection owner copyright 1. Physical and chemical properties For .I Information on basic physical and chemical properties of Appearance Consent liquid Colour light yellow to Odour stinging beige 0 Flash point not applicable Ignition temperature not applicable Autoignition temperature not applicable PH < 2 at 20 "C (undiluted) Solidification tempera- <-14°C turehange 7 / 1 3 - Eh Boiling point/boiling range no data available Vapour pressure no data available Density 1.66 - 1.7 gkm3 at 20 "C Method: DIN 51757 Water solubility completely miscible Flow time ca.20 s at 23 "C use. 4 mm other only. Method: IS0 2431 for any purposes required inspection Explosivity no explosion risk owner 10. Stability and reactivity copyright For of 10.1 Reactivity Consent Potential for exothermic hazard, Reacts violently with water. 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions Hazardous reactions Gives off hydrogen by reaction with metals. 10.4 Conditions to avoid Conditions to avoid To avoid thermal decomposition, do not overheat. 10.5 Incompatible materials Materials to avoid When diluting, always add the acid to the water, never the other way round. Incompatible with bases. Organic materials 10.6 Hazardous decomposition products Risk of decomposition. No decomposition if used as directed. 81 13 - El inspection 0 The information provided is based on our current knowledge and experience and apply to the producl as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety use. datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product. other only. any for purposes required inspection owner copyright For of Consent 0 . 13/13 -- - EP ~~ ~ ~~ Text of R phrases mentioned in Section 3 R22 Harmful if swallowed. R35 Causes severe burns. R41 Risk of serious damage to eyes. R50 Very toxic to aquatic organisms. The information provided is based on our current knowledge and experience and apply to the 0 this safety datasheet does not free the recipient of the product from his own responsibility to product as delivered. Regarding the product properties, these are not guaranteed. The delivery of follow the relevant rules and regulations concerning this product. use. other only. any for purposes required inspection owner copyright For of Consent 0 Gardolene V 651 3 Version: 2 24.10.2007 1. IDENTIFICATION OF THE SUBSTANCElPREPARATlON AND OF THE COMPANYlUNDERTAKlNG English Product information Commercial Product Name Gardolene V 651 3 Recommended use Activating rinsing agent for metal surfaces before phosphating. Company: Chemetall plc Denbigh Road 0 Bletchley Milton Keynes MKI 1 PB Lead Organisation: Contact person: use. Telephone: 01908 649333 Telefax: 01908 373939 other only. any Product safety: for Telephone: +49(0)69 7165 2292 E-mail address: msds.de@chemetall.com purposes required I inspection Emergency telephone: 01908 649333 owner copyright For of Consent Risk advice to man and the environment Additional advice: Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 19991451EC. The product does not need to be labelled in accordance with EC directives or 0 respective national laws.

TOXICOLOGICAL INFORMATION

1 .I Information on toxicological effects Acute toxicity Acute oral toxicity LD50: 2,150 mg/kg Species: rat CAS NO. 7664-93-9 Acute oral toxicity Sulphuric acid LD50: 2,140 mg/kg Species: rat use. Diethylthiourea LD50: 316.0 mglkg other only. for Species: rat any Skin irritation Causes severe required purposes burns. Skin corrosionlirritation inspection owner Serious eye damageleye irritation For Eye irritation Causes copyright serious eye damage. of Respiratory or skin sensitization Consent Sensitisation Contains one or more substance(s) classified as sensitising. Human experience If swallowed, severe burns in the oral cavity and throat as well as danger of perforation of the digestive tract and stom- ach.

ECOLOGICAL INFORMATION

2.1 Toxicity Toxicity to fish no data available Toxicity to fish Sulphuric acid LC50: 42 mg/l 9 / 1 3 -!i Exposure time: 96 h Species: Gambusia affinis (Mosquito fish) LC50: 82 mg/l Exposure time: 24 h Species: Danio rerio (zebra fish) 12.2 Persistence and degradability Biodegradability no data available 12.3 Bioaccumulative potential Bioaccumulation no data available use. 12.4 Mobility in soil other only. any Mobility no data available for

Results of PBT and vPvB assessment

purposes required inspection no data available owner Additional ecological informa- slightly water endangering copyright

Other hazards

For of Consent Avoid subsoil penetration. tion Do not flush into surface water or sanitary sewer system. 13. Disposal considerations 13.1 Waste treatment methods Product Dispose of as hazardous waste in compliance with local and national regulations. Contaminated packaging Dispose of as hazardous waste in compliance with local and national regulations. Waste Code Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities. 14. Transport information ADR 10 I 1 3 - Er

UN Number

1830 UN proper shipping name SULPHURIC ACID with more than 51% acid Transport hazard class(es) 8 Packing group II 1830 Description of the goods SULPHURIC ACID with more than 51% acid Class 8 Packing group II Labels 8 use. Packing instruction (cargo 855 other aircraft) only. any IATA-C for required Environmentally hazardous no purposes Packing instruction (passen- 851 owner ger aircraft) inspection IATA-P For Environmentally hazardous no copyright of IMDG Consent 1830 Description of the goods SULPHURIC ACID with more than 51% acid Class 8 Packing group II Labels 8 Ems Number 1 F-A 0 Ems Number 2 S-B Marine pollutant no RID 1830 Description of the goods SULPHURIC ACID with more than 51% acid Transport hazard class(es) 8 Packing group II 3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- phosphoric acid, Nickel(l1) nitrate Transport hazard class(es) Packing group Ill Classification Code c 1 Hazard identification No 80 Packing instruction (LQ) LQ19 Labels Tunnel restriction code E), Environmentally hazardous yes IATA 3264 Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- I 2 6 E\ phosphoric acid Class Packing group Ill Labels Packing instruction (cargo 820 aircraft) IATA-C Environmentally hazardous no Packing instruction (passen- 818 ger aircraft) Environmentally hazardous no IATA-P IMDG 3264 use Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- other phosphoric acid, Nickel dinitrate any Class only for Packing group Ill Labels purposes Ems Number 1 F-A required Ems Number 2 S-B owner Marine pollutant no inspection For RID copyright 3264 of Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Ortho- Consent phosphoric acid , Nickel(l1) nitrate Transport hazard class(es) Packing group Ill Classification Code c1 Labels Hazard identification No 80 Packing instruction (LQ) LQ19 Environmentally hazardous yes Regulatory information Safety, health and environmental regulationsllegislation specific for the substance or mixture Water contaminating class WGK 3 highly water endangering Germany) WVWVS A4 Other regulations German regulation: Soluble nickel salts are carcinogenic sub- stances, category 1 15/26 Eh The product is classified and labelled in accordance with EC directives or respective national laws Regional or national implementations of GHS may not imple- ment all hazard classes and categories Chemical Safety Assessment A Chemical Safety Assessment has been carried out for one or more substances in this product Other information Full text of R-phrases referred to under sections 2 and 3 R 8 Contact with combustible material may cause fire R20122 Harmful by inhalation and if swallowed R22 Harmful if swallowed use R34 Causes burns other R38 R4 1 Irritating to skin Risk of serious damage to eyes only any R42143 May cause sensitization by inhalation and skin contact for R48123 Toxic: danger of serious damage to health by prolonged exposure purposes through inhalation required R50 Very toxic to aquatic organisms inspection owner R49 May cause cancer by inhalation R51 153 Toxic to aquatic organisms, may cause long-term adverse effects in the For aquatic environment copyright R53 May cause of long-term adverse effects in the aquatic environment R61 May cause harm to the unborn child R68 Possible risk of irreversible effects Consent Full text of H-Statements referred to under sections 2 and 3 H272 May intensify fire; oxidiser H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H332 Harmful if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if in- haled H341 Suspected of causing genetic defects H350i May cause cancer by inhalation H360D May damage the unborn child H372 Causes damage to organs through prolonged or repeated exposure if inhaled H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects Full text of Notas referred to under section 3 I 2 6 Er Nota B Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solu- tions require different labelling since the hazards vary at different con- centrations. In Annex I entries with Note B have a general designation of the following type: nitric acid .... %. In this case the manufacturer or any other person who markets such a substance in aqueous solution must state the percentage concentration of the solution on the label Example: nitric acid 45 %. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis The use of additional data (e.g. specific gravity, degrees Baume) or descriptive phrases (e.g. fuming or glacial) is permissible Nota E Substances with specific effects on human health (see Chapter 4 of reproduction in categories 1 or 2 are ascribed Note E if they are also Annex VI) that are classified as carcinogenic, mutagenic and/or toxic for classified as very toxic (T+), toxic (T) or harmful (Xn). For these sub- stances, the risk phrases,R 20, R 21, R 22, R 23, R 24, R 25, R 26, R 27, R 28, R 39, R68 (harmful), R 48 and R 65 and all combinations of use these risk phrases shall be preceded by the word "Also". Examples: R other 45-23 "May cause cancer. Also toxic by inhalation". R 46-27/28 "May any cause heritable genetic damage only. Also very toxic in contact with skin and for purposes required if swallowed" The information provided is based on our current knowledge and experience and apply to the product inspection Further information owner datasheet does not free the recipient of the product from his own responsibility to follow the relevant copyright as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety For rules and regulations concerning this product of Consent I 2 6 EN Short title of Exposure Scenario: GES Zn(H2P04)2 andlor Zn(N03)2-7 Industrial and pro- essional use of surface treatment products containing Zn(H2P04)2 and/or Zn(NO3)P Main User Groups SU 3: Industrial uses: Uses of substances as such or in prepa- rations at industrial sites roduct Category PC1 4: Metal surface treatment products, including galvanic and electroplating products 3rocess category PROC: 2 Use in closed, continuous process with occasional controlled exposure PROC: 3 Use in closed batch process (synthesis or formula- tion) PROC: 4 Use in batch and other process (syn-thesis) where opportunity for exposure arises use PROC: 8a Transfer of substance or preparation (charg- other PROC: 7 Industrial spraying ingldischarging) only from/to vesselsllarge containers at non- any dedicated facilities for ing/discharging) purposes required from/to vessels/large containers at dedicated PROC: 8b Transfer of substance or preparation (charg- PROC: owner inspection Transfer of substance or preparation into small con- facilities PROC: 13 Treatment of articles by dipping and pouring copyright tainers (dedicated filling line, including weighing) For PROC: 10 Roller application or brushing of Consent PROC: 24 High (mechanical) energy work-up of substances PROC: 23 Open processing and transfer operations with min- erals/metals at elevated temperature bound in materials and/or articles Environmental Release Category ERC4: Industrial use of processing aids in processes and products, not becoming part of articles Activity Use at workplace l Contributing scenario controlling environmental exposure for: ERC4: Industrial use of wocessing aids in processes and products, not becoming part of articles roduct characteristics Concentration of the Substance in Information on the concentration may be found in chapter 3 of MixturelArticle the MSDS imount used Amount of substance in the prod- 100,000 kg uct per year Amount of the substance which 400,000 kg 18/26 Eh may be safely used within the lim- its of the exposure scenario Msafe) 3wironment factors not influenced by risk management Flow rate 18,000 m3/d Dilution Factor (River) 10 Remarks Calculated worst case river - this may be adapted using scal- ing criteria to the local receiving environment Xher given operational conditions affecting environmental exposure Number of emission days per year 365 Emission to aqueous environment Emission or Release Factor: Air O/O Emission or Release Factor: Water 100 % Emission or Release Factor: Soil use Remarks All process and non-process waters should be recycled inter- other produced, some only non-process water containing zinc can be for nally as much as possible. Even when no process waters are any formed in a required contained area. All residues containing zinc are generated (e.g. from cleaning) In industrial and professional settings, all processes are per- purposes inspection recycled, or treated as hazardous wastes owner For onditions and measures related to municipal sewage treatment plant copyright Type of Sewage Treatment Plant of Chemical precipitation and public sewage-treatment plant Flow rate of sewage treatment 2,000 m3/d plant effluent Consent Effectiveness (of a measure) 99.8 Yo Percentage removed from waste 99.8 YO eater Sludge Treatment Use sludge treatment techniques for disposal or recovery Procedures to limit air emissions Not relevant from Sewage Treatment Plant onditions and measures related to external treatment of waste for disposal Waste treatment All contaminated waste water must be processed in an indus- trial or municipal wastewater treatment plant that incorporates both primary and secondary treatments Disposal methods Can be landfilled after chemical and physical treatment, when in compliance with local regulations. (Effectiveness: 99 %) Contributing scenario controlling worker exposure for: PROC: 2 Use in closed, continu- us process with occasional controlled exposure ROC: 3 Use in closed batch process (synthesis or formulation) ROC: 4 Use in batch and other process (synthesis) where opportunity for exposure arises ROC: 8a Transfer of substance or preparation (charging/discharging) fromlto vessels/large ontainers at non-dedicated facilities Eh ROC: 8b Transfer of substance or preparation (chargingldischarging) from/to vesseldlarge ontainers at dedicated facilities ROC: 9 Transfer of substance or preparation into small containers (dedicated filling line, in- luding weighing) ROC: 10 Roller application or brushing ROC: 13 Treatment of articles by dipping and pouring ROC: 23 Open processing and transfer operations with mineralshetals at elevated tempera- Jre ROC: 24 High (mechanical) energy work-up of substances bound in materials and/or articles ctivity Use at workplace roduct characteristics Concentration of the Substance in Information on the concentration may be found in chapter 3 of use Mixture/Article the MSDS other only for Physical Form (at time of use) Liquid mixture any imou n t used required Used amount per day 50 kg purposes Amount of the substance which 50,000 kg owner may be safely used within the lim- inspection its of the exposure scenario For requency and duration of use copyright Frequency of use of 8 hourslday luman factors not influenced by risk management Consent Exposed skin area Uncovered body parts: (potentially) face Hher operational conditions affecting workers exposure Outdoor / Indoor Indoor Remarks Room temperature, room size and air exchange rate are not relevant for this exposure scenario echnical conditions and measures In industrial and professional settings the following applies Process enclosures where relevant and possible local exhaust ventilation on furnaces and other work areas with potential dust generation Dust capturing and removal techniques are applied Containment of liquid volumes in sumps to collectlprevent accidental spillage Irganisational measures to prevent /limit releases, dispersion and exposure In general, emissions are controlled and prevented by implementing an appropriate management sys- tem This would involve: informing and training workers, regular cleaning of equipment and floors, procedures for process control and maintenance, treatment and monitoring of releases to outside air and exhaust gas streams, according to national regulations SEVESO 2 compliance, if applicable 20 I 2 6 Eh onditions and measures related to personal protection, hygiene and health evaluation For personal protection see section 8 Contributing scenario controlling worker exposure for: PROC7: Industrial spraying ictivity Spraying roduct characteristics Concentration of the Substance in Information on the concentration may be found in chapter 3 of Mixture/Article the MSDS Physical Form (at time of use) Liquid mixture Process Temperature 25°C use Remarks During use, aerosols are formed other imount used only any Used amount per day 1,500 kg for Amount of the substance which M-Safe has required purposes not been derived its of the exposure scenario inspection owner may be safely used within the lim- kequency and duration of use For Workers copyright 620 min Frequency of use of 5days/week iuman factors not influenced by ris.. management Consent Exposed skin area Uncovered body parts: (potentially) face mg/d Ither operational conditions affecting workers exposure Outdoor / Indoor Indoor Temperature 25°C Ventilation rate per hour 10 Remarks Engineering controls, e.g. exhaust ventilation, general ventila- tion; specify effectiveness of measure Industrial /professional Local exhaust ventilation systems and process enclosures are generally applied Cyclones/filters (for minimizing dust emissions): efficiency 70%-90% (cyclones); dust filters (50-80%) LEV in work area: efficiency 84% (generic LEV) Dermal exposure, Inhalation exposure echnical conditions and measures In industrial and professional settings the following applies 21 /26 Et' Process enclosures where relevant and possible local exhaust ventilation on furnaces and other work areas with potential dust generation Dust capturing and removal techniques are applied Containment of liquid volumes in sumps to collect/prevent accidental spillage Irganisational measures to prevent /limit releases, dispersion and exposure In general, emissions are controlled and prevented by implementing an appropriate management sys- tem This would involve: informing and training workers, regular cleaning of equipment and floors, procedures for process control and maintenance, treatment and monitoring of releases to outside air and exhaust gas streams, according to national regulations SEVESO 2 compliance, if applicable Zonditions and measures related to personal protection, hygiene and health evaluation For personal protection see section 8. (Effectiveness: > 75 YO) use Exposure estimation and reference to its source other only any Invironment for Contributing Exposure Specific conditions required purposes Com- Type Level of Risk Scenario Assessment part- Exposure charac- Method inspection owner ment terisa- For tion copyright ratio of PEC/P NEC) ERC5 Ecetoc TRA Standard Consent parameters where used ater TPEC 5.lpg/L 0.25 Contributing Exposure Specific conditions Type Level of Risk Scenario Assessment Exposure c h a rac- 0 Method terisa- tion ratio PECIP NEC) MEASE MEASE parameters were set as follows Total systemic mgld 0.04 aqueous solution; Content in preparation exposure 525%; Process category (PROC): as indicated; Process T: 25°C; Scale of mg/d) operation: professional; Duration of expo- sure: >240 minutes; Pattern of use: wide dispersive; Patter of exposure control direct handling; Contact level: extensive; Implemented RMMs: LEVgeneric (in- door); no RMM (outdoor);Efficiency based on: median estimate; No RPE, unless indicated otherwise; Use of gloves: prop- erly designed 22 I 2 6 El MEASE MEASE parameters were set as follows Total systemic aqueous solution; Content in preparation exposure 5-25%; Process category (PROC): as indicated; Process T: 25°C; Scale of mgW operation: professional; Duration of expo- sure: >240 minutes; Pattern of use: wide dispersive; Patter of exposure control direct handling; Contact level: extensive; Implemented RMMs: LEV generic (in- door); no RMM (outdoor);Efkiency based on: median estimate; No RPE, unless indicated otherwise; Use of gloves: prop- erly designed ERC5: Industrial use resulting in inclusion into or onto a matrix Uses with a risk characterisation ratio (RCR) are considered to be use safe uses other only any Guidance to Downstream User to evaluate whether for he works inside the boundaries purposes required set by the Exposure Scenario If your uses are within the limits of the provided exposure scenario, you may use scaling options to adapt inspection owner copyright the exposure scenario to your local conditions For For further information on safe use, ask our of technical specialists Consent Short title of Exposure Scenario: GES Zn(H2P04)2 andlor Zn(N03)2-7 Industrial and pro- essional use of surface treatment products containing Zn(H2P04)Z and/or Zn(N03)2 Main User Groups SU 3: Industrial uses: Uses of substances as such or in prepa- rations at industrial sites Environmental Release Category ERC5: Industrial use resulting in inclusion into or onto a matrix Activity Corrosion inhibitors Contributing scenario controlling environmental exposure for: ERC4: Industrial use of wocessing aids in processes and products, not becoming part of articles use Concentration of the Substance in Information on the concentration may be found in chapter 3 of roduct characteristics other MixturelArticle the MSDS only any for Amount of substance in the prod- 200,000 kg required purposes imount used uct per year Amount of the substance which 200,000 owner inspection kg may be safely used within the lim- For its of the exposure scenario copyright Msafe) of kvironment factors not influenced by risk management Consent Flow rate 18,000 m3ld Dilution Factor (River) 10 Remarks Calculated worst case river - this may be adapted using scal- ing criteria to the local receiving environment Ither given operational conditions affecting environmental exposure Emission to aqueous environment Number of emission days per year 350 Emission or Release Factor: Air Emission or Release Factor: Water 100 YO Emission or Release Factor: Soil YO Remarks All process and non-process waters should be recycled inter- nally as much as possible. Even when no process waters are produced, some non-process water containing zinc can be generated (e.g. from cleaning) In industrial and professional settings, all processes are per- formed in a contained area. All residues containing zinc are recycled, or treated as hazardous wastes 24 I 2 6 EN onditions and measures related to municipal sewage treatment plant Type of Sewage Treatment Plant Chemical precipitation and public sewage-treatment plant Flow rate of sewage treatment 2,000 m3/d plant effluent Effectiveness (of a measure) 99.1 % Percentage removed from waste 99.1 % eater Sludge Treatment Use sludge treatment techniques for disposal or recovery Procedures to limit air emissions Not relevant from Sewage Treatment Plant onditions and measures related to external treatment of waste for disposal Waste treatment All contaminated waste water must be processed in an indus- trial or municipal wastewater treatment plant that incorporates both primary and secondary treatments Disposal methods Dispose of as hazardous waste in compliance with local and national regulations use other _ _ _ _ _ _ Exposure estimation and reference to its source any only for required

Product definition

Trade name Gardobond R 2600 A .2 Relevant identified uses of the substance or mixture and uses advised against Use of the Sub- Phosphating solution for metal surfaces. stance/Mixture Recommended restrictions None known. on use 0 .3 Details of the supplier of the safety data sheet Company Chemetall Ltd Denbigh Road use. Bletchley Milton Keynes MKI 1 PB other Lead Organisation only. any Contact person for Telephone 01908 649333 Telefax 01908 373939 purposes required Product safety owner copyright Telephone +49(0)6971652292 inspection E-mail address msds.de@chemetall.com For .4 Emergency telephone number of Emergency telephone Consent 01908 649333 number 0

2.2 Label elements

Labelling according to EC Directives (19991451EC) Consent 1x1 Corrosive R-phrase( s): R22 Harmful if swallowed. 0 R35 Causes severe burns. S-phrase( s): S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. s45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste.

Environmental hazards

purposes Sontributing Exposure Specific conditions Com- Type Eve1 of Risk Scenario Assessment inspection owner charac- copyright ratio Method For terisa- tion of Consent PEC/P NEC) E RC5 Chemetall General Input Data Modifiers; Produc- 0.0006 pre- tion rate: 100 units I h; Average body surface: 100 m2; Production: 22 hours I treatment day; Production: 350 days I year; Con- calculation ductivity in Phosphate tank: 20000 tool pSIcm; Conductivity in final rinse tank: 50 pS/crn; Drag out (standard = 100mUm2) 100 mum’; Number of rinse stages: 3 RC5: Industrial use resulting in inclusion into or onto a matrix kes with a risk characterisation ratio (RCR) < 1 are considered to be safe uses Guidance to Downstream User to evaluate whether he works inside the boundaries et by the Exposure Scenario ou may get the Chemetall pretreatment uses calculation tool on our homepage, 25 / 26 M El from your technical contact to assess your local installation use other only any for purposes required inspection owner copyright For of Consent 26 I 2 6 El English Product information Commercial Product Name Gardobond R 2604E Recommended use Phosphating solution for metal surfaces Company Chemetall plc Denbigh Road Bletchley Milton Keynes MK 1 PB Contact person Lead Organisation Telephone 01908649333 Telefax 01908373939 use Product safety other E-mail address ukinfo@chemetall.com only for Telephone 44(0)1908 649333 any Emergency telephone 01 908 649333 purposes required I. HAZARDS IDENTIFICATION inspection owner For Risk advice to man and the environment of copyright Carcinogenic Category 1 Consent R49 May cause cancer by inhalation Classification toxic R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation Toxic to Reproduction R61 May cause harm to the unborn child Category 2 Corrosive R34 Causes burns Mutagenic Category 3 R68 Possible risk of irreversible effects Sensitising R42143 May cause sensitization by inhalation and skin contact Dangerous for the R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment COMPOSlTlONllNFORMATlON ON INGREDIENTS Hazardous components / 7 3ardobond R 2604E fersion: 3 22.03.2010 Nickelill) nitrate 5.00 - 10.00 YO CAS-NO.: 131 38-45-9 EINECS-NO.: 236-068-5 Classification: 0; R 8 Carc.Cat.1; R49 Repr.Cat.2; R61 Mut.Cat.3; R68 T; R48/23 Xn; R20122 Xi; R38, R41 R42/43 N; R50, R53 Orthophosphoric acid 2.50 - 5.00 YO CAS-NO.: 7664-38-2 EINECS-NO.: 231 -633-2 Classification: C; R34 Manqanese fluoroborate 1 .OO - 2.50 YO CAS-NO.: 30744-82-2 El NECS-NO.: 250-320-1 Classification: C; R34 WEL substance Manqanese biddihvdroqen Dhosphatel 25.00 - 50.00 YO CAS-NO.: 1871 8-07-5 EINECS-NO.: 242-520-2 use other only any FIRST AID MEASURES for Take off contaminated clothing and shoes immediately purposes required First-aid crew: Ensure self-protection General advice Eye contact inspection owner Move out of dangerous area Rinse immediately with plenty of water, For also under the eyelids, for at least 15 minutes. Call a physician immediately copyright Skin contact of Inhalation Consent Wash off immediately with plenty of water for at least 15 minutes. Call a physician immediately Move to fresh air. If symptoms persist, call a physician Ingestion vomiting. Call a physician immediately Rinse mouth with water. Immediately give large quantities of water to drink. Do NOT induce i. FIRE-FIGHTING MEASURES Specific hazards during fire fighting Combustion may cause: nitrogen oxides (NOx) Special protective equipment for fire-fighters In the event of fire, wear self-contained breathing apparatus Suitable extinguishing media Carbon dioxide (C02), Dry powder, Water spray jet, Alcohol-resistant foam Further information Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations i. ACCIDENTAL RELEASE MEASURES Personal precautions Wear personal protective equipment 1 7 3ardobond R 2604E lersion: 3 22.03.2010 Environmental precautions Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration Methods for cleaning up Ensure adequate ventilation. Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up and shovel into suitable containers for disposal HANDLING AND STORAGE Handling Safe handling advice Provide sufficient air exchange and/or exhaust in work rooms. Have eye wash bottle or eye rinse ready at the work place. Avoid contact with skin and eyes Advice on protection against fire and explosion No special protective measures against fire required Storage Requirements for storage areas and containers use Store at room temperature in the original container. Keep container tightly closed in a dry and other well-ventilated place only any Further information for purposes required Avoid contact with metals Components with workplace control parameters inspection I. EXPOSURE CONTROLSlPERSONAL PROTECTION owner copyright For Manganese bis(dihydrogen phosphate) 1871 8-07-5 of TWA Consent 0.50 mglm3 As Mn 2006-09-01 GB EH40 Value Update Basis Nickel(l1) nitrate 131 38-45-9 Value Update Basis TWA 0.10 mg/m3 Nickel 2007-08-01 GB EH40 2007-08-01 GB EH40 Orthophosphoric acid 7664-38-2 Value Update Basis TWA OO mg/m3 2000-06-1 6 2000/39/EC STEL 2.00 mglm3 2000-06-1 6 2000/39/EC TWA OO mg/m3 2005-04-06 GB EH40 STEL 2.00 mg/m3 2005-04-06 GB EH40 Manganese fluoroborate 30744-82-2 Value Update Basis TWA 0.50 mglm3 As Mn 2006-09-01 GB EH40 TWA 2.50 mg/m3 2000-06-1 6 2000/39/EC Personal protective equipment Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Recommended Filter type NO-P3 Sardobond R 2604E Iersion: 3 22.03.2010 Hand protection Material: Neoprene General advice: Protective gloves complying with EN 374., The exact break through time can be obtained from the protective glove producer and this has to be observed., Protective gloves have to be replaced at the first sign of deterioration Eye protection Tightly fitting safety goggles Skin and body protection Chemical resistant protective clothing according to DIN EN 13034 Hvcliene measures Take off contaminated clothing and shoes immediately. Avoid contact with skin and eyes. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and immediately after handling the product Protective measures Handle in accordance with good industrial hygiene and safety practice. Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower use PHYSICAL AND CHEMICAL PROPERTIES other only any Form liquid for Odour green purposes none required Colour Solidification temperaturekange inspection "C owner For Boiling point/boiling range copyright 110 "C of Consent Flash point not applicable Density 1.53 glcm3 pH Solubilitylqualitative 1.5 completely miscible undiluted) IO. STABILITY AND REACTIVITY Conditions to avoid To avoid thermal decomposition, do not overheat Materials to avoid Contact with organic substances or other reducing agents can form mixed nitrous gases (toxic)., Incompatible with bases Hazardous decomposition products nitrogen oxides (NOx) Hazardous reactions Gives off hydrogen by reaction with metals 417 Zardobond R 2604E lersion: 3 22.03.2010 Thermal decomposition 320 "C TOXICOLOGICAL INFORMATION Skin irritation Causes burns Eye irritation Causes burns Sensitisation May cause sensitization by inhalation and skin contact Further toxicological information May cause cancer by inhalation., May cause harm to the unborn child., Possible risk of irreversible effects., Also toxic: danger of serious damage to health use. by prolonged exposure through inhalation other only any Elimination information (persistence and purposes ECOLOGICAL INFORMATION degradability) required for Chemical Oxygen Demand (COD) owner Further information copyright mg/l inspection For of Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. highly Consent water endangering DISPOSAL CONSIDERATIONS Waste key for the unused product 01 06 acids not otherwise specified Product Dispose of as hazardous waste in compliance with local and national regulations Contaminated packaging Dispose of as hazardous waste in compliance with local and national regulations TRANSPORT INFORMATION Regulation ADR UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid, Nickel(l1) nitrate Packaging group: 111 Class: a 1 7 3ardobond R 2604E lersion: 3 22.03.2010 ADWRID-Labels: 8 Regulation RID UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid, Nickel( II) nitrate Packaging group: Ill Class: 8 ADWRID-Labels: 8 Regulation IMDG UN/ID No.: 3264 Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric acid, Nickel dinitrate Packaging group: Ill Environmentally Hazardous Class: 8 Ems: F-A S-B Regulation IATA-C UN/ID No.: 3264 use Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric other acid any Packaging group: Ill only for purposes required Class: 8 Proper shipping name: CORROSIVE inspection LIQUID, ACIDIC, INORGANIC, N.O.S., Orthophosphoric Regulation IATA-P UN/ID No.: 3264 owner acid For Packaging group: Ill copyright Class: 8 of Consent REGULATORY INFORMATION Hazardous components which must be listed on the label Nickel(l1) nitrate 81 Dangerous for the environment La be II i ng Toxic R49 May cause cancer by inhalation R6 1 May cause harm to the unborn child R48123 Also toxic: danger of serious damage to health by prolonged exposure through inhalation R34 Causes burns R68 Possible risk of irreversible effects R42143 May cause sensitization by inhalation and skin contact R51 153 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 22.03.2010 S-phrase( s): s53 Avoid exposure - obtain special instructions before use S23 Do not breathe gaslfumeslvapourlspray S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice s35 This material and its container must be disposed of in a safe way S36137139 Wear suitable protective clothing, gloves and eye/face protection s45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Special labelling of certain mixtures estricted to professional users 99/45/EC - 2001 /60/EC and 200618/EC included Other regulations use German regulation: Soluble nickel salts are carcinogenic substances, category 1 other only any Other regulations for The product is classified and labelled in accordance with EC directives or respective national laws purposes required inspection owner Text of R phrases mentioned in Section 3 copyright OTHER INFORMATION For of R 8 Contact with combustible material may cause fire R20122 Harmful by inhalation and if swallowed Consent R34 Causes burns R38 Irritating to skin R41 Risk of serious damage to eyes R48123 Toxic: danger of serious damage to health by prolonged exposure through inhalation R42143 May cause sensitization by inhalation and skin contact R49 May cause cancer by inhalation R50 Very toxic to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment R61 May cause harm to the unborn child R68 Possible risk of irreversible effects Text of R phrases mentioned in Section 3 The information provided is based on our current knowledge and experience and apply to the product as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product I This data sheet contains changes from the previous version in section(s): 14 Zardoclean S 5174 lersion: 2 18.07.2008 IDENTIFICATION OF THE SUBSTANCElPREPARATlON AND OF THE OMPANYlUNDERTAKING English Product information Commercial Product Name Gardoclean S 5174 Recommended use Cleaning agent Corn pany Chemetall plc Denbigh Road Bletchley Milton Keynes MKI 1 PB Lead Organisation Contact person Telephone 01908649333 use Telefax 01908 373939 other only any Product safety for Telephone 44(0)1908 649333 E-mail address ukinfo@chemetall.com purposes required inspection Emergency telephone 01908 649333 owner For I. HAZARDS IDENTIFICATION copyright of Consent ~~ Risk advice to man and the environment Classification Corrosive R35 Causes severe burns Harmful R22 Harmful if swallowed COMPOSlTlONllNFORMATION ON INGREDIENTS Hazardous components Potassium Hvdroxide 25.00 - 50.00 Yo CAS-NO.: 1310-58-3 EINECS-NO.: 215-181-3 Classification: Xn; R22 C; R35 sodium N-~2-carboxvethvl~-N-~2-ethvlhexvl~-beta-alaninate 2.50 - 5.00 YO CAS-NO.: 94441-92-6 EINECS-NO.: 305-318-6 Classification: Xi: R41 Alcohol alkoxvlate 0.10 - 1.00 % Classification: N; R50 / 6 Sardoclean S 5174 fersion: 2 18.07.2008 FIRST AID MEASURES General advice Take off contaminated clothing and shoes immediately Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician Skin contact Wash off immediately with plenty of water. If symptoms persist, call a physician Inhalation Move to fresh air. If symptoms persist, call a physician Ingestion physician immediately Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a i. FIRE-FIGHTING MEASURES use Special protective equipment for fire-fighters other Suitable extinguishing media In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment only for any Further information purposes required Carbon dioxide (C02), Dry powder, Water spray, Alcohol-resistant foam inspection owner The product itself does not burn copyright i. ACCIDENTAL RELEASE MEASURES For Personal precautions of Wear personal protective equipment. Evacuate personnel to safe areas Environmental precautions Consent Do not flush into surface water or sanitary sewer system Methods for cleaning up up spillage and collect in suitable container for disposal Soak up with liquid binder (sand, kieselguhr, acid binder, universal binder). Sweep up or vacuum I. HANDLING AND STORAGE Handling Safe handling advice Have eye wash bottle or eye rinse ready at the work place Advice on protection against fire and explosion No special protective measures against fire required Storage Requirements for storage areas and containers Store at room temperature in the original container. Keep container tightly closed Further information Avoid contact with amphoteric metals (e.g. aluminium, lead, zinc) 216 Gardoclean S 5174 Jersion: 2 18.07.2008 EXPOSURE CONTROLSlPERSONAL PROTECTION Components with workplace control parameters Potassium Hydroxide 1310-58-3 Value Update Basis STEL 2.00 mglm3 2007 EH40 WEL Personal protective equipment Respiratory protection Not required; except in case of aerosol formation Hand protection Material: butyl-rubber Break through time: > 480 min General advice: The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it., The exact break through time can be obtained from the protective glove producer and this has to be observed use Eye protection other Tightly fitting safety goggles only any Skin and body protection for Hygiene measures required Protective suit purposes Take off contaminated clothing and shoes immediately. Avoid contact with the skin and the eyes owner Keep away from food, drink and animal copyright inspection feedingstuffs. Wash hands before breaks and at the end of workday For of Consent PHYSICAL AND CHEMICAL PROPERTIES Form liquid Colour light brown Melting pointhange c -10 "C Odour slight Boiling poinffrange 115 "C Flash point not applicable Density 1.36 g/cm3 Solubility/qualitative completely miscible pH 13.6 at: 43 g/L IO. STABILITY AND REACTIVITY Materials to avoid Amphoteric metals are attacked developing hydrogen (combustible) 1 6 Gardoclean S 5174 Jersion: 2 18.07.2008 Hazardous decomposition products No decomposition if stored and applied as directed Hazardous reactions Exothermic reaction with strong acids TOXICOLOGICAL INFORMATION Skin irritation Causes severe burns Eye irritation Causes severe burns, Sensitisation not applicable Further toxicological information use Harmful if swallowed., Ingestion: Corrosive to mouth, oesophagus other and stomach only any for Elimination information (persistence and degradability) purposes required ECOLOGICAL INFORMATION Chemical Oxygen Demand (COD): inspection owner copyright ca. 90 mg/g For Further information of Consent slightly water endangering DISPOSAL CONSIDERATIONS Waste key for the unused product 101 13 degreasing wastes containing dangerous substances Product Dispose of as hazardous waste in compliance with local and national regulations Contaminated packaging Dispose of as hazardous waste in compliance with local and national regulations TRANSPORT INFORMATION Regulation ADR UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8 ADR/RID-Labels: 8 Regulation RID 416 18.07.2008 UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: I1 Class: 8 ADR/RID-Labels: 8 Regulation IMDG UNAD No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8 Ems: F-A S-B Regulation IATA-C UN/ID No.: 1814 Proper shipping name: POTASSIUM HYDROXIDE SOLUTION Packaging group: II Class: 8 use Regulation IATA-P UN/ID No.: 1814 other Proper shipping name: POTASSIUM HYDROXIDE SOLUTION only any Packaging group: II purposes required for Class: 8 inspection owner REGULATORY INFORMATION For Hazardous components which must be listed on the label copyright Potassium Hydroxide of